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ケイフッ化カリウム

Potassium hexafluorosilicate

HCID 61851
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
16871-90-2
標準SMILES
F[Si-2](F)(F)(F)(F)F.[K+].[K+]
InChIKey
UUHPPUWEDCVPCO-UHFFFAOYSA-N
分子式
F6Si.2K
平均分子量
220.272 g/mol
単同位体質量
219.8947585

概要

Potassium fluorosilicate appears as a white, odorless crystalline powder. Denser than water. Contact may cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

名称と識別子

優先名称
Potassium hexafluorosilicate
IUPAC
dipotassium;hexafluorosilicon(2-)
現地名
ケイフッ化カリウム
英語名
Potassium fluorosilicate
分子式
F6K2Si
分子量
220.27

名称と別名

Potassium hexafluorosilicate16871-90-2Potassium fluosilicatePotassium silicofluorideDipotassium hexafluorosilicate2610W49XYDDipotassium hexafluorosilicate(2-)EINECS 240-896-2UN2655UNII-2610W49XYDSilicate(2-), hexafluoro-, potassium (1:2)DTXSID10884939
名称をさらに表示
けいふっ化カリウムヘキサフルオロけい酸カリウムヘキサフルオロけい酸カリウム(けいふっ化カリウム)ヘキサフルオリドケイ酸(2-)二カリウムヘキサフルオロけい酸カリウム( けいふっ化カリウム)ヘキサフルオロけい酸カリウム, 99%ヘキサフルオロけい酸カリウム, 99.999% (metals basis)dipotassiumhexafluorosilicate(2-)Potassium fluosilicapotassiumfluosilicateKaliumhexafluorsilikatpotassium flurosilicatePOTASSIUM FLUOROSILICATEPOTASSIUM SILICAFLUORIDEPotasssium Silicofluoride
POTASSIUM HEXAFLUOROSILICATE [MI]SILICATE, HEXAFLUORO-, DIPOTASSIUMEC 240-896-2RefChem:175487FLUOSILICATE DE POTASSIUMDipotassium hexafluorosilicate(2)FLUOROSILICATE DE POTASSIUMSILICOFLUORURE DE POTASSIUM

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
7
回転可能結合数
0
重原子数
9
形式電荷
0
複雑度
62.7

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Inorganic Compounds
CosmeticsAntiplaque; Oral care
Density · 2 件

Relative density (water = 1): 2.3

2.27 @25 °C

SolubilitySolubility in water, g/100ml at 20 °C: 0.18 (poor)
Physical Description · 4 件

Potassium fluorosilicate appears as a white, odorless crystalline powder. Denser than water. Contact may cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

Dry Powder

White solid; [Merck Index] White powder; [Alfa Aesar MSDS]

WHITE CRYSTALS OR FINE POWDER.

物理化学的性質

融点
°Cd ec.)
沸点
dec
比重(密度)
2.665 g/mL · 2.665 g/mL at 25 °C(lit.)
蒸気圧
0.01 Pa · 0.01Pa
屈折率
1.3991 · 1.3991
溶解性
insoluble in ethanol
外見
粉
比重
2.665 · 2.665
色
白い

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

P261, P262, P264, P270, P271, P280, P301+P316, P302+P352, P304+P340, P316, P321, P330, P361+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

This chemical does not meet GHS hazard criteria for 9.2% (11 of 119) of reports.

Danger

H301 (90.8%): Toxic if swallowed [Danger Acute toxicity, oral]

危険有害性情報

Regulatory Information · 5 件

Chemical: Silicate(2-), hexafluoro-, dipotassium

Silicate(2-), hexafluoro-, potassium (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicate(2-), hexafluoro-, potassium (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Dipotassium hexafluorosilicate (EC: 240-896-2)

Potassium hexafluorosilicate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Hexafluorosilicate salts: Human health tier II assessment
DOT LabelPoison
Fire Hazards · 2 件

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

Health HazardsExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Hazards Summary

化学と産業

用途と製造

Uses · 3 件

Used to make opalescent glass, in porcelain enamels, insecticides, and aluminum metallurgy; [Merck Index]

Aluminum Producing [Category: Industry]

Ceramics making [Category: Hobbies]

U.S. Production2023: 407,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesAbrasives
Use ClassificationCosmetics -> Antiplaque; Oral care
General Manufacturing Information · 2 件

Not Known or Reasonably Ascertainable

Silicate(2-), hexafluoro-, potassium (1:2): ACTIVE

応用分野 · 3 件

用途光学用レンズ、農薬

使用In the manufacture of opalescent glass, in porcelain enamels, in insecticides. Also used in aluminum metallurgy.

一般的な説明A white, odorless crystalline powder. Denser than water. Contact may cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

調製方法

純化方法Crystallise it several times from conductivity water (100mL/g) between 100o and 0o.

上流・下流製品情報

上流原料

フッ化ケイ素酸炭酸カリウム

関連反応

0 件
反応記録を作成

現在のフィルター条件では反応記録がありません。

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート

データベース識別子

CAS
16871-90-2
PubChem CID
61851
DTXSID
DTXSID10884939
UNII
2610W49XYD
EC Number
240-896-2
臭い (Odor)
Odorless
水溶解度
水にわずかに溶ける。
Merck
14 · 14,7638
化粧品成分の機能
口腔ケア抗プラーク
InChI
1S/F6Si.2K/c1-7(2,3,4,5)6;;/q-2;2*+1
InChIKey
UUHPPUWEDCVPCO-UHFFFAOYSA-N
SMILES
[K+].[K+].F[Si--](F)(F)(F)(F)F
LogP
0.001 · 0.001
CAS データベース
16871 · 16871-90-2(CAS DataBase Reference)
EPAの化学物質情報
Silicate(2-), hexafluoro-, dipotassium (16871-90-2)

化学的性質

化学的特性White, odorless, crystalline powder. D 3.0. Slightly soluble in water; soluble in hydrochlo- ric acid.

· 1 件

Causes flaccid paralysis, ataxia, and muscle contraction in oral lethal-dose studies of mice and rats; [RTECS] Hydrolyzed by hot water producing potassium fluoride, hydrogen fluoride, and silicic acid; A severe irritant; [Merck Index] A skin, eye, and respiratory tract irritant; May have effects on calcium metabolism; Chronic exposure may cause fluorosis; [ICSC] Forms hydrofluoric acid when dissolved in water; An irritant; Toxic by ingestion, inhalation, and skin absorption; [Alfa Aesar MSDS] See Sodium hexafluorosilicate.

Reactive GroupSalts, Basic
EC ClassificationSymbol: T; R: 23/24/25; S: (1/2)-26-45; Note: A
UN ClassificationUN Hazard Class: 6.1; UN Pack Group: III
Reactivity Profile · 1 件

Solutions of potassium fluorosilicate may contain some hydrofluoric acid, which can cause severe chemical burns and is one of the few materials that can etch glass. Unlike other halide ions, fluoride is quite reactive, acting as a weak base and participating in some unique reactions. In particular, fluorides react strongly with compounds containing calcium, magnesium, or silicon ions, which means that solutions containing soluble fluorides are corrosive to both living tissue and glass.

Chemical DangersDecomposes on heating. This produces toxic and corrosive fumes including fluorine. Reacts with acids. This produces corrosive hydrogen fluoride (see ICSC 0283).
Packaging and LabellingDo not transport with food and feedstuffs.

安全と保護具

Fire Fighting · 2 件

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

In case of fire in the surroundings, use appropriate extinguishing media.

First Aid Measures · 4 件

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Do NOT induce vomiting. Refer immediately for medical attention.

First AidExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Safe StorageSeparated from acids and food and feedstuffs.
Exposure Control and Personal Protection · 2 件

Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Spillage Disposal · 1 件

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.

Isolation and EvacuationExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Eye PreventionWear safety goggles or eye protection in combination with breathing protection if powder.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly when dispersed.
Skin PreventionProtective gloves. Protective clothing.
Exposure PreventionPREVENT DISPERSION OF DUST!

毒性情報

Exposure RoutesThe substance can be absorbed into the body by ingestion.
Signs and Symptoms · 4 件

Burning sensation. Cough. Sore throat. See Ingestion.

Redness. Pain.

Redness. Pain. Blurred vision.

Abdominal cramps. Burning sensation. Nausea. Vomiting. Weakness. Convulsions. Shock or collapse.

安全データ

F
21
wgk
2
tsca
TSCA listed
rtecs
VV8400000
ridadr
UN 2655
hs_code
2826908090
risk_code
23/24/25
hazard_code
T,Xi
hazard_note
Irritant
safety_code
26-45
hazard_class
6.1
packing_group
III
毒劇物取締法
III
Hazard Classifications
Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 3 Oral
ストレージクラス
6.1D - Non-combustible acute toxic Cat.3toxic hazardous materials or hazardous materials causing chronic effects
危険度評価(NFPA 704基準/消防庁データ)
人的[青]=2 火災[赤]=0
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