化工社化工社 化学情報印刷レポート · 研究参考用
アザイド
アザイド · アジ化物 · Azide · azide(1-) · Irbesartan EP Impurity B · (E/Z)-N,N-Didesmethyl-4-hydroxy Tamoxifen 2&rsquo
識別子と物理属性
| CAS No. | 14343-69-2 |
|---|---|
| 分子式 | N3- |
| 平均分子量 | 42.021 g/mol |
| 単同位体質量 | 42.00922201 g/mol |
| SMILES | [N-]=[N+]=[N-] |
| InChIKey | IVRMZWNICZWHMI-UHFFFAOYSA-N |
| PubChem CID | 33558 |
| ChEMBL | CHEMBL79455 |
| ChEBI | CHEBI:40910 |
| DTXSID | DTXSID8074310 |
| 現地名 | アザイド |
化学・物理的性質
| XLogP | 1.5 |
|---|---|
| 極性表面積 | 3 |
| 水素結合供与体数 | 0 |
| 水素結合受容体数 | 2 |
| 回転可能結合数 | 0 |
| 重原子数 | 3 |
| 形式電荷 | -1 |
| 複雑度 | 15 |
| 融点 | 119-120 °C (decomp) |
| EPAの化学物質情報 | Azide (14343-69-2) |
安全性と法規制
| 規制情報 | Azide (anion): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
|---|---|
| 有害性の概要 | All azide salts are unstable, and some explode after heat or shock. Organic azides are sensitized by metal salts or strong acids. Azides emit toxic fumes when heated to decomposition. [Sax] The azide group (N3) has an affinity for ferric iron in mitochondrial cytochrome oxidase. Like cyanide poisoning, azide poisoning disrupts cellular aerobic metabolism. [AHLS, p. 202] Most of the fulminates and azides of heavy metals are sensitive explosives. These materials do not make efficient explosivestheir sole attraction is their sensitivity. [Reference #1] See Sodium azide. |
| 有害作用 | Other Poison - Chemical Asphyxiant |
用途
解説
アジ化水素酸の塩およびN3基をもつ分子の総称．塩は古くトリアゾ水素酸塩，窒化水素酸塩などとよばれたこともある．N3基を有する有機化合物はアジドとよぶことが多い．