基本情報
- CAS
7787-32-8- 標準SMILES
[Ba+2].[F-].[F-]- InChIKey
OYLGJCQECKOTOL-UHFFFAOYSA-L- 分子式
- BaF2
- 平均分子量
- 175.32 g/mol
- 単同位体質量
- 175.902053
概要
Barium fluoride is a fluoride of barium that occurs naturally as the mineral frankdicksonite. It is used to make optical components such as lenses, in to production of welding agents, and in aluminum refining. Barium fluoride can also be used as a scintillator for the detection of X-rays and gamma rays. Barium is a metallic alkaline earth metal with the symbol Ba, and atomic number 56. It never occurs in nature in its pure form due to its reactivity with air, but combines with other chemicals such as sulfur or carbon and oxygen to form barium compounds that may be found as minerals. (L214, 408, L205)
名称と識別子
- 優先名称
- Barium fluoride
- IUPAC
- barium(2+) difluoride
- 現地名
- フッ化バリウム
- 英語名
- Barium fluoride
- 分子式
- BaF2
- 分子量
- 175.32
名称と別名
Barium fluoride (BaF2)Baryum fluorureH96A02I53YRefChem:116522barium(2+) ion difluoride232-108-0DTXCID00480527787-32-8Barium fluorideDTXSID4064848barium(2+);difluorideBaryum fluorure [French]
名称をさらに表示
バリウムジフルオリドバリウムフルオリド二フッ化バリウムふっ化バリウム, 99.9%ふっ化バリウム (99.99+%-Ba) PURATREMふっ化バリウム, 99%ふっ化バリウムジフルオロバリウムBariumFlouridebaryumfluorureBarium flupridebariumdifluorideBarium fluoride 99Barium fluoride 99%bariumfluoride(baf2)BARIUM (II) FLUORIDEBarium fluoride, 98%
EINECS 232-108-0UNII-H96A02I53YBarium fluoride, ultra dryBarium fluoride, powder, 98%SCHEMBL1057410Barium fluoride crystal optic disc, 13mm x 2mm, polished both sidesBarium fluoride crystal optic disc, 32mm x 3mm, polished both sidesAKOS015902590
データベース識別子
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 2
- 回転可能結合数
- 0
- 重原子数
- 3
- 形式電荷
- 0
- 複雑度
- 2.8
実験および物理化学的性質
Chemical ClassesMetals -> Metals, Inorganic Compounds
SpringerMaterials Propertiesthermal expansion coefficient
Density4.893 @25 °C
Boiling Point2260 °C @760 [mm Hg]
Melting Point1368 °C
Physical Description
Large Crystals; Dry Powder
Transparent solid; Partially soluble in water (1.607 g/L at 20 deg C); [Merck Index] Colorless or white odorless lump; Slightly soluble in water; [Alfa Aesar MSDS]
物理化学的性質
- 融点
- 1354 °C · 1354 °C
- 沸点
- 2260 °C · 2260 °C(lit.)
- 比重(密度)
- 4.89 g/mL · 4.89 g/mL at 25 °C(lit.)
- 蒸気圧
- 0 Pa · 0Pa at 20℃
- 屈折率
- 1.4741 · 1.4741
- 闪点
- 2260 °C · 2260°C
- 貯蔵温度
- 5 °C · Store at +5°C to +30°C.
- 溶解性
- 1.2 g/リットル · 1.2g/リットル
- 外見
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
This chemical does not meet GHS hazard criteria for 0.4% (1 of 253) of reports.
Warning
H302 (92.1%): Harmful if swallowed [Warning Acute toxicity, oral]
P261, P264, P270, P271, P301+P317, P304+P340, P317, P330, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 253 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Danger
危険有害性情報
Regulatory Information
Chemical: Barium fluoride (BaF2)
Barium fluoride (BaF2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Barium fluoride (BaF2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: Barium fluoride (EC: 232-108-0)
Barium fluoride: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary
Poisonous; [Merck Index] Causes somnolence, dyspnea, and respiratory depression in oral lethal-dose study of rats; Causes urine changes, normocytic anemia, and weight loss in 17-week inhalation study of rats; [RTECS] An irritant; Harmful by ingestion and inhalation; [Alfa Aesar MSDS] See Barium.
Hazard Classes and Categories
Acute Tox. 4 (92.1%)
Acute toxicity (Oral) - Category 3
Acute toxicity (Oral) - Category 3
安全と保護具
Exposure Control and Personal Protection
化学と産業
薬理情報
Metabolism/Metabolites
Barium compounds are absorbed via ingestion and inhalation, the extent of which depends on the individual compound. In the body, the majority of the barium is found in the bone, while small amounts exists in the muscle, adipose, skin, and connective tissue. Barium is not metabolized in the body, but it may be transported or incorporated into complexes or tissues. Barium is excreted in the urine and faeces. (L214)
MeSH Pharmacological ClassificationSubstances used to allow enhanced visualization of tissues.
用途と製造
Uses
Used as a flux in vitreous enamels and to make carbon brushes for electrical motors and generators; Also used in heat-treating metals and glass manufacturing; [Merck Index] Used as detector material in PET cameras; [ChemIDplus]
Heat Treating [Category: Heat or Machine]
Enameling [Category: Hobbies]
Barium fluoride is used to make optical components such as lenses, in to production of welding agents, and in aluminum refining. Barium fluoride can also be used as a scintillator for the detection of X-rays and gamma rays. (L205)
U.S. Production2023: 131,585 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesCatalyst
General Manufacturing Information
Primary Metal Manufacturing
Barium fluoride (BaF2): ACTIVE
応用分野
解説フッ化バリウム,炭酸バリウムをフッ化水素酸で中和すると得られる．無色の等軸晶系結晶．密度4.89 g cm－3．融点1280 ℃，沸点2260 ℃．水に難溶，塩化アンモニウム水溶液に可溶．空気中で熱すると1000 ℃ 以上で分解して酸化バリウムを生じる．ほうろう工業，金属加工に融剤として，また防腐剤，エナメル，光学ガラス，赤外線分光器の窓，シンチレーター(X線，γ線蛍光スクリーン)として用いられる．有毒．森北出版「化学辞典（第2版）
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