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4-(ジメチルアミノ)-2-メチルアゾベンゼン

4-(Dimethylamino)-2-methylazobenzene

HCID 5916
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
54-88-6
標準SMILES
Cc1cc(N(C)C)ccc1N=Nc1ccccc1
InChIKey
QXTOLYZIJUDOIT-UHFFFAOYSA-N
分子式
C15H17N3
平均分子量
239.32 g/mol
単同位体質量
239.14224756

概要

2-methyl-4-dimethylaminoazobenzene is a red-orange crystalline solid. (NTP, 1992)

名称と識別子

優先名称
4-(Dimethylamino)-2-methylazobenzene
IUPAC
N,N,3-trimethyl-4-phenyldiazenylaniline
現地名
4-(ジメチルアミノ)-2-メチルアゾベンゼン
英語名
4-Dimethylamino-2-methylazobenzene
分子式
C15H17N3
分子量
239.32

名称と別名

54-88-62-Methyl-4-(dimethylamino)azobenzene4-(Dimethylamino)-2-methylazobenzene25Q2BUE0ASNSC-102372DTXSID0074845RefChem:1070103DTXCID00415614-Dimethylamino-2-methylazobenzene2-MeDAB2-Methyl-4-dimethylaminoazobenzeneN,N,3-Trimethyl-4-(phenyldiazenyl)aniline
名称をさらに表示
4-(ジメチルアミノ)-2-メチルアゾベンゼン2-メチルDABN,N,2-トリメチルアゾベンゼン-4-アミン4-ジメチルアミノ-2-メチルアゾベンゼン2-メチル-4-(ジメチルアミノ)アゾベンゼンN,N-ジメチル-4-フェニルアゾ-m-トルイジン2,N,N-トリメチルアゾベンゼン-4-アミン2-methyldab2METHYLDIMETHYLAMINOAZOBENZENE2,N,N-Trimethylazobenzen-4-amine4-dimethylamino-2-methyl-azobenzenN,N-DIMETHYL-4-(O-TOLYLAZO)ANILINEN,N,3-Trimethyl-4-(phenyldiazenyl)
2-Methyl-DAB2-Methyl-N,N-dimethyl-4-aminoazobenzeneN,N-Dimethyl-4-(phenylazo)-m-toluidine2,N,N-Trimethyl-4-aminoazobenzeneMFCD00008306Azobenzene, 4-dimethylamino-2-methyl-NSC 1023724-N,N-Dimethylamino-2-methylazobenzene

物性

構造計算による物性

XLogP
4.2
極性表面積
28 Ų
水素結合供与体数
0
水素結合受容体数
3
回転可能結合数
3
重原子数
18
形式電荷
0
複雑度
269

実験および物理化学的性質

Solubilityless than 1 mg/mL at 66 °F (NTP, 1992)
Physical Description2-methyl-4-dimethylaminoazobenzene is a red-orange crystalline solid. (NTP, 1992)

物理化学的性質

融点
67 · 67-69 °C(lit.)
沸点
150 °C · 150 °C / 16mmHg
比重(密度)
1.1092 · 1.1092 (rough estimate)
屈折率
1.561 · 1.5610 (estimate)
溶解性
溶解度 水にほとんど溶けません。エタノール、アセトンに可溶
外見
クリスタル
酸解離定数(Pka)
3.68 · 3.68(at 25℃)
色
赤いオレンジ
安定性
安定。強酸、強酸化剤とは相容れない。
主な用途
線虫駆除剤、アミロイド蓄積や肝発癌に関連する疾患の診断薬として
EPAの化学物質情報
2 · 2-Methyl-4-(dimethylamino)azobenzene (54-88-6)

化学的性質

化学的特性orange crystalline solid

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Warning

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P203, P264, P270, P273, P280, P301+P317, P318, P330, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Reactive GroupAmines, Phosphines, and Pyridines
Reactivity Profile · 1 件

2-METHYL-4-DIMETHYLAMINOAZOBENZENE is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.

Air and Water ReactionsDust can be explosive when suspended in air at specific concentrations. Insoluble in water.
Hazard Classes and CategoriesAcute Tox. 4 (100%)

安全と保護具

First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

化学と産業

応用分野

使用4-Dimethylamino-2-methylazobenzene is an azo dye. Dyes and metabolites.

一般的な説明Red-orange crystalline solid.

上流・下流製品情報

上流原料

N,N-ジメチル-m-トルイジンアニリン

サプライヤー27 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
郑州汇聚化工有限公司0371-53399770 18037166334 · [email protected]
杭州品高化工有限公司0571-87658025 · [email protected]
Aladdin Scientific[email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
安耐吉化学&3A(安徽泽升科技股份有限公司)400-0056266 · [email protected]
烟台盛凯伦生物制品有限公司13356901049 · [email protected]
玛雅试剂+86 (573) 82222445 (0)18006601000 452520369 · [email protected]
TCI AMERICA800-4238616 · [email protected]
TOKYO CHEMICAL INDUSTRY CO., LTD.

関連反応

0 件
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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート

データベース識別子

CAS
54-88-6
PubChem CID
5916
DTXSID
DTXSID0074845
UNII
25Q2BUE0AS
EC Number
200-217-2
Nikkaji
J2.800B
Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

安全データ

wgk
3
rtecs
XU5950000
hs_code
2927.00.5000
risk_code
22-40
hazard_code
Xn
safety_code
36/37
03-36680489 · [email protected]
TCI Europe320-37350700 · [email protected]
上海鑫圭生物科技有限公司15121041756 · [email protected]
九鼎化学(上海)科技有限公司4009209199 · [email protected]
上海阿拉丁生化科技股份有限公司6206333 13167063860 · [email protected]
上海颖心实验室设备有限公司021-021-59178156 15300768757 · [email protected]
烟台盛凯伦化学科技有限公司13356901049 · [email protected]
广州市金华大化学试剂有限公司020-84383047 · [email protected]
上海贤鼎生物科技有限公司021-021-52271985 17721149837 · [email protected]
安徽凯泽合联医药科技有限公司18130062233 · [email protected]
江苏艾康生物医药研发有限公司025-66113011 19370895928 · [email protected]
范德(北京)生物科技有限责任公司15911056312 · [email protected]
TCI Chemicals (India) Pvt. Ltd.[email protected]
陕西缔都医药化工有限公司029-029-029-81148696 18161915376 · [email protected]
北京百灵威科技有限公司18210857532 18210857532 · [email protected]
HANGZHOU LEAP CHEM CO., LTD.+86-571-87711850 +8619957148339 · [email protected]
陕西缔都医药化工有限公司+86-29-87569266 +86-17392581500 · [email protected]
上海鼓臣生物技术有限公司021-34675735 19147740836 · [email protected]