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五塩化モリブデン

Molybdenum pentachloride

HCID 61497
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基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
10241-05-1
標準SMILES
[Cl][Mo]([Cl])([Cl])([Cl])[Cl]
InChIKey
GICWIDZXWJGTCI-UHFFFAOYSA-I
分子式
Cl5Mo
平均分子量
273.2 g/mol
単同位体質量
272.7496716

概要

Molybdenum pentachloride is a green-black odorless solid. It is toxic by ingestion and an irritant to skin. It may react with water to produce corrosive hydrochloric acid and toxic fumes.

名称と識別子

優先名称
Molybdenum pentachloride
IUPAC
pentachloromolybdenum
現地名
五塩化モリブデン
英語名
MOLYBDENUM(V) CHLORIDE
分子式
Cl5Mo
分子量
273.2

名称と別名

Molybdenum(V) chlorideMolybdenum pentachloride10241-05-1PentachloromolybdenumMoCl5BB0UFP2VO5CHEBI:30635RefChem:159384DTXCID1032721233-575-3DTXSID0065012MOLYBDENUM CHLORIDE (MoCl5)
名称をさらに表示
五塩化モリブデンモリブデン(V)ペンタクロリド塩化モリブデン(V)塩化モリブデン(Ⅴ)塩化モリブデン(V), 99.5%塩化モリブデン(V), 99.6% (metals basis)塩化モリブデン(V), 無水, 99.6%ペンタクロロモリブデンMOLYBDENUM CHLORIDEybdenum(V) chLMOLYBDENUMCHLORIDE(V)MOLYBDENUM(+5)CHLORIDEmolybdenumchloride(mocl5)Molybdenum(V)pentachloride
MFCD00003467EINECS 233-575-3UNII-BB0UFP2VO5UN2508pentachloridomolybdenum[MoCl5]SCHEMBL454117Molybdenum(V) chloride, 95%

データベース識別子

CAS
10241-05-1
PubChem CID
61497
DTXSID
DTXSID0065012
ChEBI
CHEBI:30635
EC Number
233-575-3

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
0
重原子数
6
形式電荷
0
複雑度
37.1

実験および物理化学的性質

Chemical Classes · 2 件

Metals -> Metals, Inorganic Compounds

Corrosives

Density2.93 @25 °C
Boiling Point268 °C @760 [mm Hg]
Physical Description · 2 件

Molybdenum pentachloride is a green-black odorless solid. It is toxic by ingestion and an irritant to skin. It may react with water to produce corrosive hydrochloric acid and toxic fumes.

Green-black solid; Dark-red as liquid or vapor; Hygroscopic; Reacts with water and air; [Hawley] Black crystalline solid with a pungent odor; Reacts with water; [MSDSonline]

物理化学的性質

融点
194 °C · 194 °C (lit.)
沸点
268 °C · 268 °C (lit.)
比重(密度)
2.928 g/mL · 2.928 g/mL at 25 °C (lit.)
蒸気圧
1.75 mm · 1.75 mm Hg ( 25 °C)
溶解性
乾燥エーテル、乾燥アルコール、有機溶剤、塩素系溶剤に可溶。
外見
粉
色
白から灰色
比重
2.928 · 2.928
水溶解度
93 · 乾燥エーテル、乾燥アルコール、その他の有機溶媒に可溶 [HAW93]
安定性
安定していますが、湿気や空気に敏感です。水と接触すると、有毒ガスが放出されます。水と相容れない、強力な酸化剤。
InChI
InChI=1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5
InChIKey
GICWIDZXWJGTCI-UHFFFAOYSA-I
SMILES
[Mo](Cl)(Cl)(Cl)(Cl)Cl
CAS データベース
10241 · 10241-05-1(CAS DataBase Reference)
EPAの化学物質情報
Molybdenum chloride (MoCl5) (10241-05-1)

化学的性質

化学的特性Green-black solid, dark red as liquid orvapor.Hygroscopic,reacting with water and air. Soluble in dry ether,dry alcohol, and other organic solvents.

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 71 reports by companies from 6 notifications to the ECHA C&L Inventory.

危険有害性情報

Regulatory Information · 3 件

Chemical: Molybdenum chloride (MoCl5)

Molybdenum (V) chloride: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelCorrosive
Fire Hazards · 2 件

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

· Combustible material: may burn but does not ignite readily.

Health Hazards · 2 件

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

Hazards Summary · 1 件

An irritant; [Hawley] May react with water evolving hydrochloric acid; A skin irritant; [CAMEO] Corrosive to skin and eyes; [eChemPortal: ERMA] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline] See Molybdenum.

DOT ID and Guide2508 156
Reactive GroupHalogenating Agents
Reactivity AlertsWater-Reactive
Reactivity Profile · 1 件

MOLYBDENUM PENTACHLORIDE is a corrosive, hygroscopic solid, on contact with water or steam it decomposes to form hydrochloric acid. When heated to decomposition it emits toxic fumes of molybdenum chlorides and metallic molybdenum [Lewis, 3rd ed., 1993, p. 892]. Explodes on contact with finely divided sodium [Berry D. H., Chem. Eng. News, 1989, 67(47), p. 2]. Reaction with finely divided sodium sulfide is violent, may lead to autoignition [Kaner, R. B., Nature, 1991, 349, p. 510].

DOT Hazard Classification · 4 件

Molybdenum pentachloride

UN2508

Class 8 Corrosive material (49 eCFR § 173.136)

PG III: the degree of danger presented by the material is minor

Air and Water ReactionsMolybdenum pentachloride may react with water to produce corrosive hydrochloric acid and toxic fumes.
Hazard Classes and Categories · 2 件

Skin Corr. 1B (100%)

Corrosives, Reactive agents - 2nd degree

安全と保護具

Fire FightingExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 件

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Isolation and Evacuation · 2 件

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

Immediate precautionary measure

Threshold Limit Values (TLV)0.5 [mg/m3], as Mo, respirable fraction
Permissible Exposure Limit (PEL)5.0 [mg/m3], as Mo
Protective Action Criteria (PAC) · 3 件

1.8 [ppm]

22 [ppm]

100 [ppm]

Personal Protective Equipment (PPE)Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Emergency Response Planning Guidelines· Note: Most foams will react with the material and release corrosive/toxic gases.
Immediately Dangerous to Life or Health (IDLH) · 2 件

1000 mg Mo/m3 (NIOSH, 2024)

1000.0 [mg/m3], as Mo

毒性情報

Adverse EffectsDermatotoxin - Skin burns.

安全データ

F
1-3-10
wgk
3
tsca
TSCA listed
rtecs
QA4690000
ridadr
UN 2508
hs_code
28273985
risk_code
29-34-48/20/22-40
hazard_code
C
safety_code
26-36/37/39-43-45
hazard_class
8
packing_group
III
Hazard Classifications
Carc. 2Eye Dam. 1Skin Corr. 1B
ストレージクラス
8A - Combustible corrosive hazardous materials

化学と産業

用途と製造

Uses · 2 件

Used as a chlorination catalyst and intermediate; Also used in molybdenum coatings, fire-retardant resins, and brazing/soldering fluxes; [Hawley]

Brazing [Category: Heat or Machine]

General Manufacturing InformationMolybdenum chloride (MoCl5): ACTIVE
応用分野 · 3 件

用途高純度金属化合物。

用途塩素化剤、触媒。

使用Chlorination catalyst, vapor-deposited molyb-denum coatings, component of fire-retardant resins,brazing and soldering flux, intermediate fororganometallic compounds, e.g., molybdenum hex-acarbonyl.

上流・下流製品情報

上流原料

Metal mo

下流製品

モリブデン(VI)ジクロリドジオキシドモリブデンMolybdenum,bis(eta-benzene)-

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化合物ノート

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