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硝酸ウラニル(2+)六水和物

Uranyl nitrate hexahydrate

HCID 61640
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
13520-83-7
標準SMILES
O.O.O.O.O.O.O=[N+]([O-])O.O=[N+]([O-])O.[O]=[U]=[O]
InChIKey
WRIBVRZWDPGVQH-UHFFFAOYSA-N
分子式
H14N2O14U
平均分子量
504.15 g/mol
単同位体質量
504.09529

概要

See also: Para-BN (FDA NDC: 64616-102) (component of); D-40 (FDA NDC: 58264-0040) (component of); Panacode (FDA NDC: 43406-0686) (component of) ... View More ...

名称と識別子

優先名称
Uranyl nitrate hexahydrate
IUPAC
dioxouranium;bis(nitric acid);hexahydrate
現地名
硝酸ウラニル(2+)六水和物
英語名
URANYL NITRATE HEXAHYDRATE
分子式
H12N2O14U
分子量
502.13

名称と別名

Uranyl dinitrate hexahydrateUranylnitrate hexahydrateDinitratodioxouranium hexahydrateUNII-3V057702FY3V057702FYUranium, bis(nitrato-kappaO)dioxo-, hexahydrate, (T-4)-RefChem:5619113520-83-7Uranium nitricumUranyl nitrate hexahydrateURANYL NITRATE, HEXAHYDRATEdioxouranium;nitric acid;hexahydrate
名称をさらに表示
硝酸ウラニル(2+)六水和物硝酸ウラニル,六水和物(T-4)-ビス(ニトラト-κO)ジオキシドウラン六水和物硝酸ウラニル(6水和物)URANYL NITRATE HYDRATEURANIUM NITRATEURANYL NITRATE GRURANIUMOXYNITRATEUranium nitrate hydratehexahydrate(t-4)-uraniubis(nitrato-O)dioxouraniumUranyl(Ⅵ)nitrate hexahydrateURANYL(2+)NITRATEHEXAHYDRATE
Uranyl(VI) nitrate hexahydrateUN2980Uranium, dinitratodioxo-, hexahydrateUranium, bis(nitrato-O)dioxo-, hexahydrate (T-4)-URANYL NITRATE HEXAHYDRATE, ACS

物性

構造計算による物性

極性表面積
172 Ų
水素結合供与体数
8
水素結合受容体数
14
回転可能結合数
0
重原子数
17
形式電荷
0
複雑度
116

実験および物理化学的性質

Chemical ClassesPhysical/Radiation -> Radioactive Compounds
Density2.807 @ 13°C
Boiling Point118 °C @760 [mm Hg]
Melting Point60.2 °C
Physical Description"Acidic solution in water of uranyl nitrate, a radioactive yellow crystalline solid. Mildly chemically toxic. Contains nitric acid. . . . Minimal radiation hazard during transportation. No protective shielding is required." [CAMEO]

物理化学的性質

融点
60 · 60,2°C
沸点
118 ℃ · 118℃ [HAW93]
比重(密度)
2 · 2,807 g/cm3
溶解性
soluble in ethanol, ethyl ether
外見
黄色の斜方晶
色
yellow orthorhombic crystals, crystalline; hygroscopic
水溶解度
2 O · H2O (g/100g): 98(0℃), 122(20℃), 474(100℃)[LAN05]; アルコール、エーテルによく溶ける[MER06][SIE94]
安定性
放射性ですが、化学的に安定しています。強力な酸化剤。吸湿性。可燃性物質、還元剤との混和性。セルロースおよび特定の有機溶媒と爆発的に反応する可能性があります。
InChI
InChI=1S/2NO3.6H2O.2O.U/c2*2-1(3)4;;;;;;;;;/h;;6*1H2;;;/q2*-1;;;;;;;;;+2

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

Danger

H272 (97.4%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P260, P264, P270, P271, P273, P280, P284, P301+P316, P304+P340, P316, P319, P320, P321, P330, P370+P378, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H341: Suspected of causing genetic defects [Warning Germ cell mutagenicity]

危険有害性情報

Regulatory Information · 3 件

Chemical: Uranium, bis(nitrato-O)dioxo-, hexahydrate

Uranyl nitrate hexahydrate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Uranium, bis(nitrato-O)dioxo-, hexahydrate: Human health tier I assessment
Hazards SummaryProduces toxic oxides of nitrogen when involved in fires. [CAMEO] See Uranyl nitrate. See Uranium and linked occupational diseases.
Hazard Classes and Categories · 2 件

Ox. Sol. 2 (97.4%)

Germ cell mutagenicity - Category 2

安全と保護具

Exposure Control and Personal ProtectionBiological Exposure Indices (BEI) [ACGIH] - Uranium in urine = 200 ug/L at end of shift; [ACGIH]

化学と産業

応用分野 · 1 件

一般的な説明Acidic solution in water of uranyl nitrate, a radioactive yellow crystalline solid. Mildly chemically toxic. Contains nitric acid. Noncombustible, but will accelerate the burning of other combustible materials if concentrated or if the water evaporates. Large quantities may explode if exposed to fire. Produces toxic oxides of nitrogen if involved in fire. Radioactive materials emit certain rays which can be detected only by instruments. Unirradiated uranium is only mildly radioactive. Minimal radiation hazard during transportation. No protective shielding is required. Non-fissile (natural or depleted) uranium, containing not more than 1.0% u-235, cannot sustain a nuclear chain reaction.

調製方法 · 1 件

純化方法Crystallise the nitrate from water by cooling to -5o, taking only the middle fraction of the solid which separates. Dry the deliquescent rhombic yellow crystals of the hexahydrate over 35-40% H2SO4 in a vacuum desiccator. The crystals reflect a greenish lustre. They are remarkable because on crushing, rubbing or shaking they show triboluminescence with occasional detonation. They are very soluble in EtOH, and solutions of the nitrate in Et2O can explode in the presence of sunlight.

上流・下流製品情報

上流原料

硝酸ウラニル

サプライヤー29 社

Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]
陕西缔都新材料有限公司81124267 17392282731 · [email protected]
上海金试生化科技有限公司18601717983 18601717983 · [email protected]
合肥翰刚医药科技有限公司

関連反応

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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート

データベース識別子

CAS
13520-83-7
PubChem CID
61640
EC Number
626-992-0
InChIKey
LPWRMIDZYQRIKR-UHFFFAOYSA-N
SMILES
[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[U+2](=O)=O.O.O.O.O.O.O
CAS データベース
13520 · 13520-83-7(CAS DataBase Reference)
EPAの化学物質情報
Uranium, bis(nitrato-.kappa.O)dioxo-, hexahydrate, (T-4)- (13520-83-7)

化学的性質

化学的特性yellow crystals

Threshold Limit Values (TLV) · 2 件

0.2 [mg/m3], as U

0.6 [mg/m3], as U

Permissible Exposure Limit (PEL)0.05 [mg/m3], as U (sol), 0.25 mg/m3, as U (insol)
Protective Action Criteria (PAC) · 3 件

1.3 [mg/m3]

7.0 [mg/m3]

42 [mg/m3]

Immediately Dangerous to Life or Health (IDLH)10.0 [mg/m3], as U

安全データ

rtecs
YR3850000
ridadr
2912
毒性
cat,LDLo,oral,238mg/kg (238mg/kg),"Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 1, Pg. 310, 1955.
hs_code
28441000
risk_code
26/28-33-51/53
hazard_code
T+,R,N
safety_code
20/21-45-61
hazard_class
7
packing_group
II
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