基本情報
- 標準SMILES
F[Si-2](F)(F)(F)(F)F.[Mg+2]- InChIKey
INWUJAAIUAAHJA-UHFFFAOYSA-N- 分子式
- F6Si.Mg
- 平均分子量
- 166.38 g/mol
- 単同位体質量
- 165.95238755
概要
Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.
名称と識別子
- 優先名称
- Magnesium hexafluorosilicate
- IUPAC
- magnesium hexafluorosilicon(2-)
- 現地名
- ケイフッカマグネシウム
- 英語名
- Magnesium fluosilicate
- 分子式
- F6MgSi
- 分子量
- 166.38
名称と別名
名称をさらに表示
データベース識別子
- CAS
16949-65-8、18972-56-0- PubChem CID
- 61861
- DTXSID
DTXSID70884950- UNII
- H37V80D2JS
- EC Number
- 241-022-2、606-187-0
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 7
- 回転可能結合数
- 0
- 重原子数
- 8
- 形式電荷
- 0
- 複雑度
- 62.7
実験および物理化学的性質
Physical Description
Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.
Dry Powder
Solid; [CAMEO] White powder; [Gelest MSDS]
物理化学的性質
- 融点
- 120 °C · 120°C
- 沸点
- 120 °C · >120°C
- 比重(密度)
- 1.788 · 1.788
- 蒸気圧
- 0.001 Pa · 0.001Pa at 25℃
- 外見
- 粉
- 比重
- 1.788 · 1.788
- 水溶解度
- 498.4 g/L · 498.4g/L at 18.3℃
- 化粧品成分の機能
- 抗プラーク口腔ケア
- InChI
- InChI=1S/F6Si.Mg.6H2O/c1-7(2,3,4,5)6;;;;;;;/h;;6*1H2/q-2;+2;;;;;;
- InChIKey
- ZYDDCPHMRLLEEV-UHFFFAOYSA-N
- SMILES
- [Si-2](F)(F)(F)(F)(F)F.O.O.O.O.O.O.[Mg+2]
- LogP
- 0 at · 0 at 25℃
- CAS データベース
- 16949 · 16949-65-8(CAS DataBase Reference)
- EPAの化学物質情報
- Magnesium fluosilicate (16949-65-8)
安全と法規制
GHS分類
GHS Classification
Danger
H301: Toxic if swallowed [Danger Acute toxicity, oral]
P264, P270, P301+P316, P321, P330, P405, and P501 (click each P-code to see the statement)
Danger
H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]
P261, P264, P264+P265, P270, P271, P280, P301+P316, P304+P340, P305+P354+P338, P317, P321, P330, P405, and P501 (click each P-code to see the statement)
危険有害性情報
Regulatory Information
Chemical: Silicate(2-), hexafluoro-, magnesium (1:1)
Silicate(2-), hexafluoro-, magnesium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicate(2-), hexafluoro-, magnesium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: Magnesium hexafluorosilicate (EC: 241-022-2)
Magnesium hexafluorosilicate: Does not have an individual approval but may be used under an appropriate group standard
Magnesium fluorosilicate: Does not have an individual approval but may be used under an appropriate group standard
Fire Hazards
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Health Hazards
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
· Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.
Hazards Summary
Toxic by ingestion; May cause serious eye injury [Classifications by the EC] Not a skin irritant in rabbits (80% aqueous solution); Hematological and clinical chemistry changes, adverse dental effects, mineralization in bone tissue, interstitial nephritis, hyperkeratosis of the stomach, increased relative liver and kidney weights, and increased relative testes and adrenal weights in males observed in 4-week oral study of rats at 3,000 ppm dietary (approximately 300 mg/kg/day); [IUCLID] An eye irritant; Corrosive to mucous membranes; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause osteofluorosis; [Gelest MSDS] See Magnesium. See Fluorosilicic acid. See Calcium hexafluorosilicate.
Reactivity Profile
MAGNESIUM FLUOROSILICATE gives basic aqueous solutions. Reacts with acids. Does not usually react as either oxidizing agents or reducing agents. It can react slowly with water to generate hydrofluoric acid, which can cause severe chemical burns and is one of the few materials that can etch glass.
DOT Hazard Classification
Magnesium fluorosilicate
UN2853
Div 6.1 Poisonous materials (49 eCFR § 173.132)
PG III: the degree of danger presented by the material is minor
Hazard Classes and Categories
Acute Tox. 3 (100%)
Acute toxicity (ingestion) - category 3
Acute toxicity (Oral) - Category 3
Acute toxicity (Oral) - Category 3
Acute Tox. 3 *
安全と保護具
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
First Aid
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
General First Aid:
Exposure Control and Personal Protection
· Wear positive pressure self-contained breathing apparatus (SCBA).
Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)
1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]
Isolation and Evacuation
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Immediate precautionary measure
毒性情報
安全データ
- tsca
- TSCA listed
- ridadr
- UN 2853
- 毒性
- LD in guinea pigs (mg/kg): 200 orally, 400 s.c. (Waldbott)
- risk_code
- 25
- hazard_code
- T
- safety_code
- 24/25-45
- hazard_class
- 6.1
- packing_group
- III
化学と産業
用途と製造
Uses
Used for mothproofing textiles; [Merck Index] Used to make other chemicals; [CAMEO]
Textiles (Printing, Dyeing, or Finishing) [Category: Industry]
General Manufacturing Information
Non-metallic Mineral Product Manufacturing (includes clay, glass, cement, concrete, lime, gypsum, and other non-metallic mineral product manufacturing)
Silicate(2-), hexafluoro-, magnesium (1:1): ACTIVE
応用分野
用途繊維用防虫剤
一般的な説明Crystalline solid. Decomposes at 120°C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.
上流・下流製品情報
上流原料
サプライヤー50 社
補足説明
定義本品は、次の化学式で表される無機塩である。
関連反応
現在のフィルター条件では反応記録がありません。
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