CAS 32687-78-8 1,2-Bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamoyl)hydrazine (HCID 61916)

名称と識別子

優先名称: 1,2-Bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamoyl)hydrazine
IUPAC: 3-(3,5-ditert-butyl-4-hydroxyphenyl)-N'-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide
現地名: 酸化防止1024
英語名: antioxidant 1024
分子式: C34H52N2O4
分子量: 552.79

名称と別名

Antioxidant 10241,2-bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamoyl)hydrazineIrganox MD 1024Irganox 1024MD 1024EINECS 251-156-3Q4267VWT5Y1,2-Bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamoyl)hydrazideLOWINOX MD 24ADK STAB CDA 10N,N'-Bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl)hydrazineIRGANOX MD 2014

名称をさらに表示

酸化防止1024N，N’-ビス｛3-（3，5-ジ-tert-ブチル-4-ヒドロキシフェニル）プロピオニル｝ヒドラジン3-(3,5-ジ-tert-ブチル-4-ヒドロキシフェニル)-N'-[3-(3,5-ジ-tert-ブチル-4-ヒドロキシフェニル)プロパノイル]プロパンヒドラジドIRGANOX® MD 1024IrganoxR MD 10244,4′-(3,6-ジオキソ-4,5-ジアザオクタン-1,8-ジイル)ビス(2,6-ジ-tert-ブチルフェノール)イルガノックスMD-10241,1′-(ヒドラジン-1,2-ジイル)ビス[3-(3,5-ジ-tert-ブチル-4-ヒドロキシフェニル)-1-プロパノン]1,2-ビス[3-(3,5-ジtert-ブチル-4-ヒドロキシフェニル)プロピオニル]ヒドラジン1,2-ビス[3-(3,5-ジ-tert-ブチル-4-ヒドロキシフェニル)プロピオニル]ヒドラジン3,5-ビス(1,1-ジメチルエチル)-4-ヒドロキシベンゼンプロパン酸[2-[3-[3,5-ビス(1,1-ジメチルエチル)-4-ヒドロキシフェニル]-1-オキソプロピル]ヒドラジド]1,2-ビス[3-[4-ヒドロキシ-3,5-ビス(1,1-ジメチルエチル)フェニル]プロピオニル]ヒドラジンN,N′-ビス[3-(3,5-ジ-tert-ブチル-4-ヒドロキシフェニル)プロピオニル]ヒドラジン1,2-ビス[3-(4-ヒドロキシ-3,5-ジ-tert-ブチルフェニル)プロピオニル]ヒドラジン1,2-ビス(3,5-ジ-tert-ブチル-4-ヒドロキシヒドロシンナモイル)ヒドラジン4,4′-[ヒドラジン-1,2-ジイルビス(3-オキソプロパン-3,1-ジイル)]ビス(2,6-ジ-tert-ブチルフェノール)hydrazideLABOTEST-BB LT00261277At 1024MD-1024AO-1024HRao-1024

2',3-Bis[[3-[3,5-di-tert-butyl-4-hydroxyphenyl]propionyl]]propionohydrazideBis(3,5-di-tert-butyl-4-hydroxyhydrocinnamoyl)hydrazine3,5-Bis(1,1-dimethylethyl)-4-hydroxybenzenepropionic acidBenzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, 2-(3-(3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl)-1-oxopropyl)hydrazideBenzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, 2-[3-[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropyl]hydrazideDTXSID6027979Hydrazine, 1,2-bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamoyl)-EC 251-156-3

データベース識別子

CAS: 32687-78-8
PubChem CID: 61916
DTXSID: DTXSID6027979
UNII: Q4267VWT5Y
EC Number: 251-156-3
Nikkaji: J30.792K

物性

構造計算による物性

XLogP: 8.8
極性表面積: 98.7 Å²
水素結合供与体数: 4
水素結合受容体数: 4
回転可能結合数: 10
重原子数: 40
形式電荷: 0
複雑度: 724

実験および物理化学的性質

Polymers · 2 件

Plastics -> Antioxidants

Plastics -> Polyolefin-I; PUR; Polyolefin-II; PVC (soft); PA; PC

Food Contact Substances · 6 件

FCS -> FDA Cumulative Estimated Daily Intake (CEDI)

FCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR

FCS -> FDA Inventory of Effective Food Contact Substance (FCS) Notifications

Physical DescriptionOther Solid; Dry Powder; Large Crystals

物理化学的性質

融点: 60 · 60-67°C
沸点: 652.6 · 652.6±55.0 °C(Predicted)
比重(密度): 1.054 · 1.054±0.06 g/cm3(Predicted)
屈折率: 20 D · n20D 1.54
貯蔵温度: Refrigerator, under inert atmosphere
溶解性: アセトニトリル（微量）、クロロホルム（微量）
外見: 個体
酸解離定数(Pka): 11.1 · 11.10±0.50(Predicted)
色: ホワイトからオフホワイト
主な用途: 食品および飲料医薬品プラスチック
InChIKey: HCILJBJJZALOAL-UHFFFAOYSA-N
SMILES: C1(CCC(NNC(=O)CCC2=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C2)=O)=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1
LogP: 4.8 at · 4.8 at 23℃
CAS データベース: 32687 · 32687-78-8(CAS DataBase Reference)
EPAの化学物質情報: 1 · 1,2-Bis[3,5-bis(tert-butyl)-4-hydroxyhydrocinnamoyl]hydrazide (32687-78-8)

化学的性質 · 1 件

化学的特性Antioxidant 1024, white to slightly yellowish crystalline powder, is a non-staining, high molecular weight, hindered phenolic antioxidant and metal deactivator. It improves properties in polymers exposed to sour gasoline. It offers antioxidant protection in immersion, dry-out and ageing testing due to its good extraction resistance in fuels and oils. In this grade, the metal deactivating functions provide better end-use heat and light stability by deactivating metal catalyst residues in polyolefins and polymers. Antioxidant 1024, when combined with Antioxidants 58 and 60, enhances the heat resistance and metal deactivation properties. It finds application in EPDM, crosslinked polyethylene, nylon, polyacetal and nitrile polymers. The recommended dosage level in plastic is 0.02-0.50%, and in rubber, it is 2 phr by weight.

安全と法規制

GHS分類

GHS Classification · 4 件

This chemical does not meet GHS hazard criteria for 61.3% (291 of 475) of all reports.

H412 (38.1%): Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P273, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 475 reports by companies from 6 notifications to the ECHA C&L Inventory.

危険有害性情報

Regulatory Information · 4 件

Chemical: Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, 2-[3-[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropyl]hydrazide

Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, 2-[3-[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropyl]hydrazide is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, 2-[3-[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropyl]hydrazide are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 31-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/5967

Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, 2-3-3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl-1-oxopropylhydrazide: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesAquatic Chronic 3 (38.1%)

安全データ

tsca: TSCA listed
hs_code: 2928009010
化審法: (3)-3536
Hazard Classifications: Aquatic Chronic 4
ストレージクラス: 11 - Combustible Solids

化学と産業

用途と製造

UsesPlastics -> Typical concentration range in plastic materials -> 0.002 - 3.0%

U.S. Production2023: 850,000 - <1,000,000 lb

Consumer UsesPlasticizer

Industry UsesUV stabilizer

Use Classification · 2 件

Plastics -> Polymer Type -> Polyolefin-I; PUR; Polyolefin-II; PVC (soft); PA; PC

Plastics -> Antioxidants

General Manufacturing Information · 2 件

Synthetic Rubber Manufacturing

Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, 2-[3-[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropyl]hydrazide: ACTIVE

応用分野

説明FDA approve antioxidant 1024 usage in packaging polymers, resins, and adhesives intended for food contact applications. It is approved in many countries for food contact applications.

使用Antioxidant 1024 is used in conjunction with phenolic antioxidants, phosphites/phosphonites, thio-synergists and other co-additives.

上流・下流製品情報

上流原料

抱水ヒドラジン Propionyl hydrazide プロピオニルクロリドプロピオン酸メチル 4-ヒドロキシ-3,5-ジ-tert-ブチルベンゼンプロピオン酸

サプライヤー100 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

湖北永阔科技有限公司027-59223108 15972152991 · [email protected]

湖北万得化工有限公司15377098680 15377098680 · [email protected]

Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]

杭州景优化工有限公司87211835 13957193240 · [email protected]

化合物ノート

読み込み中…

酸化防止1024

基本情報