基本情報
- CAS
14708-14-6- 標準SMILES
F[B-](F)(F)F.F[B-](F)(F)F.[Ni+2]- InChIKey
UTWSZAKRMXIKQI-UHFFFAOYSA-N- 分子式
- B2F8Ni
- 平均分子量
- 232.31 g/mol
- 単同位体質量
- 231.941177
概要
Nickel fluoroborate is a green odorless aqueous solution. Sinks in and mixes with water. (USCG, 1999)
名称と識別子
- 優先名称
- Borate(1-), tetrafluoro-, nickel(2+) (2:1)
- IUPAC
- nickel(2+) ditetrafluoroborate
- 現地名
- 硼弗化ニツケル
- 英語名
- Nickel tetrafluoroborate
- 分子式
- BF4Ni+
- 分子量
- 145.5
名称と別名
14708-14-6Nickel(II) fluoborateNickel II fluoborateBorate(1-), tetrafluoro-, nickel(2+) (2:1)EINECS 238-753-4Tetrafluoroborate(1-) nickel(2+) (2:1)DTXSID00884766RefChem:120980DTXCID201024190Tetrafluoroborate(1) nickel(2+) (2:1)Borate(1), tetrafluoro, nickel(2+) (2:1)Nickel tetrafluoroborate
名称をさらに表示
ホウフッ化ニッケル硼弗化ニツケルホウフッ化ニッケル(Ⅱ)ほうふっ化ニッケル(Ⅱ)溶液テトラフルオロほう酸ニッケル(II)溶液ﾃﾄﾗﾌﾙｵﾛﾎｳ酸ﾆｯｹﾙ(2+)tl1091NICKEL FLUOBORATEnickelborofluoridenickelfluoroboratenickel(ii)fluoboratenickeloustetrafluoroborateNickeltetrafluoroborate6H2Onickel(2+) tetrafluoroborate
Nickel(II) tetrafluoroboratenickel(2+);ditetrafluoroborateNickel fluoroborateNickel borofluorideNickelous tetrafluoroborateNickel bis(tetrafluoroborate)Nickelous fluoborateTL 1091
データベース識別子
- CAS
14708-14-6- PubChem CID
- 61765
- DTXSID
DTXSID00884766- EC Number
- 238-753-4
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 10
- 回転可能結合数
- 0
- 重原子数
- 11
- 形式電荷
- 0
- 複雑度
- 19.1
実験および物理化学的性質
Chemical ClassesMetals -> Nickel Compounds, Inorganic
Density1.5 at 68 °F (USCG, 1999) - Denser than water; will sink
Physical Description
Nickel fluoroborate is a green odorless aqueous solution. Sinks in and mixes with water. (USCG, 1999)
Green liquid; [CAMEO] Apple-green needles; [Ullmann]
物理化学的性質
- 比重(密度)
- 1.47 · 1.47
- CAS データベース
- 14708 · 14708-14-6(CAS DataBase Reference)
- EPAの化学物質情報
- Borate(1-), tetrafluoro-, nickel(2+) (2:1) (14708-14-6)
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Danger
H317: May cause an allergic skin reaction [Warning Sensitization, Skin]
P203, P233, P260, P261, P264, P270, P271, P272, P273, P280, P284, P302+P352, P304+P340, P318, P319, P321, P333+P317, P342+P316, P362+P364, P391, P403, P405, and P501 (click each P-code to see the statement)
Danger
H317 (97.7%): May cause an allergic skin reaction [Warning Sensitization, Skin]
P203, P233, P260, P261, P264, P270, P271, P272, P273, P280, P284, P302+P352, P304+P340, P318, P319, P321, P333+P317, P342+P316, P362+P364, P391, P403, P405, and P501 (click each P-code to see the statement)
危険有害性情報
Regulatory Information
Chemical: Borate(1-), tetrafluoro-, nickel(2+) (2:1)
Hazard Traits - Carcinogenicity; Reproductive Toxicity; Respiratory Toxicity
Restricted substance: Nickel bis(tetrafluoroborate)
Borate(1-), tetrafluoro-, nickel(2+) (2:1): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Other Safety InformationIMAP assessments - Soluble nickel compounds (Group 1): Human health tier II assessment
DOT LabelClass 9
Fire HazardsExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
Health HazardsIngestion causes irritation of mouth and stomach. Liquid irritates eyes and skin and may cause dermatitis. (USCG, 1999)
Hazards SummarySkin and eye irritant; [CAMEO] See Potassium tetrafluoroborate. See Nickel and linked occupational diseases.
Reactive GroupNon-Redox-Active Inorganic Compounds
Reactivity Profile
Acidic inorganic salts, such as NICKEL FLUOROBORATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
Air and Water ReactionsWater soluble.
Hazard Classes and Categories
Skin Sens. 1 (97.7%)
Acute toxicity - category 4
Carc. 1A
安全と保護具
Fire FightingExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
First AidINGESTION: give large amount of water; induce vomiting; get medical attention.
Exposure Control and Personal Protection1.0 [mg/m3]
Nonfire Spill ResponseExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
Isolation and EvacuationExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
Threshold Limit Values (TLV)0.1 [mg/m3], inhalable fraction, as Ni
Permissible Exposure Limit (PEL)1.0 [mg/m3], as Ni
Personal Protective Equipment (PPE)Safety glasses and face shield; rubber gloves; rubber apron (USCG, 1999)
Immediately Dangerous to Life or Health (IDLH)
10 mg Ni/m3 ; A potential occupational carcinogen. (NIOSH, 2024)
250.0 [mg/m3], as Ni
毒性情報
Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Toxicity DataLCLo (mice) = 530 mg/m3/10min
安全データ
- tsca
- TSCA listed
- rtecs
- QR6650000
- ridadr
- 1759
- hs_code
- 28269080
- risk_code
- 45-34-42/43-31
- hazard_code
- T,C
- hazard_note
- Corrosive
- safety_code
- 53-45-36/37/39-26-23
- hazard_class
- 6.1(b)
- packing_group
- III
化学と産業
用途と製造
Uses
Limited use in specialty nickel plating; [Ullmann]
Electroplating [Category: Plate]
General Manufacturing InformationBorate(1-), tetrafluoro-, nickel(2+) (2:1): ACTIVE
応用分野
一般的な説明Green odorless aqueous solution. Sinks in and mixes with water.
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