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銅(II)ジフルオリド

Copper fluoride

HCID 522688
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
7789-19-7
標準SMILES
[F][Cu][F]
InChIKey
GWFAVIIMQDUCRA-UHFFFAOYSA-L
分子式
CuF2
平均分子量
101.54 g/mol
単同位体質量
100.92640394

概要

Copper(II) fluoride is a fluoride of copper. Copper is a chemical element with the symbol Cu and atomic number 29. Copper is an essential elements in plants and animals as it is required for the normal functioning of more than 30 enzymes. It occurs naturally throughout the environment in rocks, soil, water, and air. (L277, L278)

名称と識別子

優先名称
Copper fluoride
IUPAC
difluorocopper
現地名
銅(II)ジフルオリド
英語名
Cupric fluoride
分子式
CuF2
分子量
101.54

名称と別名

Copper fluorideRefChem:580037Cupric fluorideCopper(II) fluoridedifluorocopperCuF2Copper difluorideCopper fluoride (CuF2)UNII-ML04XYE5C1ML04XYE5C1EINECS 232-147-3copper(II) flouride
名称をさらに表示
ふっ化第二銅銅(II)ジフルオリドふっ化銅(II)フッ化フッ化銅(Ⅱ)ふっ化銅(II), 無水ふっ化銅(II), 無水, 99%フッ化銅(2+)Copper(II) fLIron(Ⅲ) fluorideCoper difluorideCOPPER (II) FLUORIDEcopperfluoride(cuf2)COPPER (II) FLOURIDE
copper(2+) difluorideCopper(II) fluoride, 98%SCHEMBL2162223DTXSID80894782AKOS015915951Q419686

データベース識別子

CAS
7789-19-7
PubChem CID
522688
DTXSID
DTXSID80894782
EC Number
232-147-3

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
0
重原子数
3
形式電荷
0
複雑度
2.8

物理化学的性質

融点
950 °C · 950 °C (dec.)(lit.)
沸点
950 °C · 950 °C
比重(密度)
4.23 g/mL · 4.23 g/mL at 25 °C(lit.)
外見
粉
比重
4.85 · 4.85
色
白い
水溶解度
冷水に溶ける
Merck
14 · 14,2638
晶系
単斜
空间群
21 · P21/n
晶格常数
30.46157 · a/nmb/nmc/nmα/oβ/oγ/oV/nm30.461570.456240.329739096.707900.069
安定性
吸湿性
InChI
1S/Cu.2FH/h;2*1H/q+2;;/p-2
InChIKey
GWFAVIIMQDUCRA-UHFFFAOYSA-L
SMILES
F[Cu]F
CAS データベース
7789 · 7789-19-7(CAS DataBase Reference)
NISTの化学物質情報
Copper difluoride(7789-19-7)
EPAの化学物質情報
Copper fluoride (CuF2) (7789-19-7)
化学的性質 · 3 件

銅フッ化物は銅Cuとフッ素Fからなる無機化合物の一種ですこの化合物にはいくつかの異なる形態がありそれぞれが異なる化学式を持っています最も一般的な形態は一フッ化銅CuF2と二フッ化銅CuF2ですこれらの化合物はその化学的特性や用途によって異なりさまざまな産業分野で利用されています

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

Danger

H302 (14.6%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 48 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H319: Causes serious eye irritation [Warning Serious eye damage/eye irritation]

危険有害性情報

Hazard Classes and Categories · 2 件

Acute Tox. 4 (14.6%)

Serious eye damage/eye irritation - Category 2A-2B

安全と保護具

Minimum Risk LevelAcute Oral: 0.01 mg/kg/day (L134) Intermediate Oral: 0.01 mg/kg/day (L134)

毒性情報

Treatment · 1 件

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 件

People must absorb small amounts of copper every day because copper is essential for good health, however, high levels of copper can be harmful. Very-high doses of copper can cause damage to your liver and kidneys, and can even cause death. Copper may induce allergic responses in sensitive individuals. (L278, L279)

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Copper is mainly absorbed through the gastrointestinal tract, but it can also be inhalated and absorbed dermally. It passes through the basolateral membrane, possibly via regulatory copper transporters, and is transported to the liver and kidney bound to serum albumin. The liver is the critical organ for copper homoeostasis. In the liver and other tissues, copper is stored bound to metallothionein, amino acids, and in association with copper-dependent enzymes, then partitioned for excretion through the bile or incorporation into intra- and extracellular proteins. The transport of copper to the peripheral tissues is accomplished through the plasma attached to serum albumin, ceruloplasmin or low-molecular-weight complexes. Copper may induce the production of metallothionein and ceruloplasmin. The membrane-bound copper transporting adenosine triphosphatase (Cu-ATPase) transports copper ions into and out of cells. Physiologically normal levels of copper in the body are held constant by alterations in the rate and amount of copper absorption, compartmental distribution, and excretion. (L277, L279)

用途と製造

General Manufacturing InformationCopper fluoride (CuF2): ACTIVE
応用分野 · 3 件

用途銅フッ化物はその特異な化学的性質により多岐にわたる用途を持っています最も注目される用途の一つが触媒としての使用です特に二フッ化銅CuF2は有機合成反応において高い効率と選択性を提供するため製薬業界や化学合成業界で重宝されていますさらに銅フッ化物はガラスや陶磁器の着色剤としても利用されることがあり特定のフッ化銅化合物は美しい緑色や青色を生み出すことができます

使用Ceramics, enamels, flux in metallurgy, highenergy batteries, fluorinating agent.

一般的な説明Copper fluoride is a monoclinic weak ferromagnet. The structural properties were investigated by neutron diffraction.

サプライヤー39 社

Hebei Chuanghai Biotechnology Co., Ltd

関連反応

12 件
反応記録を作成
HRID 1369336 の反応式
HRID 1369336触媒としてuspto-grants-2003_06
HRID 1369337 の反応式
HRID 1369337触媒としてuspto-grants-2003_06
HRID 1369338 の反応式
HRID 1369338触媒としてuspto-grants-2003_06
HRID 1369339 の反応式
HRID 1369339触媒としてuspto-grants-2003_06
HRID 1369340 の反応式
HRID 1369340触媒としてuspto-grants-2003_06
HRID 1369341 の反応式
HRID 1369341触媒としてuspto-grants-2003_06
HRID 1369342 の反応式
HRID 1369342触媒としてuspto-grants-2003_06
HRID 1369343 の反応式
HRID 1369343触媒としてuspto-grants-2003_06
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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
化学的特性

化学的特性Cupric fluoride is blue powder

化学性质銅フッ化物は独特の物理的及び化学的性質を持っています二フッ化銅CuF2は無色または薄い緑色の結晶として存在し水に溶けやすく湿気を含む空気中で徐々に分解してフッ化水素HFガスを放出しますこの性質は扱いにあたって特別な注意を要する理由の一つです

Exposure RoutesOral (L277) ; inhalation (L277) ; dermal (L277)
Toxicity Summary · 1 件

Excess copper is sequestered within hepatocyte lysosomes, where it is complexed with metallothionein. Copper hepatotoxicity is believed to occur when the lysosomes become saturated and copper accumulates in the nucleus, causing nuclear damage. This damage is possibly a result of oxidative damage, including lipid peroxidation. Copper inhibits the sulfhydryl group enzymes such as glucose-6-phosphate 1-dehydrogenase, glutathione reductase, and paraoxonases, which protect the cell from free oxygen radicals. It also influences gene expression and is a co-factor for oxidative enzymes such as cytochrome C oxidase and lysyl oxidase. In addition, the oxidative stress induced by copper is thought to activate acid sphingomyelinase, which lead to the production of ceramide, an apoptotic signal, as well as cause hemolytic anemia. Copper-induced emesis results from stimulation of the vagus nerve. (L277, T49, A174, L280)

Signs and SymptomsBreathing high levels of copper can cause irritation of the nose and throat. Ingesting high levels of copper can cause nausea, vomiting, diarrhea, headache, dizziness, and respiratory difficulty. (L278, L279)
Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

安全データ

F
3-10
wgk
3
tsca
TSCA listed
ridadr
UN 3260 8/PG 3
PRTR法
第1種指定化学物質
hs_code
2826199090
risk_code
32-34-36/37/38-20/21/22
化審法
1-1067
hazard_code
C,Xi
hazard_note
Hygroscopic
safety_code
26-36/37/39-45-24/25-27-22
hazard_class
6.1
packing_group
III
ストレージクラス
8A - Combustible corrosive hazardous materials
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補足説明

定義The anhydrous form, CuF2, is also available.