フタロシアニン銅 (α-型)
フタロシアニン銅 (α-型) · フタロシアニン銅 (β-型) · ピグメント ブルー 15 · シアンブルーGTNF · フタロシアニンブルー · C.I.ピグメントブルー15 · フタロシアニン/銅,(1:1) · シアニンブルーC
識別子と物理属性
| CAS No. | 147-14-8 |
|---|---|
| 分子式 | C32H16CuN8 |
| 平均分子量 | 576.1 g/mol |
| SMILES | [Cu].c1ccc2c(c1)C1=NC2=NC2=NC(=NC3=NC(=NC4=NC(=N1)c1ccccc14)c1ccccc13)c1ccccc12 |
| InChIKey | VVOLVFOSOPJKED-UHFFFAOYSA-N |
| PubChem CID | 475701 |
| ChEBI | CHEBI:155903 |
| DTXSID | DTXSID8027117 |
| 現地名 | フタロシアニン銅 (α-型) |
化学・物理的性質
| 極性表面積 | 98.9 |
|---|---|
| 水素結合供与体数 | 0 |
| 水素結合受容体数 | 0 |
| 回転可能結合数 | 0 |
| 重原子数 | 41 |
| 形式電荷 | 0 |
| 複雑度 | 1,070 |
| 融点 | 600°C (dec.) |
| 密度 | 1.62[at 20℃] |
| 貯蔵条件 | Inert atmosphere,Room Temperature |
| 溶解度 | insoluble in H2O, ethanolsoluble in concHSO 4<0.1 g/100 mL で 20 ºC |
| 外観・状態 | 微結晶性粉末 |
| 色 | 濃紺 |
| 臭い | 無臭 |
| Merck | 14,2520 |
| BRN | 4121848 |
| 化粧品成分の機能 | 着色剤ヘアカラーリング |
| InChIKey | XCJYREBRNVKWGJ-UHFFFAOYSA-N |
| SMILES | c1ccc2c(c1)C3=NC4=[N@@H]5C(=Nc6n7c(N=C8c9ccccc9C%10=[N@@H]8[Cu]57N3C2=N%10)c%11ccccc6%11)c%12ccccc4%12 |
| LogP（分配係数） | -1 at 23℃ |
| NISTの化学物質情報 | Copper phthalocyanine(147-14-8) |
| EPAの化学物質情報 | C.I. Pigment Blue 15 (147-14-8) |
| Absorption | λmax 678 nm (DMF) |
化学的特性
dark blue fine crystalline powder
安全性と法規制
| CSL Reaction Information | CSL00157Copper phthalocyanine + Chlorosulfonic acidCopper phthalocyanine was added too fast to chlorosulfonic acid causing a violent formation of hydrogen chloride.ExplosiveNot AvailableSubstance identification sources: Copper phthalocyanine. CAS Common Chemistry. CAS, a division of the American Chemical Society, n.d. https://commonchemistry.cas.org/detail?cas_rn=147-14-8 (retrieved 2022-01-27) (CAS RN: 147-14-8). Chlorosulfonic acid. CAS Common Chemistry. CAS, a division of the American Chemical Society, n.d. https://commonchemistry.cas.org/detail?cas_rn=7790-94-5 (retrieved 2022-01-27) (CAS RN: 7790-94-5). |
|---|---|
| 水環境危害等級（WGK） | - |
| TSCA 収載状態 | TSCA listed |
| RTECS 番号 | GL8510000 |
| 毒性 | LD50 intraperitoneal in rat: > 3gm/kg |
| 税関コード | 32041300 |
| 化審法 | (5)-3299, (5)-5216 |
| 安衛法 | 57,57-2 |
| 安全措置（S） | 22-24/25 |
| 貯蔵分類 | 11 - Combustible Solids |
| 有害物質データ | 147-14-8(Hazardous Substances Data) |
用途
解説
フタロシアニンの銅錯塩．きわめて堅ろうな青色有機顔料として著名．フタロニトリルまたは無水フタル酸と銅化合物からつくられる．α型(赤味)，β型(緑味)などの結晶形があるが，β型がもっとも安定である．ベンゼン環の水素をハロゲンで置換すると青緑から緑色になる．
用途
有機顔料(塗料,印刷インキ,プラスチック,ゴム),染料?顔料中間体 (NITE CHRIP)
用途
塗料、印刷インキ、プラスチック添加用色素。
説明
Copper(II) phthalocyanine, known as CuPc, has been used as an electron donorwith fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV).Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer . CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device . Device stability was achieved bydepositing a copper phthalocyanine CuPc hole-injection layerHIL on the ITO anode.
使用
Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing.Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper.
一般的な説明
Copper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10-4 cm2/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.
製法・合成法
純化方法
Precipitate it twice from conc H2SO4 by slow dilution with water. It has also been purified by two or three sublimations at 580o in an argon flow at 300-400Pa. [Beilstein 26 III/IV 4256.]