硫酸鉄(II)·7水和物

Ferrous sulfate heptahydrate

HCID 62662CAS 15491-23-3
部分構造検索類似構造を探す

基本情報

標準SMILES
O.O.O.O.O.O.O.O=S(=O)([O-])[O-].[Fe+2]
InChIKey
SURQXAFEQWPFPV-UHFFFAOYSA-L
分子式
FeH14O11S
平均分子量
278.02 g/mol
単同位体質量
277.96061977

概要

Iron(2+) sulfate heptahydrate is a hydrate that is the heptahydrate form of iron(2+) sulfate. It is used as a source of iron in the treatment of iron-deficiency anaemia (generally in liquid-dosage treatments; for solid-dosage treatments, the monohydrate is normally used). It has a role as a nutraceutical, a reducing agent and an anti-anaemic agent. It is an iron molecular entity and a hydrate. It contains an iron(2+) sulfate (anhydrous).

名称と識別子

優先名称
Ferrous sulfate heptahydrate
IUPAC
iron(2+);sulfate;heptahydrate
現地名
硫酸鉄(II)·7水和物
英語名
Ferrous sulfate heptahydrate
分子式
FeH14O11S
分子量
278.01

名称と別名

7782-63-0Iron(II) sulfate heptahydrateFERROUS SULFATE HEPTAHYDRATEIron(2+) sulfate heptahydrateIron sulfate heptahydrateMelanterite mineralFesotymeIrosulSiderotil mineralTauriscite mineralSzomolnikite mineralFerrous sulfate, heptahydrate
名称をさらに表示
硫酸鉄(II)七水和物プレスフェルスルイロナートイロスル鉄プロトスルファートメランテライト硫酸鉄(II)·7水和物七水硫酸硫酸鉄(II)七水和物(硫酸第一鉄)硫酸鉄(II)七水和物,3N硫酸第一鉄七水和物硫酸（ＩＩ）七水和物硫酸鉄（Ⅱ）・７水和物硫酸鉄(Ⅱ)七水和物硫酸第一鉄(結晶)[7水和物]硫酸鉄(Ⅱ)七水和物硫酸第一鉄,7水和物硫酸鉄(II) 七水和物 ACS REAGENT,≥99.0%硫酸鉄(II) 七水和物 PURISS. P.A.,ACS REAGENT,REAG. ISO,REAG. PH. EUR.,99.0-103.4% (MANGANOMETRIC)硫酸鉄(II) 七水和物 PURISS.,MEETS ANALYTICAL SPECIFICATION OF PH. EUR.,BP,USP,FCC,99.5-104.5% (MANGANOMETRIC)硫酸第一鉄結晶FERROINsulfate heptahydrateFERROIN INDICATOR SOLUTIONIron(Ⅱ) sulfate heptahydrateFERROIN INDICATORFerrous sulfate heptferrous sulfate granularFerrousSulphateMonohydrateIron(II)sulphateheptahydrate,98%
Iron(II) sulfate (1:1), heptahydrateTetucur-SDTXSID9040344CHEBI:75836RefChem:921576DTXCID7020344616-510-7Melanterite

データベース識別子

CAS
15491-23-3、7782-63-0
PubChem CID
62662
DTXSID
DTXSID9040344
ChEBI
CHEBI:75836
UNII
39R4TAN1VT
EC Number
616-510-7

物性

構造計算による物性

極性表面積
95.6 Ų
水素結合供与体数
7
水素結合受容体数
11
回転可能結合数
0
重原子数
13

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Inorganic Compounds
Density1.895 @25 °C
Physical Description · 2 件

CBI

Blue-green odorless solid; Efflorescent in dry air; Soluble in water; [Merck Index] Green crystalline solid; [Alfa Aesar MSDS]

物理化学的性質

融点
64 °C · 64 °C
比重(密度)
1.898 g/mL · 1.898 g/mL at 25 °C (lit.)
蒸気圧
14.6 mm · 14.6 mm Hg ( 25 °C)
貯蔵温度
15 °C · Store at +15°C to +25°C.
溶解性
25.6 g/100mL · 25.6g/100mL(20℃)
外見
解決

化学的性質

化学的特性light blue or light blue-green solid

安全と法規制

GHS分類

GHS Classification · 6 件

Warning

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P264, P264+P265, P270, P280, P301+P317, P302+P352, P305+P351+P338, P321, P330, P332+P317, P337+P317, P362+P364, and P501 (click each P-code to see the statement)

This chemical does not meet GHS hazard criteria for < 0.1% (2 of 2619) of reports.

Warning

H302 (> 99.9%): Harmful if swallowed [Warning Acute toxicity, oral]

危険有害性情報

Regulatory Information · 4 件

Chemical: Sulfuric acid, iron(2+) salt (1:1), heptahydrate

Regulation (EC) No 1831/2003 (amended)

Sulfuric acid, iron(2+) salt (1:1), heptahydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, iron(2+) salt (1:1), heptahydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Ferrous sulphate, heptahydrate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Sulfuric acid, iron(2+) salt (1:1), heptahydrate: Human health tier I assessment
Hazards Summary · 1 件

A skin, eye, and mucous membrane irritant; May cause gastrointestinal disturbances, shock, cyanosis, coma, and liver damage; [Merck Index] A skin and strong eye irritant; Harmful by ingestion; [Alfa Aesar MSDS] See Ferrous sulfate. See Iron salts, soluble.

Hazard Classes and Categories · 4 件

Acute Tox. 4 (> 99.9%)

Acute toxicity - category 4

Acute toxicity (Oral) - Category 4

Acute Tox. 4 *

安全と保護具

Threshold Limit Values (TLV)1.0 [mg/m3], as Fe (soluble iron salts)
Protective Action Criteria (PAC) · 3 件

2.5 [mg/m3]

27 [mg/m3]

160 [mg/m3]

毒性情報

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.

安全データ

F
10-23
wgk
1
tsca
Yes
rtecs
NO8510000
ridadr
UN3077
毒性
LD50 in mice: 65 mg/kg i.v.; 1.52 g/kg orally (Hoppe)

化学と産業

用途と製造

Uses · 3 件

Used in iron electroplating baths, fertilizers, pesticides, radiation dosimeters, writing ink, process engraving, lithography, dyeing leather, etching aluminum, water treatment, brown ring test for nitrates, and food and feed supplements; Also used as a reducing agent, wood preservative, weed killer, polymerization catalyst, plant food, and hematinic; [Merck Index] Formerly registered in the US as a moss killer/fertilizer for lawns; [NPIRS] Used as a nutritional supplement, processing aid, and stabilizer or thickener for foods; [FDA]

Aluminum Producing [Category: Industry]

Lithography printing [Category: Hobbies]

U.S. Production2023: 75,000 - <500,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesSoil amendments (fertilizers)
Household ProductsInformation on 27 consumer products that contain Ferrous sulfate heptahydrate in the following categories is provided:
General Manufacturing InformationPesticide, Fertilizer, and Other Agricultural Chemical Manufacturing
応用分野 · 8 件

解説FeSO4・7H2O．青緑色の結晶．結晶中で6個の水がFeと結合しているので，[Fe(H2O)6]SO4・H2Oと表すのがよい．水に対する溶解度は71.5 g/100 g(25 ℃)である．七水和物以外に，無水，一，四，五水和物が知られている．鉄を希硫酸に溶かし，56 ℃以下で濃縮すると得られる．水溶液は空気中の酸素で酸化される．硫酸アンモニウムとの複塩はモール塩(Mohr's salt)として知られている．インクや顔料の製造の原料として使われる．硝酸イオンと亜硝酸イオンの検出試薬としても使われる．

用途汎用試薬、調製液原料。

用途過酸化水素比色定量用。

用途調製液原料、染料、媒染剤、インキ、青写真。

用途ベンガラ、し尿処理剤、顔料(紺青、黒インキ、製版)、医薬(鉄剤)、食品添加物(発色剤)

説明§184.1315(a) Ferrous sulfate heptahydrate (iron (II) sulfate heptahydrate, FeS04-7H2O) is prepared by the action of sulfuric acid on iron. It occurs as pale, blueish-green crystals or granules. Progressive heating of ferrous sulfate heptahydrate produces ferrous sulfate (dried). Ferrous sulfate (dried) consists primarily of ferrous sulfate monohydrate (CAS No. 17375-41-6) with varying amounts of ferrous sulfate tetrahydrate (CAS No. 20908-72-9) and occurs as a grayish-white to buff-colored powder.

使用Used in quantitative analysis of nitrates .

一般的な説明A greenish or yellow-brown crystalline solid. Density 15.0 lb /gal. Melts at 64°C and loses the seven waters of hydration at 90°C. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Used for water or sewage treatment, as a fertilizer ingredient.

調製方法 · 1 件

純化方法Crystallise the sulfate from 0.4M H2SO4, or precipitate it from an aqueous solution with EtOH. It is efflorescent in dry air, and is converted to the tetrahydrate at 57o, then to the monohydrate at 65o (or by heating the heptahydrate in a vacuum at 140o). It forms a brown-black complex, FeSO4.NO, with nitric oxide and is used in a qualitative test for nitrates (“brown ring” test).

上流・下流製品情報

下流製品

サプライヤー50 社

国药集团化学试剂有限公司86-21-63210123 · [email protected]
北京华美互利生物化工010-56205725 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]
上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]
補足説明 · 2 件

定義本品は、硫酸(*)の第一鉄塩であり、次の化学式で表される。参照表示名称：硫酸

定義ChEBI: A hydrate that is the heptahydrate form of iron(2+) sulfate. It is used as a source of iron in the treatment of iron-deficiency anaemia (generally in liquid-dosage treatments; for solid-dosage treatments, the monohydrate is normally used).

関連反応

91 件
反応記録を作成

関連ノート

読み込み中…