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二次亜塩素酸バリウム

Barium hypochlorite

HCID 61628
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
13477-10-6
標準SMILES
[Ba+2].[O-]Cl.[O-]Cl
InChIKey
HPEWZLCIOKVLBZ-UHFFFAOYSA-N
分子式
Ba(ClO)2
平均分子量
240.23 g/mol
単同位体質量
239.832782

概要

Barium hypochlorite, with more than 22% available chlorine appears as a white-colored crystalline solid. Denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. May accelerate the burning of combustible materials. Prolonged exposure to heat or flames may result in an explosion.

名称と識別子

優先名称
Barium hypochlorite
IUPAC
barium(2+) dihypochlorite
現地名
二次亜塩素酸バリウム
英語名
Barium hypochlorite
分子式
Ba.2ClHO
分子量
242.25

名称と別名

Hypochlorous acid, barium saltBarium hypochlorite13477-10-6RefChem:116531(chlorooxy)bario hypochloritebarium(2+);dihypochloriteBarium dihypochloriteUN2741SCHEMBL2046099DTXSID70928747HPEWZLCIOKVLBZ-UHFFFAOYSA-NBarium hypochlorite with >22% available chlorine
名称をさらに表示
二次亜塩素酸バリウム次亜塩素酸バリウムBarium hypochlorite.Dihypochlorous acid barium salt
Q4138814Barium hypochlorite with >22% available chlorine [UN2741] [Oxidizer]

データベース識別子

CAS
13477-10-6
PubChem CID
61628
DTXSID
DTXSID70928747

物性

構造計算による物性

極性表面積
46.1 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
0
重原子数
5
形式電荷
0
複雑度
2

実験および物理化学的性質

Physical Description · 1 件

Barium hypochlorite, with more than 22% available chlorine appears as a white-colored crystalline solid. Denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. May accelerate the burning of combustible materials. Prolonged exposure to heat or flames may result in an explosion.

物理化学的性質

EPAの化学物質情報
Hypochlorous acid, barium salt (13477-10-6)

安全と法規制

安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

Danger

H272: May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P260, P261, P264, P264+P265, P270, P271, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P308+P316, P316, P317, P319, P321, P363, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Danger

H272: May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P260, P264, P264+P265, P270, P280, P302+P352, P305+P351+P338, P308+P316, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P405, and P501 (click each P-code to see the statement)

危険有害性情報

Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelOxidizer Poison
Fire Hazards · 2 件

Excerpt from ERG Guide 141 [Oxidizers - Toxic]:

· These substances will accelerate burning when involved in a fire.

Health Hazards · 2 件

Excerpt from ERG Guide 141 [Oxidizers - Toxic]:

· Toxic by ingestion.

DOT ID and Guide2741 141
Reactive GroupSalts, Basic
Reactivity AlertsStrong Oxidizing Agent
Reactivity Profile · 1 件

Salts of hypochlorous acid, HClO. Generally toxic, irritants and powerful oxidizers, particularly in the presence of water or at higher temperature as they decompose to release oxygen and chlorine gases. On contact with urea they form the highly explosive NCl3. When heated or on contact with acids, they produce highly toxic fumes of chlorine gas [Sax, 9th ed., 1996, p. 1905].

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Barium compounds are absorbed via ingestion and inhalation, the extent of which depends on the individual compound. In the body, the majority of the barium is found in the bone, while small amounts exists in the muscle, adipose, skin, and connective tissue. Barium is not metabolized in the body, but it may be transported or incorporated into complexes or tissues. Barium is excreted in the urine and faeces. (L214)

応用分野 · 1 件

一般的な説明A white-colored crystalline solid. Denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. May accelerate the burning of combustible materials. Prolonged exposure to heat or flames may result in an explosion.

サプライヤー2 社

南通合润生物科技有限公司18362409333 · [email protected]
天津荣燊化工有限公司18317763565; 18317763565 · [email protected]

関連反応

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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
Air and Water ReactionsSoluble in water.
Hazard Classes and Categories · 2 件

Oxidizing solids - Category 2

Oxidizing solids - Category 2

安全と保護具

Fire FightingExcerpt from ERG Guide 141 [Oxidizers - Toxic]:
Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.

First Aid · 2 件

Excerpt from ERG Guide 141 [Oxidizers - Toxic]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 141 [Oxidizers - Toxic]:
Isolation and Evacuation · 2 件

Excerpt from ERG Guide 141 [Oxidizers - Toxic]:

Immediate precautionary measure

Minimum Risk LevelIntermediate Oral: 0.2 mg/kg/day (L134) Chronic Oral: 0.2 mg/kg/day (L134)
Personal Protective Equipment (PPE)Excerpt from ERG Guide 141 [Oxidizers - Toxic]:
Emergency Response Planning GuidelinesSmall Fire

毒性情報

TreatmentIntravenous infusion of potassium often relieves many of the symptoms of barium toxicity. (L214)
Health Effects · 1 件

The health effects of the different barium compounds depend on how well the compound dissolves in water or the stomach contents. At low doses, barium acts as a muscle stimulant, while higher doses affect the nervous system, causing cardiac irregularities, tremors, weakness, anxiety, dyspnea, paralysisand possibly death. Barium may also cause gastrointestinal disturbances, damage the kidneys and cause decreases in body weight. (L214)

Exposure RoutesOral (L214) ; inhalation (L214)
Toxicity Summary · 1 件

Barium is a competitive potassium channel antagonist that blocks the passive efflux of intracellular potassium, resulting in a shift of potassium from extracellular to intracellular compartments. The intracellular translocation of potassium results in a decreased resting membrane potential, making the muscle fibers electrically unexcitable and causing paralysis. Some of these barium's effects may also be due to barium induced neuromuscular blockade and membrane depolarization. (L214)

Signs and Symptoms · 1 件

Ingesting excess barium may cause vomiting, abdominal cramps, diarrhea, difficulties in breathing, increased or decreased blood pressure, numbness around the face, and muscle weakness. High levels may result in changes in heart rhythm or paralysis and possibly death. (L214)

Carcinogen Classification3, not classifiable as to its carcinogenicity to humans. (L135)

安全データ

ridadr
UN 2741 (BARIUM HYPOCHLORITE with more than 22 % available chlorine)
hazard_class
5.1
packing_group
II