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メチルアセチレンとプロパジエンの混合物

Propyne, mixed with propadiene

HCID 62152
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基本情報名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
59355-75-8
標準SMILES
C#CC.C=C=C
InChIKey
VBUBYMVULIMEHR-UHFFFAOYSA-N
分子式
C6H8
平均分子量
80.13 g/mol
単同位体質量
80.06260026

名称と識別子

優先名称
Propyne, mixed with propadiene
IUPAC
propa-1,2-diene;prop-1-yne
現地名
メチルアセチレンとプロパジエンの混合物
英語名
Methylacetylene and propadiene mixture,stabilized
分子式
C6H8
分子量
80.12772

名称と別名

59355-75-8Propadiene-methyl acetyleneMAPP gasRefChem:176562Methyl acetylene-propadiene mixture (ACGIH:OSHA)METHYL ACETYLENE-PROPADIENE MIXTURE (STABILIZED)MAPPUN1060propa-1,2-diene;prop-1-yneAllene PropynePropadien PropinSCHEMBL447120
名称をさらに表示
メチルアセチレンとプロパジエンの混合物メチルアセチレンとプロパジエンの混MAPDPROPYNE-ALLENEMIXTUREMethyl acetylene propadienePROPYL-ALLENEMIXTURE(MAPPGAS)Methyl acetylene propadiene mixture.Propyne and allene mixtures,stabilizedMethylacetylene and propadiene mixture,stabilized
56960-91-9

データベース識別子

CAS
59355-75-8
PubChem CID
62152

物性

構造計算による物性補完中

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
0
重原子数
6
形式電荷
0
複雑度
42

実験および物理化学的性質

Density · 2 件

0.576 at 59 °F

1.48(relative gas density)

SolubilityInsoluble
Flash PointNA (Gas)
Boiling Point · 2 件

-36 to -4 °F

-36 to -4 °F

Melting Point · 2 件

-213 °F

-213 °F

Vapor Density1.48
Odor ThresholdOdor Threshold Low: 100.0 [ppm];Reported odor threshold of 100 ppm
Vapor Pressure · 2 件

>1 atm

>1 atm

Physical Description · 3 件

Colorless gas with a strong, characteristic, foul odor. [Note: A fuel that is shipped as a liquefied compressed gas.]; [NIOSH]

Colorless gas with a strong, characteristic, foul odor.

Colorless gas with a strong, characteristic, foul odor. [Note: A fuel that is shipped as a liquefied compressed gas.]

物理化学的性質

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

危険有害性情報

Regulatory Information · 2 件

Chemical: Methyl acetylene-propadiene mixture

MAPP: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationIMAP assessments - Methyl acetylene-propadiene mixture: Human health tier I assessment;IMAP assessments - Methyl acetylene-propadiene mixture: Environment tier I assessment
Hazards Summary · 1 件

Possible frostbite from contact with liquid; [NIOSH] MAPP gas is an explosive hazard. Reduce hazard by keeping concentrations below 10% of lower explosive limit (3400 ppm). It can cause anesthetic effects and at very high concentrations, asphyxiation. At an exposure level of 5000 ppm 7 hours/day, 5 days/week, experimental animals show decreased body weight. [ACGIH] Classified as Simple asphyxiant; [CAMEO] Methylacetylene-propadiene mixture, stabilized (UN1060) has warning of explosive polymerization; [ERG 2016] See Methylacetylene and Propadiene.

DOT ID and Guide1060 116P(stabilized)
Flammable LimitsFlammable Gas
Lower Explosive Limit (LEL) · 2 件

3.4%

3.4%

Upper Explosive Limit (UEL) · 2 件

10.8%

10.8%

Hazardous Reactivities and IncompatibilitiesStrong oxidizers, copper alloys [Note: Forms explosive compounds at high pressure in contact with alloys containing more than 67% copper.]

安全と保護具

化学と産業

用途と製造

Uses · 2 件

Used as fuel for industrial cutting; [ACGIH]

Gas Welding and Cutting [Category: Weld]

応用分野 · 2 件

使用Industrial fuel gas for cutting, welding, brazing, heat treating, and metallizing.

一般的な説明Methylacetylene-propadiene stabilized is a colorless gas with an acetylene like odor. Methylacetylene and propadiene mixture,stabilized is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. Methylacetylene and propadiene mixture,stabilized is easily ignited. The vapors are heavier than air. Any leak can either be liquid or vapor. Methylacetylene and propadiene mixture,stabilized can asphyxiate by the displacement of air. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket.

関連反応

3 件
反応記録を作成
HRID 372366 の反応式
HRID 372366反応物としてuspto-grants-1978_05
HRID 443996 の反応式
HRID 443996反応物としてuspto-grants-1981_04
HRID 1289263 の反応式
HRID 1289263反応物としてuspto-grants-1998_05

化合物ノート

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EPAの化学物質情報
MAPP (59355-75-8)

化学的性質

化学的特性Colorless, liquefied gas.A mixture containing 60–66.5% methylacetylene and propadiene, with the balance being propane and butane.

First Aid · 1 件

(General first aid procedures);Eye: Frostbite - If eye tissue is frozen, seek medical attention immediately; if tissue is not frozen, immediately and thoroughly flush the eyes with large amounts of water for at least 15 minutes, occasionally lifting the lower and upper eyelids. If irritation, pain, swelling, lacrimation, or photophobia persist, get medical attention as soon as possible.;Skin: Frostbite - Compressed gases may create low temperatures when they expand rapidly. Leaks and uses that allow rapid expansion may cause a frostbite hazard. Wear appropriate personal protective clothing to prevent the skin from becoming frozen.;Breathing: Respiratory support

Respirator Recommendations · 1 件

NIOSH/OSHA;Up to 3400 ppm:;(APF = 10) Any supplied-air respirator;(APF = 50) Any self-contained breathing apparatus with a full facepiece;Emergency or planned entry into unknown concentrations or IDLH conditions:;(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode;(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus;Escape:;(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern;Any appropriate escape-type, self-contained breathing apparatus;Important additional information about respirator selection

Threshold Limit Values (TLV) · 4 件

1000.0 [ppm]

1250.0 [ppm]

1000 ppm [1964]

1250 ppm [1964]

Permissible Exposure Limit (PEL) · 3 件

1000.0 [ppm]

1000 ppm (1800 mg/m³)

TWA 1000 ppm (1800 mg/m3) See Appendix G

Protective Action Criteria (PAC) · 3 件

1250 [ppm]

2500 [ppm]

15000 [ppm]

Recommended Exposure Limit (REL) · 3 件

1000 ppm (1800 mg/m³)

1250 ppm (2250 mg/m³)

TWA 1000 ppm (1800 mg/m3) ST 1250 ppm (2250 mg/m3)

Immediately Dangerous to Life or Health (IDLH) · 3 件

3400.0 [ppm];Excerpts from Documentation for IDLHs: Basis for revised IDLH: Since a methyl acetylene­propadiene mixture appears to have relatively low toxicity, and based on an analogy to methyl acetylene [ACGIH 1991], the revised IDLH is 3,400 ppm based strictly on safety considerations (i.e., being 10% of the lower explosive limit of 3.4%).

3400 ppm

3400 ppm [10%LEL];See: 59355758

毒性情報

Target Organsrespiratory system, central nervous system
Adverse EffectsNeurotoxin - Acute solvent syndrome;Other Poison - Simple Asphyxiant
Exposure Routesinhalation, skin and/or eye contact (liquid)
Signs and Symptomsirritation respiratory system; excitement, confusion, anesthesia; liquid: frostbite

法規制情報

Regulatory Information · 2 件

Chemical: Methyl acetylene-propadiene mixture

MAPP: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

安全データ

OEB
A
OEL
TWA: 1000 ppm (1800 mg/m3), STEL: 1250 ppm (2250 mg/m3)
IDLA
3,400 ppm [10% LEL]