基本情報
- CAS
10026-06-9- 標準SMILES
O.O.O.O.O.[Cl][Sn]([Cl])([Cl])[Cl]- InChIKey
KHMOASUYFVRATF-UHFFFAOYSA-J- 分子式
- Cl4Sn.5H2O
- 平均分子量
- 350.6 g/mol
- 単同位体質量
- 349.83042884
概要
Stannic chloride pentahydrate is a white colored solid. It is soluble in water. It is toxic by ingestion, inhalation and skin absorption. It is used to make perfumes and dyes.
名称と識別子
- 優先名称
- Stannic chloride pentahydrate
- IUPAC
- tetrachlorostannane;pentahydrate
- 現地名
- 化スズ（ＩＶ）5水
- 英語名
- Tin(IV) chloride
- 分子式
- Cl4H2OSn
- 分子量
- 278.53
名称と別名
Tin(IV) chloride pentahydrateStannic chloride pentahydrateStannane, tetrachloro-, pentahydrateTetrachlorostannane pentahydrateUN2440Stannic chloride, pentahydrateDTXSID6074413TIN TETRACHLORIDE, (HYDRATED)TIN TETRACHLORIDE, [HYDRATED]Tin chloride (SnCl4), pentahydrateRefChem:888978DTXCID0032493
名称をさらに表示
化スズ（ＩＶ）5水塩化スズ（ＩＶ）５水塩四塩化すず五水和物塩化すず(IV)五水和物塩化スズ(Ⅳ）塩化すず(Ⅳ)五水和物塩化スズ（IV）?五水和物塩化すず(IV)五水和物(塩化第二すず五水和物)塩化スズ(IV)五水和塩化すず(Ⅳ)(5水和物)〔第二〕塩化第二すず五水和物塩化すず(IV) 五水和物塩化すず( Ⅳ) 五水和物塩化すず(IV)五水和物, 98%TIN(IV) CHLORIDETin(IV) chloride hydrateOlovo Stanicoride pentahydrate4-(289-Butyl)phenolStannic chloride hydSTANNIC CHLORIDE 5H2O
Stannane, tetrachloro, pentahydrateTIN TETRACHLORIDE, PENTAHYDRATESTANNIC TETRACHLORIDE PENTAHYDRATE600-048-810026-06-9Tin chloride pentahydratetin (IV) chloride pentahydratetetrachlorostannane;pentahydrate
物性
構造計算による物性
- 極性表面積
- 5 Ų
- 水素結合供与体数
- 5
- 水素結合受容体数
- 5
- 回転可能結合数
- 0
- 重原子数
- 10
- 形式電荷
- 0
- 複雑度
- 19.1
実験および物理化学的性質
Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical Description
Stannic chloride pentahydrate is a white colored solid. It is soluble in water. It is toxic by ingestion, inhalation and skin absorption. It is used to make perfumes and dyes.
White or slightly yellow solid with a mild odor of hydrogen chloride; [Merck Index]
物理化学的性質
- 融点
- 56 °C · 56 °C
- 比重(密度)
- 2.04 · 2.040
- 溶解性
- 2 O; · very soluble in H2O; soluble in ethanol
- 外見
- しこり
- 色
- ライトイエロー
- 水溶解度
- 溶ける
- 比熱容量
- 0.59 J/ · Cp(liquid): 0.59 J/(g·K); Cp(gas): 0.35 J/(g·K), at 25℃
- Merck
- 14 · 14,8774
- 安定性
- 安定ですが、湿気や水と接触すると分解することがあります。強酸とは相容れない。
- InChI
- InChI=1S/4ClH.H2O.Sn/h4*1H;1H2;/q;;;;;+4/p-4
- InChIKey
- KHMOASUYFVRATF-UHFFFAOYSA-J
- SMILES
- [Sn](Cl)(Cl)(Cl)Cl.O
- CAS データベース
- 10026 · 10026-06-9(CAS DataBase Reference)
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Danger
H314 (98%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P260, P261, P264, P264+P265, P271, P273, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P363, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 50 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
危険有害性情報
Regulatory Information
Chemical: Stannane, tetrachloro-, pentahydrate
Tin (IV) chloride, pentahydrate: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelCorrosive
Fire Hazards
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Health Hazards
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.
Hazards Summary
Intravenous LD50 (mouse) = 32 mg/kg; [RTECS] Corrosive; [Merck Index] Reacts with water evolving hydrochloric acid; Toxic by ingestion, inhalation, and skin absorption; [CAMEO] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS] See Stannic chloride.
DOT ID and Guide2440 154
化学と産業
用途と製造
Uses
Used as a stabilizer for colors and perfumes in soap, in fabric dyeing (mordant), weighting silk, tinning vessels, and coating ceramics; [Merck Index] Used to make dyes and perfumes; [CAMEO]
Textiles (Printing, Dyeing, or Finishing) [Category: Industry]
Ceramics making [Category: Hobbies]
応用分野
用途有機スズ化合物原料、メッキ、電子工業
使用Substitute for anhydrous stannic chloride where the presence of water is not objectionable
一般的な説明Stannic chloride pentahydrate is a white colored solid. Stannic chloride pentahydrate is soluble in water. Stannic chloride pentahydrate is toxic by ingestion, inhalation and skin absorption. Stannic chloride pentahydrate is used to make perfumes and dyes.
調製方法
合成方法融解したスズに塩素を反応させる
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関連反応
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化合物ノート
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