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テトラクロロ亜鉛酸アンモニウム

Zinc ammonium chloride

HCID 61754
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
14639-97-5
標準SMILES
[Cl][Zn-2]([Cl])([Cl])[Cl].[NH4+].[NH4+]
InChIKey
QOQUXKCHSZSKOT-UHFFFAOYSA-L
分子式
Cl4Zn.2H4N
平均分子量
243.3 g/mol
単同位体質量
239.873301

概要

Zinc ammonium chloride appears as a complex salt. Composition varies. A white crystalline solid. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is used in welding and soldering fluxes and in galvanizing steel.

名称と識別子

優先名称
Zinc ammonium chloride
IUPAC
diazanium;tetrachlorozinc(2-)
現地名
テトラクロロ亜鉛酸アンモニウム
英語名
Zinc ammonium chloride
分子式
Cl4H8N2Zn
分子量
243.28

名称と別名

Diammonium tetrachlorozincate(2-)14639-97-5EINECS 238-687-6EC 238-687-6Zincate(2-), tetrachloro-, ammonium (1:2), (T-4)-Zincate(2-), tetrachloro-, diammonium, (beta-4)-14639-97-552628-25-814639-98-6238-687-6258-054-852628-25-8AMMONIUM CHLOROZINCATE ((NH4)2(ZNCL4))AMMONIUM CHLOROZINCATE ((NH4)2[ZNCL4])
名称をさらに表示
テトラクロロ亜鉛酸アンモニウムZINC AMMONIUM CHLORIDZINC AMMONIUM CHLORIDEiazanium,tetrachlorozinc(2-)diazanium,tetrachlorozinc(2-)ZincammoniumchloridedoublesaltZinc ammonium chloride complexZINC AMMONIUM CHLORIDE 14639-97-5
Ammonium tetrachlorozincateAMMONIUM TETRACHLOROZINCATE [MI]AMMONIUM TETRACHLOROZINCATE(2-)AMMONIUM ZINC CHLORIDEAMMONIUM ZINC CHLORIDE (2NH4CL.ZNCL2)DIAMMONIUM TETRACHLOROZINCATEdiammonium tetrachlorozincdiuideDTXCID6030734

データベース識別子

CAS

物性

構造計算による物性

極性表面積
2 Ų
水素結合供与体数
2
水素結合受容体数
1
回転可能結合数
0
重原子数
7
形式電荷
0
複雑度
19.1

実験および物理化学的性質

Density1.81 at 68 °F (USCG, 1999) - Denser than water; will sink
Boiling Point644 °F at 760 mmHg (sublimes) (USCG, 1999)
Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical Description · 2 件

Zinc ammonium chloride appears as a complex salt. Composition varies. A white crystalline solid. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is used in welding and soldering fluxes and in galvanizing steel.

Liquid

物理化学的性質

融点
150 ° · ~150° (dec)
比重(密度)
1.879 · 1.879
溶解性
2 O · very soluble in H2O
外見
白い斜方晶板
色
white orthorhombic plates; hygroscopic
水溶解度
291 g/L · 291g/L at 20℃
安定性
安定。軟鋼を腐食します。
CAS データベース
14639 · 14639-97-5(CAS DataBase Reference)
EPAの化学物質情報
Ammonium tetrachlorozincate (14639-97-5)

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

Danger

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 9 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

危険有害性情報

Regulatory Information · 6 件

Chemical: Zincate(2-), tetrachloro-, diammonium, (T-4)-

Chemical: Ammonium zinc chloride

Zincate(2-), tetrachloro-, ammonium (1:2), (T-4)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Zincate(2-), tetrachloro-, ammonium (1:2), (T-4)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Diammonium tetrachlorozincate(2-) (EC: 238-687-6)

Restricted substance: Diammonium tetrachlorozincate(2-)

REACH registered substance: Ammonium zinc chloride (EC: 258-054-8)

DOT LabelCorrosive
Fire HazardsExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Health HazardsInhalation of dust irritates nose and throat. Ingestion can cause irritation or corrosion of the alimentary tract. Contact with eyes or skin causes irritation. (USCG, 1999)
Reactive GroupSalts, Acidic
Reactivity AlertsWater-Reactive

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Zinc can enter the body through the lungs, skin, and gastrointestinal tract. Intestinal absorption of zinc is controlled by zinc carrier protein CRIP. Zinc also binds to metallothioneins, which help prevent absorption of excess zinc. Zinc is widely distributed and found in all tissues and tissues fluids, concentrating in the liver, gastrointestinal tract, kidney, skin, lung, brain, heart, and pancreas. In the bloodstream zinc is found bound to carbonic anhydrase in erythrocytes, as well as bound to albumin, _2-macroglobulin, and amino acids in the the plasma. Albumin and amino acid bound zinc can diffuse across tissue membranes. Zinc is excreted in the urine and faeces. (L49)

用途と製造

U.S. Production2023: 111,564 lb
Consumer UsesStabilizing agent
Industry UsesStabilizing agent
General Manufacturing Information · 3 件

Textiles, apparel, and leather manufacturing

Zincate(2-), tetrachloro-, ammonium (1:2), (T-4)-: ACTIVE

Ammonium zinc chloride: ACTIVE

応用分野

使用Welding, soldering flux, dry batteries, galvanizing.

サプライヤー37 社

Hebei Jingbo New Material Technology Co., Ltd+86-19931165850 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
Shandong chuangyingchemical Co., Ltd.

関連反応

0 件
反応記録を作成

現在のフィルター条件では反応記録がありません。

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
14639-97-5、52628-25-8
PubChem CID
61754
EC Number
238-687-6、258-054-8

化学的性質

化学的特性White crystalline solid. Soluble in water.

Reactivity Profile · 1 件

Acidic inorganic salts, such as ZINC AMMONIUM CHLORIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 2 件

Acute Tox. 4 (100%)

Acute Tox. 4 (100%)

安全と保護具

Fire FightingExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
First AidINHALATION: remove from exposure; begin artificial respiration if breathing has ceased.
Nonfire Spill ResponseExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Isolation and EvacuationExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Minimum Risk LevelIntermediate Oral: 0.3 mg/kg/day (L134) Chronic Oral: 0.3 mg/kg/day (L134)
Personal Protective Equipment (PPE)Dust mask; goggles or face shield; protective gloves (USCG, 1999)

毒性情報

TreatmentZinc poisoning is treated symptomatically, often by administering fluids such as water or milk, or with gastric lavage. (L49)
Health EffectsChronic exposure to zinc causes anemia, atazia, lethargy, and decreases the level of good cholesterol in the body. It is also believed to cause pancreatic and reproductive damage. (L49)
Exposure RoutesOral (L49) ; inhalation (L49) ; dermal (L49)
Toxicity Summary · 1 件

Anaemia results from the excessive absorption of zinc suppressing copper and iron absorption, most likely through competitive binding of intestinal mucosal cells. Unbalanced levels of copper and zinc binding to Cu,Zn-superoxide dismutase has been linked to amyotrophic lateral sclerosis (ALS). Stomach acid dissolves metallic zinc to give corrosive zinc chloride, which can cause damage to the stomach lining. Metal fume fever is thought to be an immune response to inhaled zinc. (L48, L49, A49)

Signs and Symptoms · 1 件

Ingestion of large doses of zinc causes stomach cramps, nausea, and vomiting. Acute inhalation of large amounts of zinc causes metal fume fever, which is characterized by chills, fever, headache, weakness, dryness of the nose and throat, chest pain, and coughing. Dermal contact with zinc results in skin irritation. (L49)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

安全データ

tsca
TSCA listed
18853181302 · [email protected]
南通润丰石油化工有限公司66017690 19952660367 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
Hebei Zhuanglai Chemical Trading Co Ltd+86-16264648883 · [email protected]
HebeiShuoshengImportandExportco.,Ltd+86-18532138899 · [email protected]
陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
江苏普乐司生物科技有限公司0513-66017706 18551496367 · [email protected]
武汉市恒久化工有限公司17317534732 17671758929 · [email protected]
山东鑫恒诚化工有限公司18660169893 · [email protected]
南通合润生物科技有限公司18362409333 · [email protected]
常州市华阳科技有限公司+8615250961469 · [email protected]
Hebei Zhuanglai Chemical Trading Co.,Ltd13343047651 · [email protected]
PT CHEM GROUP LIMITED+86-85511178; +86-85511178 · [email protected]
天津荣燊化工有限公司18317763565; 18317763565 · [email protected]
Hebei Runbin Biotechnology Co. LTD13180553332 · [email protected]
HANGZHOU LEAP CHEM CO., LTD.+86-571-87711850 +86-15355479329 · [email protected]
南通市苏北化工原料有限公司0513-85290972 18762756250 · [email protected]
盼得(上海)国际贸易有限公司80159919 18662931292 · [email protected]
杭州洁汉化工有限公司+86-571-86217390; +8618058761490 · [email protected]
河南天孚化工有限公司+86-0371-55170693 +86-19937530512 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
career henan chemical co+86-0371-86658258 · [email protected]
海蔚化学86-21-51086038 · [email protected]
爆牛贸易重庆有限公司+86-023-6139-8061 +86-86-13650506873 · [email protected]
湖北信康医药化工有限公司027-027-59308705 18871579363 · [email protected]
ANHUI WITOP BIOTECH CO., LTD+8618071025641 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
武汉吉鑫益邦生物科技有限公司59768661 13297943853 · [email protected]
SUZHOU SENFEIDA CHEMICAL CO.,LTD+86-0512-83500002 +86-15195660023 · [email protected]
江苏润丰合成科技有限公司0513-66017678 18551497631 · [email protected]
Hefei TNJ Chemical Industry Co.,Ltd.+86-0551-65418671 +86-189 4982 3763 · [email protected]
Hebei Longbang Technology Co., LTD+86-18633929156 · [email protected]
南通润丰石油化工有限公司66814565 18912298907 · [email protected]
南通众合化工新材料有限公司0513-85666561 15950816326 · [email protected]

補足説明

定義A complex salt; double salts with 3–6 molecules of ammonium chloride have also been prepared.