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ケイフッカマグネシウム

Magnesium hexafluorosilicate

HCID 61861
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基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
16949-65-8
標準SMILES
F[Si-2](F)(F)(F)(F)F.[Mg+2]
InChIKey
INWUJAAIUAAHJA-UHFFFAOYSA-N
分子式
F6Si.Mg
平均分子量
166.38 g/mol
単同位体質量
165.95238755

概要

Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.

名称と識別子

優先名称
Magnesium hexafluorosilicate
IUPAC
magnesium hexafluorosilicon(2-)
現地名
ケイフッカマグネシウム
英語名
Magnesium fluosilicate
分子式
F6MgSi
分子量
166.38

名称と別名

Magnesium hexafluorosilicateMagnesium fluorosilicateCaswell No. 532Fluosilicate de magnesiumHexafluorosilicate(2-) magnesium (1:1)Silicate(2-), hexafluoro-, magnesium (1:1)EPA Pesticide Chemical Code 075304Fluosilicate de magnesium [French]EINECS 241-022-2UN2853UNII-H37V80D2JSMagnesium hexafluorosilicate(2)
名称をさらに表示
ヘキサフルオロけい酸マグネシウムけいふっ化マグネシウムケイフッカマグネシウムけいふっ化マグネシウム六水和物六フッ化ケイ酸マグネシウムフルオロケイ酸MGMagnesium fluorosiliMAGNESIUM FLUOSILICATEMAGNESIUM SILICOFLUORIDEMagnesiumhexafluorsilikatMAGNESIUMHEXAFLUOSILICATEfluosilicicacidmagnesiumsaltMAGNESIUM SILICOFLUORIDE 98%
FLUOROSILICATO DE MAGNESIODTXSID70884950hexafluorosilicate, magnesium saltMAGNESIUM HEXAFLUOROSILICATE [MI]MAGNESIUM SILICOFLUORIDE, (SOLID)EC 241-022-2MAGNESIUM SILICOFLUORIDE, [SOLID]RefChem:155211

データベース識別子

CAS
16949-65-8、18972-56-0
PubChem CID
61861
DTXSID
DTXSID70884950
UNII
H37V80D2JS
EC Number
241-022-2、606-187-0

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
7
回転可能結合数
0
重原子数
8
形式電荷
0
複雑度
62.7

実験および物理化学的性質

Chemical ClassesMineral Dusts -> Other Mineral Dusts
CosmeticsAntiplaque; Oral care
Physical Description · 3 件

Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.

Dry Powder

Solid; [CAMEO] White powder; [Gelest MSDS]

物理化学的性質

融点
120 °C · 120°C
沸点
120 °C · >120°C
比重(密度)
1.788 · 1.788
蒸気圧
0.001 Pa · 0.001Pa at 25℃
外見
粉
比重
1.788 · 1.788
水溶解度
498.4 g/L · 498.4g/L at 18.3℃
化粧品成分の機能
抗プラーク口腔ケア
InChI
InChI=1S/F6Si.Mg.6H2O/c1-7(2,3,4,5)6;;;;;;;/h;;6*1H2/q-2;+2;;;;;;
InChIKey
ZYDDCPHMRLLEEV-UHFFFAOYSA-N
SMILES
[Si-2](F)(F)(F)(F)(F)F.O.O.O.O.O.O.[Mg+2]
LogP
0 at · 0 at 25℃
CAS データベース
16949 · 16949-65-8(CAS DataBase Reference)
EPAの化学物質情報
Magnesium fluosilicate (16949-65-8)

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

P264, P270, P301+P316, P321, P330, P405, and P501 (click each P-code to see the statement)

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P316, P304+P340, P305+P354+P338, P317, P321, P330, P405, and P501 (click each P-code to see the statement)

危険有害性情報

Regulatory Information · 5 件

Chemical: Silicate(2-), hexafluoro-, magnesium (1:1)

Silicate(2-), hexafluoro-, magnesium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicate(2-), hexafluoro-, magnesium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Magnesium hexafluorosilicate (EC: 241-022-2)

Magnesium hexafluorosilicate: Does not have an individual approval but may be used under an appropriate group standard

Magnesium fluorosilicate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Magnesium hexafluorosilicates: Human health tier II assessment
DOT LabelPoison
Fire Hazards · 2 件

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards · 2 件

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.

Hazards Summary · 1 件

Toxic by ingestion; May cause serious eye injury [Classifications by the EC] Not a skin irritant in rabbits (80% aqueous solution); Hematological and clinical chemistry changes, adverse dental effects, mineralization in bone tissue, interstitial nephritis, hyperkeratosis of the stomach, increased relative liver and kidney weights, and increased relative testes and adrenal weights in males observed in 4-week oral study of rats at 3,000 ppm dietary (approximately 300 mg/kg/day); [IUCLID] An eye irritant; Corrosive to mucous membranes; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause osteofluorosis; [Gelest MSDS] See Magnesium. See Fluorosilicic acid. See Calcium hexafluorosilicate.

DOT ID and Guide2853 151
Reactive GroupSalts, Basic
Reactivity Profile · 1 件

MAGNESIUM FLUOROSILICATE gives basic aqueous solutions. Reacts with acids. Does not usually react as either oxidizing agents or reducing agents. It can react slowly with water to generate hydrofluoric acid, which can cause severe chemical burns and is one of the few materials that can etch glass.

DOT Hazard Classification · 4 件

Magnesium fluorosilicate

UN2853

Div 6.1 Poisonous materials (49 eCFR § 173.132)

PG III: the degree of danger presented by the material is minor

Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 5 件

Acute Tox. 3 (100%)

Acute toxicity (ingestion) - category 3

Acute toxicity (Oral) - Category 3

Acute toxicity (Oral) - Category 3

Acute Tox. 3 *

安全と保護具

Fire FightingExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

First Aid · 2 件

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

General First Aid:

Exposure Control and Personal Protection · 3 件

· Wear positive pressure self-contained breathing apparatus (SCBA).

Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Isolation and Evacuation · 2 件

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

Immediate precautionary measure

Threshold Limit Values (TLV)2.5 [mg/m3], as F
Permissible Exposure Limit (PEL)2.5 [mg/m3], as F
Personal Protective Equipment (PPE)Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Emergency Response Planning GuidelinesSmall Fire
Immediately Dangerous to Life or Health (IDLH)250.0 [mg/m3], as F

毒性情報

Adverse EffectsDermatotoxin - Skin burns.
Toxicity DataLC50 (rat) = 3,600 mg/m3/4hr

安全データ

tsca
TSCA listed
ridadr
UN 2853
毒性
LD in guinea pigs (mg/kg): 200 orally, 400 s.c. (Waldbott)
risk_code
25
hazard_code
T
safety_code
24/25-45
hazard_class
6.1
packing_group
III

化学と産業

用途と製造

Uses · 2 件

Used for mothproofing textiles; [Merck Index] Used to make other chemicals; [CAMEO]

Textiles (Printing, Dyeing, or Finishing) [Category: Industry]

U.S. Production2023: 88,184 lb
Consumer UsesBinder
Industry UsesBinder
Use ClassificationCosmetics -> Antiplaque; Oral care
General Manufacturing Information · 2 件

Non-metallic Mineral Product Manufacturing (includes clay, glass, cement, concrete, lime, gypsum, and other non-metallic mineral product manufacturing)

Silicate(2-), hexafluoro-, magnesium (1:1): ACTIVE

応用分野

用途繊維用防虫剤

一般的な説明Crystalline solid. Decomposes at 120°C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.

上流・下流製品情報

上流原料

水酸化マグネシウム炭酸マグネシウムフッ化ケイ素酸フッ化水素酸マグネシウムオキシド石英

補足説明

定義本品は、次の化学式で表される無機塩である。

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