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二酢酸コバルト(II)·4水和物
二酢酸コバルト(II)·4水和物 · 二酢酸コバルト(II)·四水和物 · 酢酸コバルト四水和物 · 酢酸コバルト(II)四水和物 · 酢酸コバルト(Ⅱ)四水和物 · 酢酸コバルト（II）?四水和物 · 酢酸コバルト(Ⅱ)?四水和物 · 酢酸コバルト(II)四水和物 ACS REAGENT,≥98.0%
識別子と物理属性
| CAS No. | 6147-53-1 |
|---|---|
| 分子式 | C4H6CoO4.4H2O |
| 平均分子量 | 249.08 g/mol |
| 単同位体質量 | 249.00206241 g/mol |
| SMILES | CC(=O)[O-].CC(=O)[O-].O.O.O.O.[Co+2] |
| InChIKey | ZBYYWKJVSFHYJL-UHFFFAOYSA-L |
| PubChem CID | 61372 |
| EC No. | 612-153-6 |
| DTXSID | DTXSID80210423 |
| 現地名 | 二酢酸コバルト(II)·4水和物 |
化学・物理的性質
| 極性表面積 | 84.3 |
|---|---|
| 水素結合供与体数 | 4 |
| 水素結合受容体数 | 8 |
| 回転可能結合数 | 0 |
| 重原子数 | 13 |
| 形式電荷 | 0 |
| 複雑度 | 25.5 |
| 物質分類 | Metals -> Organic Acids, Metal Salts |
| 密度 | 1.7 g/cm³1,71 g/cm3 |
| 溶解度 | Solubility in water, g/100ml at 25 °C: (very good)348g/リットル380g/L(20℃) |
| 融点 | 140 °C |
| Physical Description | Dry PowderIntense red solid[Merck Index] Violet crystals, soluble in water[MSDSonline] Delliquescent[Ullmann]RED CRYSTALS. |
| 屈折率 | 1.542 |
| 貯蔵条件 | Store at +5°C to +30°C. |
| 外観・状態 | 個体 |
| 色 | 赤 |
| 比重 | 1.71 |
| 臭い | 酢酸臭 |
| pH | 7.2 (50g/l, H2O, 20℃) |
| Merck | 14,2433 |
| BRN | 3731397 |
| 安定性 | 安定。湿気、熱を避けてください。 |
| InChI | 1S/2C2H4O2.Co.4H2O/c2*1-2(3)4/h2*1H3,(H,3,4)4*1H2/q+2/p-2 |
| InChIKey | ZBYYWKJVSFHYJL-UHFFFAOYSA-L |
| SMILES | [H]O[H].[H]O[H].[H]O[H].[H]O[H].CC(=O)O[Co]OC(C)=O |
| CAS データベース | 6147-53-1(CAS DataBase Reference) |
| EPAの化学物質情報 | Cobalt acetate tetrahydrate (6147-53-1) |
化学的特性
Reddish violet deliequecent crystals.
安全性と法規制
| GHS 分類 | DangerH317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]P203, P233, P260, P261, P271, P272, P273, P280, P284, P302+P352, P304+P340, P318, P321, P333+P317, P342+P316, P362+P364, P391, P403, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 2209 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.H350: May cause cancer [Danger Carcinogenicity] |
|---|---|
| 規制情報 | Chemical: Acetic acid, cobalt(2+) salt, tetrahydrateRegulation (EC) No 1831/2003 (amended)Acetic acid, cobalt(2+) salt, hydrate (2:1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Acetic acid, cobalt(2+) salt, hydrate (2:1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Cobalt (II) acetate tetrahydrate: Does not have an individual approval but may be used under an appropriate group standard |
| その他の安全情報 | IMAP assessments - Soluble cobalt (II) and salts: Human health tier II assessment |
| 火災危険 | Not combustible. Gives off irritating or toxic fumes (or gases) in a fire. |
| 有害性の概要 | A skin, eye, and respiratory tract irritantMay cause skin sensitization[ICSC] Harmful if swallowedMay cause skin and respiratory tract sensitization[MSDSonline] See Cobalt. |
| Chemical Dangers | Decomposes on heating. This produces irritating fumes. Reacts with strong oxidants. This generates fire and explosion hazard. |
| Packaging and Labelling | Do not transport with food and feedstuffs. |
| Hazard Classes and Categories | Skin Sens. 1 (100%)Acute toxicity - category 4Acute toxicity (Oral) - Category 4Carcinogenicity - Category 1B |
| 消火 | In case of fire in the surroundings, use appropriate extinguishing media. |
| 応急処置措置 | Fresh air, rest. Refer for medical attention.Remove contaminated clothes. Rinse skin with plenty of water or shower. Seek medical attention if you feel unwell.First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention . |
| 安全保管 | Separated from strong oxidants. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing. |
| 暴露管理・個人防護 | Biological Exposure Indices (BEI) [ACGIH] - Cobalt in urine = 15 ug/Lsample at end of shift at end of workweek |
| 漏出処分 | Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Then store and dispose of according to local regulations. |
| Eye Prevention | Wear safety goggles or eye protection in combination with breathing protection. |
| Inhalation Risk | A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered. |
| Skin Prevention | Protective gloves. Protective clothing. |
| Exposure Prevention | PREVENT DISPERSION OF DUST! AVOID ALL CONTACT! |
| Ingestion Prevention | Do not eat, drink, or smoke during work. Wash hands before eating. |
| Inhalation Prevention | Use local exhaust or breathing protection. |
| Threshold Limit Values (TLV) | 0.02 [mg/m3], as Co |
| 有害作用 | Skin Sensitizer - An agent that can induce an allergic reaction in the skin. |
| 暴露経路 | The substance can be absorbed into the body by inhalation and by ingestion. |
| Signs and Symptoms | Cough. Shortness of breath. Sore throat.Redness.Redness. Pain.Abdominal pain. Nausea. Vomiting. |
| ICSC Environmental Data | Bioaccumulation of this chemical may occur in seafood. |
| 水環境危害等級（WGK） | 2 |
| TSCA 収載状態 | No |
| RTECS 番号 | AG3325000 |
| 輸送番号（UN） | 3077 |
| PRTR法 | 1-132 |
| 税関コード | 29152300 |
| 危険文句（R） | 22-38-40-43-53-50/53-42/43-36/37/38-20/21/22-68-60-49 |
| 安衛法 | 特定化学物質障害予防規則:第2類物質,57,57-2 |
| 危険表示 | Xn,N,T |
| 安全措置（S） | 36/37-61-45-29-24-22-37/39-36/37/39-26-60-53 |
| 危険等級 | 9Acute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Carc. 1B InhalationEye Irrit. 2Muta. 2Repr. 1BResp. Sens. 1Skin Sens. 1 |
| 包装等級 | III |
| 貯蔵分類 | 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects |
用途
用途
ワニス塗料乾燥剤,ワニス原料,陶器顔料,液相酸化触媒,アルミニウム表面処理剤,医薬中間体 (NITE CHRIP)
用途
塗料の乾燥剤、ワニスの原料
用途
油溶性コバルト塩、触媒、医薬原料、顔料。
使用
Cobalt(II) acetate tetrahydrate is used to prepare complexes for examination of the properties of metals with unusual coordination geometries. used as a catalyst for oxidation and esterification. used as an industrial catalyst to harden paints and varnishes, an active catalyst for oxidation and esterification reactions.
一般的な説明
Cobalt(II) acetate tetrahydrate has an octahedral structure, the central cobalt orbit is coordinated by four water molecules and two acetate ligands. Cobalt(II) acetate tetrahydrate becomes anhydrous by 140oC.
製法・合成法
純化方法
Several recrystallisations from 50% aqueous acetic acid give the tetrahydrate. It is converted to the anhydrous salt by drying at 80o/1mm for 60hours. [Beilstein 2 IV 120.]