Sudan Black B (HCID 61336)

概要

Sudan black B is a member of the class of perimidines that is 2,2-dimethyl-2,3-dihydro-1H-perimidine carrying a [4-(phenyldiazenyl)naphthalen-1-yl]diazenyl substituent at position 6. A fat-soluble dye predominantly used for demonstrating triglycerides in frozen sections and for staining of protein bound lipids in paraffin sections. It has a role as a histological dye. It is a member of azobenzenes, a member of perimidines and a bis(azo) compound.

名称と識別子

優先名称: Sudan Black B
IUPAC: (2,2-dimethyl-1,3-dihydroperimidin-6-yl)-(4-phenyldiazenylnaphthalen-1-yl)diazene
現地名: ズダンブラック B
英語名: Solvent Black 3
分子式: C29H24N6
分子量: 456.54

名称と別名

Sudan black B4197-25-5Fat Black HBC.I. Solvent Black 3Ceres Black BNFast Black HBTypogen BlackLacquer Black SNubian Black BTHexatype Black BLacquer Black VBFast Black HBN

名称をさらに表示

ズダンブラック B2,3-ジヒドロ-2,2-ジメチル-6-[4-(フェニルアゾ)-1-ナフチルアゾ]-1H-ペリミジンオイルブラックBT6-[4-(フェニルアゾ)ナフタレン-1-イルアゾ]-2,3-ジヒドロ-2,2-ジメチル-1H-ペリミジン2,3-ジヒドロ-2,2-ジメチル-6-[[4-(フェニルアゾ)-1-ナフチル]アゾ]-1H-ペリミジン2,3-ジヒドロ-2,2-ジメチル-6-[[4-(フェニルアゾ)ナフタレン-1-イル]アゾ]-1H-ペリミジンセレスブラックBNスーダンブラックC.I.ソルベントブラック3スダンブラックBスダンブラックスーダンブラックBN,N'-イソプロピリデン-4-[4-(フェニルアゾ)-1-ナフチルアゾ]-1,8-ナフタレンジアミンスダンブラック Bソルベントブラック3ズダンブラックBスダンブラック BズダンブラックB標準品CI 26150Nsc 11239Black 2Bsot-black6BSudan BlaSudanblack199664-25GCI NO 26150typogenblack

Sudan Deep Black BBSudan Deep Black BNC.I. 26150Aizen SOT Black 6Sudan Black X 60Fat Black HB 01Neptune Black X 60DTXSID0052091

データベース識別子

CAS: 4197-25-5
PubChem CID: 61336
DTXSID: DTXSID0052091
ChEMBL: CHEMBL1872445
ChEBI: CHEBI:88216
UNII: 9YDL1Q990E
EC Number: 224-087-1
Nikkaji: J34.104E

物性

構造計算による物性

XLogP: 8.4
極性表面積: 73.5 Å²
水素結合供与体数: 2
水素結合受容体数: 6
回転可能結合数: 4
重原子数: 35
形式電荷: 0
複雑度: 773

実験および物理化学的性質

Chemical ClassesDyes -> Azo Dyes

CosmeticsHair dyeing

Physical DescriptionPowder; [Sigma-Aldrich MSDS]

物理化学的性質

融点: 120 · 120-124 °C(lit.)
沸点: 552.68 °C · 552.68°C (rough estimate)
比重(密度): 1.4899 · 1.4899 (rough estimate)
屈折率: 1.457 · 1.4570 (estimate)
貯蔵温度: Store at RT.
溶解性: 水に不溶、エタノール、アセトン、ベンゼン、トルエン、キシレン、エチレングリコールに可溶
酸解離定数(Pka): 2.94 · 2.94±0.40(Predicted)
外見: 粉体・固形
色: 非常に濃い茶色から黒
水溶解度: 油、脂肪、温ワセリン、パラフィン、フェノール、エタノール、アセトン、ベンゼン、トルエン、炭化水素に可溶。水に溶けません。
Merck: 13 · 13,8970
BRN: 723248 · 723248
安定性: 光に敏感
主な用途: 診断アッセイの製造血液学組織学
化粧品成分の機能: ヘアカラーリング
InChI: 1S/C29H24N6/c1-29(2)30-26-14-8-13-22-25(17-18-27(31-29)28(22)26)35-34-24-16-15-23(20-11-6-7-12-21(20)24)33-32-19-9-4-3-5-10-19/h3-18,30-31H,1-2H3/b33-32+,35-34+
InChIKey: YCUVUDODLRLVIC-VPHDGDOJSA-N
SMILES: CC1(C)Nc2cccc3c(ccc(N1)c23)\N=N\c4ccc(\N=N\c5ccccc5)c6ccccc46
CAS データベース: 4197 · 4197-25-5(CAS DataBase Reference)
EPAの化学物質情報: 3 · C.I. Solvent Black 3 (4197-25-5)

化学的性質 · 1 件

化学的特性It is a very dark brown to black fine crystalline powder. It is soluble in ethanol, toluene, acetone, and other solvents. In concentrated sulfuric acid, it is violet-black; when diluted, it is dark greenish-blue and produces a blue to black precipitate. The ethanol solution of the dye is bluish-black when concentrated hydrochloric acid is added and dark blue when concentrated sodium hydroxide solution is added.

安全と法規制

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 8.2% (182 of 2225) of reports.

Warning

H341 (90.7%): Suspected of causing genetic defects [Warning Germ cell mutagenicity]

P203, P280, P318, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 2225 reports by companies from 6 notifications to the ECHA C&L Inventory.

危険有害性情報

Regulatory Information · 2 件

Chemical: 1H-Perimidine, 2,3-dihydro-2,2-dimethyl-6-[[4-(phenylazo)-1-naphthalenyl]azo]-

1H-Perimidine, 2,3-dihydro-2,2-dimethyl-6-4-(phenylazo)-1-naphthalenylazo-: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryIntravenous LD50 (mouse) = 63 mg/kg; [RTECS] May cause irritation; [Sigma-Aldrich MSDS]

Hazard Classes and CategoriesMuta. 2 (90.7%)

安全データ

wgk: 3
tsca: TSCA listed
rtecs: SD4431500
毒性: LD50 ivn-mus: 63 mg/kg CSLNX* NX#04918
hs_code: 32041900
risk_code: 11-36/37/38
化審法: (5)-3141
hazard_code: F,Xi
safety_code: 24/25-16-37/39-26
hazard_class: IRRITANT
Hazard Classifications: Muta. 2
ストレージクラス: 11 - Combustible Solids

化学と産業

薬理情報

MeSH Pharmacological ClassificationChemicals and substances that impart color including soluble dyes and insoluble pigments. They are used in INKS; PAINTS; and as INDICATORS AND REAGENTS.

用途と製造

Uses · 1 件

Composed of 2 major blue components, SBB-I and SBB-II (defined by this CAS# and name), and at least 12 minor components; Used as a biological stain for lipids; [Merck Index] Permitted for use as an inert ingredient in non-food pesticide products; [EPA]

Use ClassificationCosmetics -> Hair dyeing

General Manufacturing Information1H-Perimidine, 2,3-dihydro-2,2-dimethyl-6-[2-[4-(2-phenyldiazenyl)-1-naphthalenyl]diazenyl]-: ACTIVE

応用分野

使用Sudan Black is a basic black dye that is used in staining triglycerides and lipids off some lipoproteins. Biological stain. Dyes and metabolites, Environmental Testing.

調製方法

製造方法aniline diazotization, and Naphthalen-1-amine coupling, and its product to diazotization, and 2,2-Dimethyl-2,3-dihydro-1H-perimidinecoupling.

上流・下流製品情報

上流原料

1-ナフチルアミンアニリン 1-ナフチルアミン 2,2-dimethyl-2,3-dihydro-1H-perimidine

サプライヤー50 社

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]

上海康朗生物科技有限公司021-61998208 18217752821 · [email protected]

補足説明 · 1 件

定義ChEBI: Sudan black B is a member of the class of perimidines that is 2,2-dimethyl-2,3-dihydro-1H-perimidine carrying a [4-(phenyldiazenyl)naphthalen-1-yl]diazenyl substituent at position 6. A fat-soluble dye predominantly used for demonstrating triglycerides in frozen sections and for staining of protein bound lipids in paraffin sections. It has a role as a histological dye. It is a member of azobenzenes, a bis(azo) compound and a member of perimidines.

ズダンブラック B

基本情報

概要