ビス(10H-フェノキサルシン-10-イル)エーテル

ビナジン · 10,10'-オキシジ(10H-フェノキサルシン) · ビス(10H-フェノキサルシン-10-イル)エーテル · 10,10'-オキシビス(10H-フェノキサルシン) · ビニゼン · バイナジン · バイナジンSB · 10-(10H-フェノキサルシニン-10-イルオキシ)-10H-フェノキサルシニン

https://huagongshe.com/ja/chemical/6017

識別子と物理属性

CAS No.	58-36-6
分子式	C24H16As2O3
平均分子量	502.2 g/mol
単同位体質量	501.95313737 g/mol
SMILES	c1ccc2c(c1)Oc1ccccc1[As]2O[As]1c2ccccc2Oc2ccccc21
InChIKey	VCRZAKVGPJFABU-UHFFFAOYSA-N
PubChem CID	6017
EC No.	200-377-3
DTXSID	DTXSID0032443
現地名	ビス(10H-フェノキサルシン-10-イル)エーテル

化学・物理的性質

極性表面積	27.7
水素結合供与体数	0
水素結合受容体数	3
回転可能結合数	2
重原子数	29
形式電荷	0
複雑度	482
物質分類	Metals -> Arsenic Compounds, Organic
密度	1.40-1.42 @25 °C
融点	363 to 365 °F (EPA, 1998)180-184°C
蒸気圧	0.00001 [mm Hg] @25 °C
Physical Description	Phenoxarsine, 10,10'-oxydi- appears as a clear light yellow liquid with a mild odor. Insoluble in water and slightly denser than water. Contact may severely irritate skin, eyes, and mucous membranes.Colorless solid[Merck Index] White crystalline solid[MSDSonline]
沸点	232.5°C
貯蔵条件	Sealed in dry,Room Temperature
外観・状態	個体
色	無色または白色の結晶、EtOH または 2-プロパノールからの単斜晶プリズム
溶解度	不溶性
InChI	InChI=1S/C24H16As2O3/c1-5-13-21-17(9-1)25(18-10-2-6-14-22(18)27-21)29-26-19-11-3-7-15-23(19)28-24-16-8-4-12-20(24)26/h1-16H
InChIKey	VCRZAKVGPJFABU-UHFFFAOYSA-N
SMILES	O([As]1C2=CC=CC=C2OC2=C1C=CC=C2)[As]1C2=CC=CC=C2OC2=C1C=CC=C2
CAS データベース	58-36-6(CAS DataBase Reference)
EPAの化学物質情報	10,10'-Oxybisphenoxarsine (58-36-6)

化学的特性

10-10′-Oxidiphenoxarsine is a colorless crystalline, organometallic solid or a dense yellow liquid. Odorless.

安全性と法規制

GHS 分類	DangerH300 (73.4%): Fatal if swallowed [Danger Acute toxicity, oral]P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P330, P361+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 94 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
規制情報	Chemical: 10H-Phenoxarsine, 10,10'-oxybis-Restricted substance: Diphenoxarsin-10-yl oxide10H-Phenoxarsine, 10,10'-oxybis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
輸送ラベル（DOT）	Corrosive
火災危険	(Non-Specific -- Arsenic Compounds) When heated to decomposition, it emits highly toxic fumes of arsenic. (EPA, 1998)
健康有害性	(Non-Specific -- Arsenic Compounds) Arsenic compounds are acutely poisonous by ingestion. Ingestion or inhalation may result in chronic poisoning. Arsenic compounds are recognized carcinogens of the skin, lungs, and liver. (EPA, 1998)
有害性の概要	Severely irritating to skinToxic by ingestion and inhalationOral LD50 (rat) = 40 mg/kg[Sax] Retards growth and causes liver effects in high-dose feeding studiesNo developmental, reproductive, or mutagenic effectsArsenic accumulates in liver and kidneys of exposed animals with clearing 2 weeks after last exposureThe potential for occupational exposure to OBPA is minimal provided that OBPA is used in a closed system and that appropriate Personal Protective Equipment (PPE) is worn. [EPA REDs] An irritant that can cause skin burnsMay be lethal if ingested or inhaledMay cause liver and kidney damage[MSDSonline] Almost nothing is known regarding health effects of organic arsenic compounds in humans. Studies in animals show that some simple organic arsenic compounds are less toxic than inorganic forms. Ingestion of methyl and dimethyl compounds can cause diarrhea and damage to the kidneys. [ATSDR ToxProfiles]

用途

一般的な説明

A clear light yellow liquid with a mild odor. Insoluble in water and slightly denser than water. Contact may severely irritate skin, eyes, and mucous membranes. Flash point 98°F.