基本情報
- CAS
66470-81-3- 標準SMILES
FC(F)(F)C(OP(OC(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)C(F)(F)F)C(F)(F)F- InChIKey
MJOVEPJSFHDSOJ-UHFFFAOYSA-N- 分子式
- C9H3F18O3P
- 平均分子量
- 532.06 g/mol
- 単同位体質量
- 531.9532379
名称と識別子
- 優先名称
- Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite
- IUPAC
- tris(1,1,1,3,3,3-hexafluoropropan-2-yl) phosphite
- 現地名
- 亜りん酸トリス(1,1,1,3,3,3-ヘキサフルオロ-2-プロピル)
- 英語名
- TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE
- 分子式
- C9H3F18O3P
- 分子量
- 532.06
名称と別名
Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphiteRefChem:900100623-540-466470-81-3tris(1,1,1,3,3,3-hexafluoropropan-2-yl) phosphiteTris(1,1,1,3,3,3-hexafluoro-2-propyl)phosphiteMFCD00192561NSC334060A835470C9H3F18O3PSCHEMBL2378613tris(hexafluoroisopropyl)phosphite
名称をさらに表示
亜りん酸トリス(1,1,1,3,3,3-ヘキサフルオロ-2-プロピル)tris(2h-perfluoro-2-propyl) phosphiteTris(1,1,1,3,3,3-hexafluoro-2-propoxy)phosphiteTris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite 98%2-Propanol, 1,1,1,3,3,3-hexafluoro-, 2,2',2''-phosphitePhosphorous Acid Tris(1,1,1,3,3,3-hexafluoro-2-propyl) Ester
DTXSID20318694Tris[2,2,2-trifluoro-1-(trifluoromethyl)ethyl] phosphitetris[1,1,1,3,3,3-hexakis(fluoranyl)propan-2-yl] phosphitephosphorous acid tris(1,1,1,3,3,3-hexafluoropropan-2-yl) esterAKOS025310360NSC-334060AS-67362SY235278
データベース識別子
- CAS
物性
構造計算による物性
- XLogP
- 7
- 極性表面積
- 27.7 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 21
- 回転可能結合数
- 6
- 重原子数
- 31
- 形式電荷
- 0
- 複雑度
- 444
物理化学的性質
- 沸点
- 130 °C · 130 °C (lit.)
- 比重(密度)
- 1.69 g/mL · 1.69 g/mL at 25 °C (lit.)
- 屈折率
- 20 · n20/D 1.300(lit.)
- 外見
- clear liquid
- 色
- Colorless to Almost colorless
- BRN
- 2315565 · 2315565
- InChI
- 1S/C9H3F18O3P/c10-4(11,12)1(5(13,14)15)28-31(29-2(6(16,17)18)7(19,20)21)30-3(8(22,23)24)9(25,26)27/h1-3H
- InChIKey
- MJOVEPJSFHDSOJ-UHFFFAOYSA-N
- SMILES
- FC(F)(F)C(OP(OC(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)C(F)(F)F)C(F)(F)F
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
危険有害性情報
Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (100%)
安全データ
- wgk
- 3
- hs_code
- 2920290090
- risk_code
- 36/37/38
- hazard_code
- Xi
- safety_code
- 26-36
- Hazard Classifications
- Eye Irrit. 2Skin Irrit. 2STOT SE 3
- ストレージクラス
- 10 - Combustible liquids
化学と産業
応用分野
使用Tris(1,1,1,3,3,3-hexafluoro-2-propyl) Phosphite acts as a catalyst in combination with rhodium complex in the hydroformylation of olefins.
一般的な説明Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite (tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphite) is a sterically hindered, weakly σ-donating and strongly π-accepting ligand. It can be prepared by the reaction of lithium salt of 1,1,1,3,3,3-hexafluoro-2-propoxide with PCl3. It reacts with nucleosides to form deoxyribonucleoside 3′-bis(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite units.
上流・下流製品情報
上流原料
サプライヤー34 社
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]
上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]
上海毕得医药科技股份有限公司400-1647117 13681763483 · [email protected]
関連反応
7 件
化合物ノート
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