ホスファゼン塩基 P2-ET

2,N'3,N'3,N3,N3,N'5,N'5,N5,N5-nonamethyl-2,4,6-triaza-3lambda5,5lambda5-diphosphaocta-3,5-diene-3,3,5,5-tetramine

HCID 3393106

ノート反応

部分構造検索類似構造を探す

基本情報

CAS: 165535-45-5
標準SMILES: CCN=P(N=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C
InChIKey: CFUKEHPEQCSIOM-UHFFFAOYSA-N
分子式: C12H35N7P2
平均分子量: 339.4 g/mol
単同位体質量: 339.24291738

名称と識別子

優先名称: 2,N'3,N'3,N3,N3,N'5,N'5,N5,N5-nonamethyl-2,4,6-triaza-3lambda5,5lambda5-diphosphaocta-3,5-diene-3,3,5,5-tetramine
IUPAC: N-[dimethylamino-ethylimino-[[tris(dimethylamino)-λ5-phosphanylidene]amino]-λ5-phosphanyl]-N-methylmethanamine
現地名: ホスファゼン塩基 P2-ET
英語名: 1-Ethyl-2,2,4,4,4-pentakis(dimethylamino)-2lambda5,4lambda5-catenadi(phosphazene)
分子式: C12H35N7P2
分子量: 339.4

名称と別名

2,n'3,n'3,n3,n3,n'5,n'5,n5,n5-Nonamethyl-2,4,6-triaza-3lambda5,5lambda5-diphosphaocta-3,5-diene-3,3,5,5-tetramineRefChem:446554635-462-8Phosphazene base P2-Et165535-45-5P2Et PhosphazeneMFCD00145113N',N',N'',N''-hexamethylphosphorimidic triamide-N,N,N',N',N'',N''-hexamethylphosphorimidic triamideN-[dimethylamino-ethylimino-[[tris(dimethylamino)-lambda5-phosphanylidene]amino]-lambda5-phosphanyl]-N-methylmethanaminePhosphorimidic triamide, N'''-[P,P-bis(dimethylamino)-N-ethylphosphinimyl]-N,N,N',N',N'',N''-hexamethyl-Phosphazene ligand P2-EtSCHEMBL1356930

名称をさらに表示

ホスファゼン塩基 P2-ETTetramethyl(tris(dimethylamino)phosphoranylidene)phosphorictriamid-Et-iminPhosphazene base PPhosphazene base P2-Et >=98.0% (NT)TETRAMETHYL(TRIS(DIMETHYLAMINO)PHOSPHOR&Phosphazene base P2-Et purum, >=98.0% (NT)1-ethyl-2,2,4,4,4-pentakis(dimethylamino)-2λ5,4λ5-catenadi(phosphazene)

DTXSID00392093C12H35N7P2QGA53545AKOS0159136321-Ethyl-2,2,4,4,4-pentakis(dimethylamino)-2lambda5,4lambda5-catenadi(phosphazene)CS-0217064Phosphazene base P2-Et, >=98.0% (NT)ST51016136

データベース識別子

CAS: 165535-45-5
PubChem CID: 3393106
DTXSID: DTXSID00392093
EC Number: 635-462-8
Nikkaji: J744.125H

物性

構造計算による物性

XLogP: 1.8
極性表面積: 40.9 Å²
水素結合供与体数: 0
水素結合受容体数: 7
回転可能結合数: 7
重原子数: 21
形式電荷: 0
複雑度: 387

物理化学的性質

沸点: 96 °C0.05 · 96 °C0.05 mm Hg(lit.)
比重(密度): 1.02 g/mL · 1.02 g/mL at 25 °C(lit.)
屈折率: 20 · n20/D 1.492(lit.)
闪点: 113 °C · 113 °C
貯蔵温度: 2 · 2-8°C, protect from light, stored under nitrogen
外見: liquid
BRN: 7485991 · 7485991
InChI: 1S/C12H35N7P2/c1-12-13-20(15(2)3,16(4)5)14-21(17(6)7,18(8)9)19(10)11/h12H2,1-11H3
InChIKey: CFUKEHPEQCSIOM-UHFFFAOYSA-N
SMILES: CCN=P(N=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 1 notifications to the ECHA C&L Inventory.

危険有害性情報

Hazard Classes and CategoriesSkin Corr. 1B (100%)

安全データ

F: 3-10-21-34
wgk: 3
ridadr: UN 3267 8/PG 2
risk_code: 34
hazard_code: C
safety_code: 26-36/37/39-45-27
Hazard Classifications: Skin Corr. 1B
ストレージクラス: 8A - Combustible corrosive hazardous materials

化学と産業

応用分野 · 1 件

使用P2Et phosphazene is a strong non-ionic base has the ability to catalyze a wide variety of organic transformations. This includes but is not limited to cross coupling reactions, deprotonation of sulphones and conversion of vinyl sufone to allyl sulfone