基本情報
- CAS
12071-83-9- 標準SMILES
CC(CNC(=S)[S-])NC(=S)[S-].[Zn+2]- InChIKey
KKMLIVYBGSAJPM-UHFFFAOYSA-L- 分子式
- C5H8N2S4Zn
- 平均分子量
- 289.8 g/mol
- 単同位体質量
- 287.886175
概要
Propineb is a polymeric complex of zinc with the propylene 1,2-bis(dithiocarbamate) anionic ligand. A fungicide, it is used to control a wide range of fungal diseases, including downy mildew, brown rot, black rot, red fire, leaf spot, and blight in crops such as grapes, tomatoes, potatoes, berries, citrus, rice and tea. It has a role as an antifungal agrochemical. It is a macromolecule, a zinc coordination entity and a dithiocarbamate salt. It contains a propylene 1,2-bis(dithiocarbamate).
名称と識別子
- 優先名称
- Propineb
- IUPAC
- zinc N-[1-(sulfidocarbothioylamino)propan-2-yl]carbamodithioate
- 現地名
- 1-メチルエチレンビス(ジチオカルバミド酸)亜鉛
- 英語名
- Propineb
- 分子式
- C5H10N2S4
- 分子量
- 226.41
名称と別名
PropinebAntracol12071-83-9MethylzinebMezinebPropinebeAironeTaifenBayer 46131DTXSID1052741Zinc propylene bisdithiocarbamateBAY 46131
名称をさらに表示
メチルジネブ1-メチルエチレンビス(ジチオカルバミド酸)亜鉛メジネブアントラコールアントラコール70プロピアントラコールNMシプロマートLC(1-メチル-1,2-エタンジイル)ビス(ジチオカルバミド酸)亜鉛プロピネブプロピネブ標準品N,N'-プロピレンビス(ジチオカルバミン酸)と亜鉛の重合物 (別名 プロピネブ)プロビネブプロピネブ (ジカルバメート)6-メチル-1,3-ジチア-5,8-ジアザ-2-ジンカシクロノナン-4,9-ジチオンメジネブ標準品N,N '-ﾌﾟﾛﾋﾟﾚﾝﾋﾞｽ(ｼﾞﾁｵｶﾙﾊﾞﾐﾝ酸)と亜鉛の重 合物(1-methyl-1,2-ethanediyl)bis-carbamodithioic acid zinc complexlh30/zlh3012KORUNEBENERCOLAGROCOL
Zinc 1,2-propylene bisdithiocarbamatePropylenebis(dithiocarbamato)zincBAYER-46131CHEBI:81755003VPM353KB-5078propynebTsipromat
物性
構造計算による物性
- 極性表面積
- 90.2 Ų
- 水素結合供与体数
- 2
- 水素結合受容体数
- 4
- 回転可能結合数
- 3
- 重原子数
- 12
- 形式電荷
- 0
- 複雑度
- 148
実験および物理化学的性質
Pesticides
Fungicides
Active substance -> EU Pesticides database: Not approved
Pesticides -> Dithiocarbamates (Pesticide)
Endocrine DisruptorsPotential endocrine disrupting compound
Vapor Pressure0.0000016 [mmHg]
Physical DescriptionWhite to yellowish solid; [Merck Index] Yellow solid; [MSDSonline]
物理化学的性質
- 融点
- 157 · 157-159°C
- 貯蔵温度
- 0 · 0-6°C
- 溶解性
- DMSO（微加熱）
- 外見
- 個体
- 色
- オフホワイトからライトベージュ
- Merck
- 13 · 13,7911
- 主な用途
- 農業環境
- InChI
- 1S/C5H10N2S4.Zn/c1-3(7-5(10)11)2-6-4(8)9;/h3H,2H2,1H3,(H2,6,8,9)(H2,7,10,11);/q;+2/p-2
- InChIKey
- KKMLIVYBGSAJPM-UHFFFAOYSA-L
- SMILES
- CC1CNC(=S)S[Zn]SC(=S)N1
- CAS データベース
- 12071 · 12071-83-9(CAS DataBase Reference)
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Warning
H317: May cause an allergic skin reaction [Warning Sensitization, Skin]
P260, P261, P271, P272, P273, P280, P302+P352, P304+P340, P317, P319, P321, P333+P317, P362+P364, P391, and P501 (click each P-code to see the statement)
Not Classified
Aggregated GHS information provided per 43 reports by companies from 4 notifications to the ECHA C&L Inventory.
Warning
危険有害性情報
Regulatory Information
Chemical: Zinc, [[(1-methyl-1,2-ethanediyl)bis(carbamodithioato)](2-)]-, homopolymer
Commission Regulation No 844/2012
03/39/EC, Reg. (EU) 2016/2016, Reg. (EU) 2018/309, Reg. (EU) No 540/2011, Reg. (EU) No 823/2012, Reg.(EU) No 84/2018
REACH registered substance: Zinc, [[(1-methyl-1,2-ethanediyl)bis[carbamodithioato]](2-)]-, homopolymer (EC: 620-365-5)
Propineb: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Hazards Summary
Skin sensitization reported in a farmworker; [Kanerva, p. 1847] Non-irritating to skin or eyes of rabbits; Sensitizing in guinea pig maximization test, but not sensitizing in Buehler test on guinea pigs; [IUCLID] Has goitrogenic effect in rats, but effect not reported in rabbits or dogs; Dogs fed 75 mg/kg for 2 years had no adverse effects; No reports of skin sensitization in humans; Unlikely to present acute hazard in normal use. [WHO-JMPR] May cause irritation; [MSDSonline]
Hazard Classes and Categories
Not Classified
Skin Sens. 1 (100%)
Acute toxicity - category 4
Skin sensitization - Category 1
Carcinogenicity - Category 1B
Acute Tox. 4 *
毒性情報
化学と産業
用途と製造
Uses
Used as an agricultural fungicide; [Merck Index]
Farming (Pesticides) [Category: Industry]
応用分野
使用Propineb is a dithiocarbamate compound, which is used as a fungicide. Sensitization was reported in an agricultural worker.
サプライヤー74 社
阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖南韵邦生物科技股份有限公司0731-88532326 13319508186 · [email protected]
湖北威德利化学试剂有限公司186-02735115 18062128043 · [email protected]
湖北科麦迪化工有限公司18372743325 · [email protected]
武汉欣扬瑞和化学科技有限公司13720274133 · [email protected]
广州佳途科技股份有限公司81960175-877 18933936954 · [email protected]
河南赢创生物科技有限公司16650615803 · [email protected]
Qingdao Trust Agri Chemical Co.,Ltd+86-008615963231493 +86-008613573296305 · [email protected]
梯希爱（上海）化工贸易有限公司021-61109150 · [email protected]
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