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五フッ化塩素

Chlorine pentafluoride

HCID 61654
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
構造図なし

基本情報

CAS
13637-63-3
InChIKey
KNSWNNXPAWSACI-UHFFFAOYSA-N
分子式
ClF5
平均分子量
130.44 g/mol

概要

Chlorine pentafluoride appears as a colorless gas with a sweet odor. Toxic by inhalation and an irritant to skin, eyes and mucus membranes. Corrosive. Heavier than air. Under prolonged exposure to fire or intense heat the containers may violently rupture or rocket. Used as an oxidizer in propellants.

名称と識別子

優先名称
Chlorine pentafluoride
IUPAC
pentafluoro-λ5-chlorane
現地名
五フッ化塩素
英語名
CHLORINE PENTAFLUORIDE
分子式
ClF5
分子量
130.45

名称と別名

CHLORINE PENTAFLUORIDE13637-63-3Chlorine fluoride (ClF5)O4RJ1HW01HDTXSID90894056RefChem:125328DTXCID901324098237-123-6pentafluoro-lambda5-chloraneEINECS 237-123-6UN2548UNII-O4RJ1HW01H
名称をさらに表示
五フッ化塩素塩素(V)ペンタフルオリドペンタフルオロ塩素(V)ペンタフルオロ-λ5-クロランふっ化塩素(V)ClF5chlorinefluoride(clf5)Chlorinepentafluoride99%Chlorine pentafluoride 99%pentafluoro-λ5-chlorane
Pentafluoro-lambda~5~-chloraneKNSWNNXPAWSACI-UHFFFAOYSA-NSBB085767DB-243239Chlorine pentafluoride [UN2548] [Poison gas]Q419447

データベース識別子

CAS
13637-63-3
PubChem CID
61654
DTXSID
DTXSID90894056
UNII
O4RJ1HW01H
EC Number
237-123-6
Nikkaji
J74.677K

物性

構造計算による物性

XLogP
3.6
極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
5
回転可能結合数
0
重原子数
6
形式電荷
0
複雑度
37.1

実験および物理化学的性質

Chemical Classes · 2 件

Toxic Gases & Vapors -> Oxidizers

Corrosives

Density5.332 g/L
Boiling Point-13.1 °C @760 [mm Hg]
Melting Point-103 °C
Physical Description · 2 件

Chlorine pentafluoride appears as a colorless gas with a sweet odor. Toxic by inhalation and an irritant to skin, eyes and mucus membranes. Corrosive. Heavier than air. Under prolonged exposure to fire or intense heat the containers may violently rupture or rocket. Used as an oxidizer in propellants.

Colorless gas with a sweet odor; [CAMEO]

物理化学的性質

融点
-103 °C · -103°C
沸点
-13 · -13,1°C
比重(密度)
1.774 · 1.774 (estimate)
外見
無色のガス
色
colorless
EPAの化学物質情報
Chlorine fluoride (ClF5) (13637-63-3)

化学的性質

colorless gas; critical temp 142.6°C; enthalpy of vaporization 22.21 kJ/mol; specific conductivity 1.25×109 ohm· cm [KIR78]

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Danger

H270 (100%): May cause or intensify fire; oxidizer [Danger Oxidizing gases]

P220, P244, P260, P264, P271, P280, P284, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P320, P321, P363, P370+P376, P403, P403+P233, P405, P410+P403, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 111 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazards IdentificationToxic/poison by inhalation (TIH/PIH)
Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelPoison Gas Oxidizer Corrosive
Fire Hazards · 2 件

Excerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:

· Substance does not burn but will support combustion.

Health Hazards · 2 件

Excerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:

· TOXIC and/or CORROSIVE; may be fatal if inhaled or absorbed through skin.

Hazards SummaryReacts with water or moisture in the air to form hydrofluoric acid and chloride gas; Contact with liquefied gas can cause burns or frostbite; May be fatal if inhaled or absorbed through skin; [CAMEO]
DOT ID and Guide2548 124
Reactive Group

化学と産業

用途と製造

UsesUsed as a propellant; [CAMEO]
応用分野 · 2 件

使用Chlorine pentafluoride does not have anysignificant commercial application. It is usedas a fluorinating and oxidizing agent.

一般的な説明A colorless gas with a sweet odor. Toxic by inhalation and an irritant to skin, eyes and mucus membranes. Corrosive. Heavier than air. Under prolonged exposure to fire or intense heat the containers may violently rupture or rocket. Used as an oxidizer in propellants.

関連反応

0 件
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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
化学的特性
Oxidizing Agents, Strong
Reactivity AlertsStrong Oxidizing Agent
Reactivity Profile · 1 件

CHLORINE PENTAFLUORIDE is a strong oxidizing agent. Nonflammable, but likely to react vigorously on contact with combustible materials. Reacts violently with lithium, calcium. Emits highly toxic fluoride and chloride fumes when heated to decomposition. Extremely vigorous reaction with water, steam, even ice [Pilipovich D. et al., Inorg. Chem., 1967, 6, p. 1918]. Very vigorous reaction with anhydrous nitric acid even at -100 °C [Christie, K. O., Inorg. Chem. 1992, 11, p. 1220].

DOT Hazard Classification · 4 件

Chlorine pentafluoride

UN2548

Div 2.3 Poisonous gas (49 eCFR § 173.115)

Div 2.3 Poisonous gas (49 eCFR § 173.115)

Air and Water Reactions · 1 件

Reacts with water or moisture in the air to produce corrosive hydrofluoric acid and toxic chlorine gas. Interaction with ice at -100 °C, or with water vapor above 0 °C is extremely vigorous (Christe, K.O. Inorg. Chem. 1972 11, 1220). Hydrochloric acid fumes might also be generated upon reaction with water.

安全と保護具

Fire FightingExcerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:
Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Do not touch or walk through spilled material.

First Aid · 2 件

Excerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:

General First Aid:

Exposure Control and Personal Protection · 3 件

· Wear positive pressure self-contained breathing apparatus (SCBA).

TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].

1.0 [mg/m3], as F, inhalable fraction[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:
Isolation and Evacuation · 4 件

Excerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:

Immediate precautionary measure

Small spill:

Small spill:

Threshold Limit Values (TLV)2.5 [mg/m3], as F
Permissible Exposure Limit (PEL)2.5 [mg/m3], as F
Protective Action Criteria (PAC) · 3 件

0.015 [ppm]

0.17 [ppm]

8.0 [ppm]

Personal Protective Equipment (PPE)Excerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:
Emergency Response Planning GuidelinesCAUTION: These materials do not burn but will support combustion. Some will react violently with water.
Immediately Dangerous to Life or Health (IDLH) · 2 件

1.7 ppm [From IDLH Table: Chlorine Pentafluoride] (NIOSH, 2024)

9.05 [mg/m3]

毒性情報

Adverse EffectsDermatotoxin - Skin burns.
Toxicity DataLC50 (rat) = 122 ppm/1H

法規制情報

DHS Chemicals of Interest (COI) · 4 件

Chlorine pentafluoride

4.07

15

Weapons of Mass Effect chemical material that, if stolen or diverted, can be converted into weapons using simple chemistry, equipment, or techniques.

安全データ

IDLA
1.7 ppm
ridadr
UN 2548
hs_code
2812199000
hazard_code
O
hazard_note
Oxidising agent
safety_code
17-36/37/39
hazard_class
2.3