基本情報
- 標準SMILES
C#CC.C=C=C- InChIKey
VBUBYMVULIMEHR-UHFFFAOYSA-N- 分子式
- C6H8
- 平均分子量
- 80.13 g/mol
- 単同位体質量
- 80.06260026
名称と識別子
- 優先名称
- Propyne, mixed with propadiene
- IUPAC
- propa-1,2-diene;prop-1-yne
- 現地名
- メチルアセチレンとプロパジエンの混合物
- 英語名
- Methylacetylene and propadiene mixture,stabilized
- 分子式
- C6H8
- 分子量
- 80.12772
名称と別名
名称をさらに表示
データベース識別子
- CAS
59355-75-8- PubChem CID
- 62152
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 0
- 回転可能結合数
- 0
- 重原子数
- 6
- 形式電荷
- 0
- 複雑度
- 42
実験および物理化学的性質
Density
0.576 at 59 °F
1.48(relative gas density)
Boiling Point
-36 to -4 °F
-36 to -4 °F
Melting Point
-213 °F
-213 °F
Vapor Pressure
>1 atm
>1 atm
Physical Description
Colorless gas with a strong, characteristic, foul odor. [Note: A fuel that is shipped as a liquefied compressed gas.]; [NIOSH]
Colorless gas with a strong, characteristic, foul odor.
Colorless gas with a strong, characteristic, foul odor. [Note: A fuel that is shipped as a liquefied compressed gas.]
物理化学的性質
- EPAの化学物質情報
- MAPP (59355-75-8)
化学的性質
化学的特性Colorless, liquefied gas.A mixture containing 60–66.5% methylacetylene and propadiene, with the balance being propane and butane.
安全と法規制
危険有害性情報
Regulatory Information
Chemical: Methyl acetylene-propadiene mixture
MAPP: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Hazards Summary
Possible frostbite from contact with liquid; [NIOSH] MAPP gas is an explosive hazard. Reduce hazard by keeping concentrations below 10% of lower explosive limit (3400 ppm). It can cause anesthetic effects and at very high concentrations, asphyxiation. At an exposure level of 5000 ppm 7 hours/day, 5 days/week, experimental animals show decreased body weight. [ACGIH] Classified as Simple asphyxiant; [CAMEO] Methylacetylene-propadiene mixture, stabilized (UN1060) has warning of explosive polymerization; [ERG 2016] See Methylacetylene and Propadiene.
Lower Explosive Limit (LEL)
3.4%
3.4%
Upper Explosive Limit (UEL)
10.8%
10.8%
安全と保護具
First Aid
(General first aid procedures);Eye: Frostbite - If eye tissue is frozen, seek medical attention immediately; if tissue is not frozen, immediately and thoroughly flush the eyes with large amounts of water for at least 15 minutes, occasionally lifting the lower and upper eyelids. If irritation, pain, swelling, lacrimation, or photophobia persist, get medical attention as soon as possible.;Skin: Frostbite - Compressed gases may create low temperatures when they expand rapidly. Leaks and uses that allow rapid expansion may cause a frostbite hazard. Wear appropriate personal protective clothing to prevent the skin from becoming frozen.;Breathing: Respiratory support
Respirator Recommendations
NIOSH/OSHA;Up to 3400 ppm:;(APF = 10) Any supplied-air respirator;(APF = 50) Any self-contained breathing apparatus with a full facepiece;Emergency or planned entry into unknown concentrations or IDLH conditions:;(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode;(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus;Escape:;(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern;Any appropriate escape-type, self-contained breathing apparatus;Important additional information about respirator selection
Threshold Limit Values (TLV)
1000.0 [ppm]
1250.0 [ppm]
1000 ppm [1964]
1250 ppm [1964]
Permissible Exposure Limit (PEL)
1000.0 [ppm]
1000 ppm (1800 mg/m³)
TWA 1000 ppm (1800 mg/m3) See Appendix G
Protective Action Criteria (PAC)
1250 [ppm]
2500 [ppm]
15000 [ppm]
Recommended Exposure Limit (REL)
1000 ppm (1800 mg/m³)
1250 ppm (2250 mg/m³)
TWA 1000 ppm (1800 mg/m3) ST 1250 ppm (2250 mg/m3)
Immediately Dangerous to Life or Health (IDLH)
3400.0 [ppm];Excerpts from Documentation for IDLHs: Basis for revised IDLH: Since a methyl acetylenepropadiene mixture appears to have relatively low toxicity, and based on an analogy to methyl acetylene [ACGIH 1991], the revised IDLH is 3,400 ppm based strictly on safety considerations (i.e., being 10% of the lower explosive limit of 3.4%).
3400 ppm
3400 ppm [10%LEL];See: 59355758
毒性情報
法規制情報
Regulatory Information
Chemical: Methyl acetylene-propadiene mixture
MAPP: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
安全データ
- OEB
- A
- OEL
- TWA: 1000 ppm (1800 mg/m3), STEL: 1250 ppm (2250 mg/m3)
- IDLA
- 3,400 ppm [10% LEL]
化学と産業
用途と製造
Uses
Used as fuel for industrial cutting; [ACGIH]
Gas Welding and Cutting [Category: Weld]
応用分野
使用Industrial fuel gas for cutting, welding, brazing, heat treating, and metallizing.
一般的な説明Methylacetylene-propadiene stabilized is a colorless gas with an acetylene like odor. Methylacetylene and propadiene mixture,stabilized is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. Methylacetylene and propadiene mixture,stabilized is easily ignited. The vapors are heavier than air. Any leak can either be liquid or vapor. Methylacetylene and propadiene mixture,stabilized can asphyxiate by the displacement of air. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket.
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