基本情報
- CAS
2144-45-8- 標準SMILES
O=C(OCc1ccccc1)OOC(=O)OCc1ccccc1- InChIKey
IAWYWVVBKGWUEP-UHFFFAOYSA-N- 分子式
- C16H14O6
- 平均分子量
- 302.28 g/mol
- 単同位体質量
- 302.07903816
概要
This solid peroxide is sensitive to heat. Storage of this material must be done so with stringent temperature control measures. Its explosion hazard is also mitigated by mixing the peroxide in a water slurry.
名称と識別子
- 優先名称
- Dibenzyl peroxydicarbonate
- IUPAC
- benzyl phenylmethoxycarbonyloxy carbonate
- 現地名
- ペルオキシ二炭酸ジベンジル
- 英語名
- Diphenylmethyl peroxydicarbonate
- 分子式
- C16H14O6
- 分子量
- 302.28
名称と別名
dibenzyl peroxydicarbonatePeroxydicarbonic acid, C,C'-bis(phenylmethyl) esterDIBENZYL PEROXYDICARBONATE, (<= 87% WITH WATER)DIBENZYL PEROXYDICARBONATE, [<= 87% WITH WATER]RefChem:586442PEROXYDICARBONIC ACID, DIBENZYL ESTERPeroxydicarbonic acid, bis(phenylmethyl) esterbenzyl phenylmethoxycarbonyloxy carbonate2144-45-8Bisbenzyl peroxydicarbonateHA86UR6MBTUNII-HA86UR6MBT
名称をさらに表示
ペルオキシ二炭酸ジベンジルジベンジルペルジカルボナートペルオキシジ炭酸ジベンジル[α,β-ペルオキシ]二炭酸ジベンジルジベンジルパージカーボネートジベンジル-ペルオキシ-ジカーボネート{[({[(ベンジルオキシ)カルボニル]ペルオキシ}カルボニル)オキシ]メチル}ベンゼンDibenzyl perdicarbonatePeroxydicarbonic acid dibenzylPeroxydicarbonic acid dibenzyl ester[α,β-Peroxy]dicarbonic acid dibenzyl esterdibenzyl peroxydicarbonate, <= 87% with waterDiphenylmethyl peroxydicarbonate(not more than 87%,with water)benzyl phenylmethoxycarbonyloxy carbonate[content ≤87%, water content]
EINECS 218-406-3Dibenzyl peroxydicarbonate, >87% with waterDibenzyl peroxydicarbonate, >87% with water [Forbidden]NSC617286SCHEMBL454115Diphenylmethyl peroxydicarbonateCHEMBL1972427DTXSID4075295
データベース識別子
- CAS
2144-45-8- PubChem CID
- 357763
- DTXSID
DTXSID4075295- ChEMBL
CHEMBL1972427- UNII
- HA86UR6MBT
- EC Number
- 218-406-3
- Nikkaji
- J9.208H
物性
構造計算による物性
- XLogP
- 4
- 極性表面積
- 71.1 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 6
- 回転可能結合数
- 9
- 重原子数
- 22
- 形式電荷
- 0
- 複雑度
- 311
実験および物理化学的性質
Physical DescriptionThis solid peroxide is sensitive to heat. Storage of this material must be done so with stringent temperature control measures. Its explosion hazard is also mitigated by mixing the peroxide in a water slurry.
物理化学的性質
- 融点
- 101 °C · 101 °C (decomp)
- 沸点
- 403.32 °C · 403.32°C (rough estimate)
- 比重(密度)
- 1.3128 · 1.3128 (rough estimate)
- 屈折率
- 1.4795 · 1.4795 (estimate)
- EPAの化学物質情報
- Peroxydicarbonic acid, bis(phenylmethyl) ester (2144-45-8)
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
危険有害性情報
DOT LabelOrganic Peroxide
Fire HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Health HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Reactive GroupPeroxides, Organic
Reactivity AlertsExplosive
Reactivity Profile
DIBENZYL PEROXYDICARBONATE decomposes violently or explosively at temperatures 0-10 °C. owing to self-accelerating exothermic decomposition; Several explosions were due to shock, heat or friction; amines and certain metals can cause accelerated decomposition [Bretherick, 1979 p. 156]. Danger of explosion when dry
DOT Hazard Classification
Dibenzyl peroxydicarbonate, with more than 87 percent with water
Forbidden explosives/materials (49 eCFR § 173.54/§ 173.21)
Air and Water ReactionsNo rapid reaction with air. No rapid reaction with water.
安全と保護具
Fire FightingExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
First AidExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Nonfire Spill ResponseExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Isolation and EvacuationExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Personal Protective Equipment (PPE)Excerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
安全データ
- ridadr
- 3114
- hazard_class
- 5.2
- packing_group
- II
化学と産業
応用分野
一般的な説明Diphenylmethyl peroxydicarbonate(not more than 87%,with water) is sensitive to heat. Storage of Diphenylmethyl peroxydicarbonate(not more than 87%,with water) must be done so with stringent temperature control measures. Its explosion hazard is also mitigated by mixing the peroxide in a water slurry.
サプライヤー2 社
海蔚化学86-21-51086038 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]
関連反応
0 件
現在のフィルター条件では反応記録がありません。
化合物ノート
読み込み中…