ジクロロメチルシラン

用途フェニル基、ビニル基が導入されたジクロロシラン類の合成原料で、ケイ素樹脂改質用に用いられる。

説明Methyl dichlorosilane, is a colorless liquid with a sharp irritating odor. It is a dangerous fire risk, corrosive, and water reactive. The flammable range is wide, from 6% on the lower end to 55% on the upper end. Boiling point is 107°F (41°C), flash point is 15°F (9°C), and ignition temperature is more than 600°F (315°C). Specific gravity is 1.11, which is heavier than water. Vapors are heavier than air and will travel to ignition sources. It is immiscible in water and decomposes on contact to release hydrogen chloride gas. Methyl dichlorosilane is toxic by inhalation and skin absorption; it is irritating to the skin, eyes, and respiratory system. Contact with the material may cause burns to the eyes and skin. The four-digit UN identification number is 1242. The NFPA 704 designation is health 3, flammability 3, and reactivity 2. The white space at the bottom of the diamond has a W with a slash through it, indicating water reactivity. The primary use is in the manufacture of siloxanes, which are straight-chained compounds similar to paraffin hydrocarbons.

使用Dichloromethylsilane is a monomer ('building block') in the production of silicone polymers. An intermediate (starting material) in the production of other organic and inorganic chemicals. In the electronics industry for the production of ultra-pure polysilicon and in the manufacture of semiconductors and photovoltaics.

一般的な説明A colorless fuming liquid with a pungent odor. Flash point: -26°F; Boiling point: 41°C (106°F) . Vapors heavier than air. Vapor and liquid may cause burns. Denser than water and decomposed by water to form hydrochloric acid, a corrosive material.

純化方法Impurities are generally other chloromethyl silanes. Distil it through a conventional Stedman column (p 11) of 20 theoretical plates or more. It should be protected from H2O by storing over P2O5. [Stck & Somieski Chem Ber 52 695 1919, Sauer J Am Chem Soc 68 962 1946, Beilstein 4 IV 4096.]