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クロロ（メチル）シラン

(Chlorosilyl)methane

HCID 61244
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
993-00-0
標準SMILES
C[SiH2]Cl
InChIKey
YGZSVWMBUCGDCV-UHFFFAOYSA-N
分子式
CH5ClSi
平均分子量
80.59 g/mol
単同位体質量
79.9849044

概要

Methyl chlorosilane is a colorless gas with a distinctive odor. It is insoluble in water. Its vapors are heavier than air. Contact with the material causes severe irritation to skin, eyes, and mucous membranes. It is toxic by ingestion and skin absorption. It is also a dangerous fire risk. It is used to make water repellent materials. Prolonged exposure of container to fire or intense heat may result in their violent rupturing and rocketing.

名称と識別子

優先名称
(Chlorosilyl)methane
IUPAC
chloro(methyl)silane
現地名
クロロ（メチル）シラン
英語名
Chloromethyl silane
分子式
CH5ClSi
分子量
80.59

名称と別名

(CHLOROSILYL)METHANERefChem:1050834DTXCID90818510213-600-4993-00-0Chloro(methyl)silaneDTXSID00870821MethylchlorosilanePAH66FWC6LSCHEMBL22226SCHEMBL28604445NS00126910
名称をさらに表示
クロロ（メチル）シランメチルクロロシランUn2534Einecs 213-600-4Chloromethyl silaneSilane, chloromethyl-Methylchlorosilane,mixed monomerMethylchlorosilane Mixed MonomersSilane, chloromethyl-(6CI,7CI,8CI,9CI)Chloromethyl silane ISO 9001：2015 REACHMethylchlorosilane [un2534] [poison gas]

データベース識別子

CAS
993-00-0
PubChem CID
61244
DTXSID
DTXSID00870821
EC Number
213-600-4

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
0
重原子数
3
形式電荷
0
複雑度
4.8

実験および物理化学的性質

Chemical ClassesCorrosives
SpringerMaterials PropertiesSchoenflies notation
SolubilitySolubility in water: reaction
Flash Point-9 °C
Boiling Point-45 °C @760 [mm Hg]
Melting Point-135 °C
Vapor PressureVapor pressure, kPa at 20 °C: 18.3
Physical Description · 2 件

Methyl chlorosilane is a colorless gas with a distinctive odor. It is insoluble in water. Its vapors are heavier than air. Contact with the material causes severe irritation to skin, eyes, and mucous membranes. It is toxic by ingestion and skin absorption. It is also a dangerous fire risk. It is used to make water repellent materials. Prolonged exposure of container to fire or intense heat may result in their violent rupturing and rocketing.

COLOURLESS LIQUID.

物理化学的性質

融点
-134.1 °C · -134.1°C
沸点
8.7 °C · 8.7°C (estimate)

安全と法規制

安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Danger

H220 (100%): Extremely flammable gas [Danger Flammable gases]

P203, P210, P222, P231+P232, P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P377, P381, P402+P404, P403, P405, P410+P403, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 49 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazards IdentificationToxic/poison by inhalation (TIH/PIH)
Regulatory Information · 2 件

REACH registered substance: Chloro(methyl)silane (EC: 213-600-4)

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelPoison Gas Flammable Gas Corrosive
Fire Hazards · 3 件

Excerpt from ERG Guide 119 [Gases - Toxic - Flammable]:

· Flammable; may be ignited by heat, sparks or flames.

Extremely flammable.

Health Hazards · 2 件

Excerpt from ERG Guide 119 [Gases - Toxic - Flammable]:

· TOXIC; may be fatal if inhaled or absorbed through skin. Some may cause severe skin burns and eye damage.

DOT ID and Guide2534 119
Reactive GroupChlorosilanes
UN ClassificationUN Hazard Class: 2.3; UN Subsidiary Risks: 2.1 and 8

化学と産業

応用分野 · 1 件

一般的な説明Methyl chlorosilane is a colorless gas with a distinctive odor. Chloromethyl silane is insoluble in water. Its vapors are heavier than air. Contact with the material causes severe irritation to skin, eyes, and mucous membranes. Chloromethyl silane is toxic by ingestion and skin absorption. Chloromethyl silane is also a dangerous fire risk. Chloromethyl silane is used to make water repellent materials. Prolonged exposure of container to fire or intense heat may result in their violent rupturing and rocketing.

上流・下流製品情報

上流原料

亜鉛 (粉末)銅(I)クロリドクロロメタン

下流製品

クロロトリメチルシラントリアセトキシメチルシランジクロロメチルシランメチルシランクロロジメチルシラン

サプライヤー7 社

湖南省华中特种气体有限公司0734-8755555 15674722888 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]

関連反応

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反応記録を作成

現在のフィルター条件では反応記録がありません。

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
比重(密度)
0.884 · 0.8840
外見
液体
EPAの化学物質情報
Methylchlorosilane (993-00-0)
Reactivity AlertsHighly Flammable
Reactivity Profile · 1 件

Chlorosilanes, such as METHYLCHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.

Chemical Dangers · 1 件

Decomposes on contact with hot surfaces or flames. This produces toxic and corrosive fumes including hydrogen chloride and phosgene. Decomposes on contact with bases. This produces flammable/explosive gas (hydrogen - see ICSC 0001). Reacts violently with oxidants. Reacts violently with water. This produces hydrogen chloride (see ICSC 0163). Attacks many metals in the presence of water.

DOT Hazard Classification · 4 件

Methylchlorosilane

UN2534

Div 2.3 Poisonous gas (49 eCFR § 173.115)

Div 2.3 Poisonous gas (49 eCFR § 173.115)

安全と保護具

Fire Fighting · 2 件

Excerpt from ERG Guide 119 [Gases - Toxic - Flammable]:

Use alcohol-resistant foam, dry powder, carbon dioxide. NO water.

First Aid Measures · 4 件

Fresh air, rest. Half-upright position. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Do NOT induce vomiting. Refer for medical attention .

Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 件

Excerpt from ERG Guide 119 [Gases - Toxic - Flammable]:

General First Aid:

Safe StorageFireproof. Ventilation along the floor. Cool. Dry. Store in an area without drain or sewer access.
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 119 [Gases - Toxic - Flammable]:
Spillage Disposal · 1 件

Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.

Isolation and Evacuation · 4 件

Excerpt from ERG Guide 119 [Gases - Toxic - Flammable]:

Immediate precautionary measure

Small spill:

Small spill:

Eye PreventionWear safety goggles or eye protection in combination with breathing protection. Wear face shield.
Fire PreventionNO open flames, NO sparks and NO smoking.
Inhalation RiskA harmful contamination of the air will be reached very quickly on evaporation of this substance at 20 °C.

毒性情報

Exposure RoutesThe substance can be absorbed into the body by inhalation.
Signs and Symptoms · 4 件

Burning sensation. Cough. Laboured breathing. Shortness of breath. Sore throat. Symptoms may be delayed.

Redness. Pain. Skin burns.

Pain. Redness. Severe deep burns.

Abdominal pain. Burning sensation. Shock or collapse.

法規制情報

DHS Chemicals of Interest (COI) · 4 件

Methylchlorosilane

20

45

Weapons of Mass Effect chemical material that, if stolen or diverted, can be converted into weapons using simple chemistry, equipment, or techniques.

安全データ

ridadr
UN 2534
hazard_class
2.3
PT CHEM GROUP LIMITED+86-85511178; +86-85511178 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
上海宝杨宝欣生物科技有限公司021-56698539 19921169802 · [email protected]
Dideu Industries Group Limited+86-29-81148696 +86-15129568250 · [email protected]
補足説明 · 1 件

定義One of several intermediates in the formation of silicones or siloxanes, they react with hydroxyl groups on many types of surfaces to produce a permanent, thin-surface film of silicone that imparts water repellency. Examples are methyltrichlorosilane, dimethyldichlorosilane, and trimethylchlorosilane.