CAS 1111-92-8 Dimethylphosphinic chloride (HCID 517954)

基本情報

CAS: 1111-92-8
標準SMILES: CP(C)(=O)Cl
InChIKey: CVNMBKFJYRAHPO-UHFFFAOYSA-N
分子式: C2H6ClOP
平均分子量: 112.49 g/mol
単同位体質量: 111.98447912

名称と識別子

優先名称: Dimethylphosphinic chloride
IUPAC: [chloro(methyl)phosphoryl]methane
現地名: クロロジメチルホスフィンオキシド
英語名: DIMETHYLPHOSPHINIC CHLORIDE
分子式: C2H6ClOP
分子量: 112.5

名称と別名

Dimethylphosphinic chloride1111-92-8Phosphinic chloride, dimethyl-EINECS 214-187-3DTXSID40149503RefChem:588592DTXCID2071994214-187-3[chloro(methyl)phosphoryl]methaneMFCD00002078dimethylphosphinoyl chlorideC2H6ClOP

名称をさらに表示

ジメチルホスフィン酸クロリドクロロジメチルホスフィンオキシドジメチルホスフィノイルクロリドChlorodimethylphosphine oxideDiMethylphosphinic chloride 97%Dimethylphosphinic acidchlorideDimethylphosphinic chloride, 97+%3-Pyridinecarboxylicacid,6-(1H-imidazol-2-yl)-Phosphinic chloride, dimethyl- (6CI,7CI,8CI,9CI)

Me2P(O)Cldimethylphosphinoylchloridedimethylphosphinyl chlorideDimethylphosphin1c chloridedimethyl phosphinyl chlorideSCHEMBL213567Dimethylphosphinic chloride, 97%AKOS015916086

データベース識別子

CAS: 1111-92-8
PubChem CID: 517954
DTXSID: DTXSID40149503
EC Number: 214-187-3
Nikkaji: J217.229A

物性

構造計算による物性

XLogP: 0.2
極性表面積: 17.1 Å²
水素結合供与体数: 0
水素結合受容体数: 1
回転可能結合数: 0
重原子数: 5
形式電荷: 0
複雑度: 64

実験および物理化学的性質

SpringerMaterials Properties31P nuclear magnetic resonance spectrum

物理化学的性質

融点: 65 · 65-71 °C(lit.)
沸点: 204 °C · 204 °C(lit.)
比重(密度): 1.158 · 1.158±0.06 g/cm3(Predicted)
闪点: 204 °C · 204°C
貯蔵温度: Refrigerator, under inert atmosphere
溶解性: クロロホルム（少量）、メタノール（少量）
外見: 結晶性
色: ホワイトからオフホワイト
安定性: 湿気に敏感
InChI: 1S/C2H6ClOP/c1-5(2,3)4/h1-2H3
InChIKey: CVNMBKFJYRAHPO-UHFFFAOYSA-N
SMILES: CP(C)(Cl)=O
CAS データベース: 1111 · 1111-92-8

化学的性質

化学的特性yellow to pink to tan crystals or crystalline

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazard Classes and CategoriesSkin Corr. 1 (100%)

安全データ

wgk: 3
ridadr: UN 3261 8/PG 2
risk_code: 34
hazard_code: C
safety_code: 26-27-28-36/37/39-45
hazard_class: 8
packing_group: II
Hazard Classifications: Skin Corr. 1B
ストレージクラス: 8A - Combustible corrosive hazardous materials

化学と産業

応用分野

使用Dimethylphosphinic chloride is used in the protection of amino acids in peptide synthesis. It initiates the luminescence of ABI-NH2. It is utilized in the reactivity of organophosphate-based nerve gases such as sarin gas.

一般的な説明Kinetics of pyridinolyses of dimethylphosphinic chloride in acetonitrile was studied. Kinetics and mechanism of the reaction of dimethyl phosphinic chloride with anilines in acetonitrile was studied.