CAS 921-26-6 Diisopropylphosphoramidous dichloride (HCID 5139911)

基本情報

CAS: 921-26-6
標準SMILES: CC(C)N(C(C)C)P(Cl)Cl
InChIKey: UPPVRFOGRCBSJP-UHFFFAOYSA-N
分子式: C6H14Cl2NP
平均分子量: 202.06 g/mol
単同位体質量: 201.02409144

名称と識別子

優先名称: Diisopropylphosphoramidous dichloride
IUPAC: N-dichlorophosphanyl-N-propan-2-ylpropan-2-amine
現地名: ジクロロ(ジイソプロピルアミノ)ホスフィン
英語名: DIISOPROPYLPHOSPHORAMIDOUS DICHLORIDE
分子式: C6H14Cl2NP
分子量: 202.06

名称と別名

921-26-6Diisopropylphosphoramidous dichlorideDTXSID30408696RefChem:587939DTXCID80359548633-001-5Dichloro N,N-DiisopropylphosphoramiditeN-dichlorophosphanyl-N-propan-2-ylpropan-2-amineN,N-Bis(1-methylethyl)phosphoramidous dichlorideMFCD00012236(dichlorophosphanyl)bis(propan-2-yl)aminePhosphoramidous dichloride, bis(1-methylethyl)-

名称をさらに表示

ジクロロ(ジイソプロピルアミノ)ホスフィンN,N-ジイソプロピルアミド亜りん酸ジクロリドN,N-ジイソプロピルジクロロホスフィンアミンジイソプロピルアミノジクロロホスフィンジクロロホスフィノジイソプロピルアミン(ジクロロホスファニル)ビス(プロパン-2-イル)アミン1,1-dichloro-N,N-diisopropylphosphanamineDiisopropylaminodichlorophosphineDiisopropylaminodichlorphosphanDichlorophosphinodiisopropylamineDIISOPROPYLAMINOPHOSPHORDICHLORIDEDichloro(diisopropylamino)phosphineN-diisopropylaminodichlorophosphaneBis(isopropyl)aminodichlorophosphine

Phosphoramidousdichloride, N,N-bis(1-methylethyl)-iPr2NPCl2Dichloro-N,N-diisopropylamino-phosphaneC6H14Cl2NPSCHEMBL1146068SCHEMBL10716728diisopropylphosphoramidodichloriditeUPPVRFOGRCBSJP-UHFFFAOYSA-N

データベース識別子

CAS: 921-26-6
PubChem CID: 5139911
DTXSID: DTXSID30408696
EC Number: 633-001-5
Nikkaji: J429.871C

物性

構造計算による物性

XLogP: 3.3
極性表面積: 3.2 Å²
水素結合供与体数: 0
水素結合受容体数: 1
回転可能結合数: 2
重原子数: 10
形式電荷: 0
複雑度: 87.7

実験および物理化学的性質

SpringerMaterials Properties15N nuclear magnetic resonance spectrum

物理化学的性質

沸点: 56 · 56-58°C/15mmHg.
比重(密度): 1.096 g/mL · 1.096 g/mL at 25 °C(lit.)
屈折率: 20 · n20/D 1.485(lit.)
闪点: 66 °C · 66 °C
貯蔵温度: Hygroscopic, Refrigerator, Under Inert Atmosphere
溶解性: Acetonitrile (Slightly), Chloroform (Soluble), Dichloromethane (Slightly), Ethyl
外見: Oil
酸解離定数(Pka): -1 · -1.00±0.70(Predicted)
色: Colourless to Light Yellow
安定性: 湿気に敏感
InChI: InChI=1S/C6H14Cl2NP/c1-5(2)9(6(3)4)10(7)8/h5-6H,1-4H3
InChIKey: UPPVRFOGRCBSJP-UHFFFAOYSA-N
SMILES: P(N(C(C)C)C(C)C)(Cl)Cl
CAS データベース: 921 · 921-26-6

化学的性質

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H250 (100%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]

P210, P222, P231, P233, P260, P264, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazard Classes and CategoriesPyr. Liq. 1 (100%)

安全データ

wgk: 3
ridadr: 2846
risk_code: 1-5-14-34
hazard_code: E,C
safety_code: 15-26-27-36/37/39-45
hazard_class: 4.2
packing_group: I

化学と産業

応用分野

使用Diisopropylphosphoramidous dichloride is used as a versatile phosphitylating agent for the phosphorylation of hydroxy amino acids and the preparation of protected phosphopeptides.