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ビス[(Z)-9-オクタデセノイルオキシ]水銀(II)

Mercury oleate

HCID 6433251
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基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
1191-80-6
標準SMILES
CCCCCCCC/C=C\CCCCCCCC(=O)[O-].CCCCCCCC/C=C\CCCCCCCC(=O)[O-].[Hg+2]
InChIKey
PCWIWQHAGMGLFA-CVBJKYQLSA-L
分子式
C36H66HgO4
平均分子量
763.5 g/mol
単同位体質量
764.466754

概要

Mercury oleate appears as a yellowish to red liquid/semi-solid or solid mass. Prepared by dissolving yellow mercuric oxide in oleic acid. Contains 24-26% HgO by mass. Insoluble in water. Toxic by ingestion. Used in medicine, antiseptic and antifouling paint.

名称と識別子

優先名称
Mercury oleate
IUPAC
mercury(2+);bis((Z)-octadec-9-enoate)
現地名
ビス[(Z)-9-オクタデセノイルオキシ]水銀(II)
英語名
MERCURY OLEATE
分子式
C36H66HgO4
分子量
763.5

名称と別名

Mercury oleateQuecksilberdioleatOleate of mercuryDioleate de mercureDioleato de mercurioMercuric oleate, solidCaswell No. 546BMERCURIC OLEATEMercury oleate [NF]Oleic acid, mercury(2+) salt9-Octadecenoic acid mercury saltHSDB 1199
名称をさらに表示
ビス[(Z)-9-オクタデセノイルオキシ]水銀(II)オレイン酸水銀オレイン酸水オレイン酸第二水銀mercury(2+)saltoleateofmercurymercurydioleatemercury(2++)saltMERCURY (II) OLEATEmercuricoleate,solidQuecksilber(II)-oleatMERCURY OLEATE USP/EP/BP
EINECS 214-741-4UN1640EPA Pesticide Chemical Code 05210500HPQ7674K9-Octadecenoic acid (Z)-, mercury(2+) salt9-Octadecenoic acid (9Z)-, mercury(2+) saltMERCURIC OLEATE [MI]MERCURY OLEATE [HSDB]

データベース識別子

CAS
1191-80-6

物性

構造計算による物性

極性表面積
80.3 Ų
水素結合供与体数
0
水素結合受容体数
4
回転可能結合数
28
重原子数
41
形式電荷
0
複雑度
228

実験および物理化学的性質

Chemical ClassesMetals -> Mercury Compounds, Inorganic
OdorOdor of oleic acid
Color/FormYellowish-brown, somewhat transparent, ointment-like mass
SolubilityPractically insol in water; slightly sol in alcohol or ether, freely sol in fixed oils
Physical Description · 2 件

Mercury oleate appears as a yellowish to red liquid/semi-solid or solid mass. Prepared by dissolving yellow mercuric oxide in oleic acid. Contains 24-26% HgO by mass. Insoluble in water. Toxic by ingestion. Used in medicine, antiseptic and antifouling paint.

Yellowish-brown slightly transparent solid; Sensitive to light; [Merck Index]

物理化学的性質

融点
-38.8 °C · -38.8°C
外見
液体
水溶解度
2 O;難溶性アルコール、エーテル;固定油に非常に溶ける[MER06] · 不溶性H2O;難溶性アルコール、エーテル;固定油に非常に溶ける[MER06]
EPAの化学物質情報
Mercuric oleate (1191-80-6)

化学的性質

化学的特性Yellowish to red semisolid or solid mass. Soluble in fixed oils; insoluble in water; slightly soluble in alcohol or ether.

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

危険有害性情報

DOT LabelPoison
Fire Hazards · 2 件

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards · 2 件

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.

Hazards SummaryHighly toxic by inhalation, skin absorption, and ingestion; [CAMEO] See Mercury, inorganic compounds and the linked occupational disease.
DOT ID and Guide1640 151
Reactive GroupMetals, Less Reactive
RCRA Requirements · 1 件

D009; A solid waste containing mercury may or may not become characterized as a hazardous waste when subjected to the Toxicity Characteristic Leaching Procedure listed in 40 CFR 261.24, and if so characterized, must be managed as a hazardous waste. /Mercury/

OSHA Standards · 3 件

Permissible Exposure Limit: Table Z-2 8-hr Time Weighted Avg: 0.01 mg/cu m. /Organo alkyl mercury/

Permissible Exposure Limit: Table Z-2 Acceptable Ceiling Concentration: 0.04 mg/cu m. /Organo alkyl mercury/

Vacated 1989 OSHA PEL TWA 0.01 mg/cu m; STEL 0.03 mg/cu m, skin designation, is still enforced in some states. /Mercury (organo) alkyl compounds, as Hg/

Reactivity ProfileMERCURY OLEATE is light sensitive. On standing the mercury is partly reduced to mercurous state or to the metal [Merck].
Atmospheric Standards · 1 件

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Organic mercury is absorbed mainly by the gastrointestinal tract, then distributed throughout the body via the bloodstream. Organic mercury complexes with free cysteine and the cysteine and sulfhydryl groups on proteins such as haemoglobin. These complexes are able to mimic methionine and thus be transported throughout the body, including through the blood-brain barrier and placenta. Organic mercury is metabolized into inorganic mercury, which is eventually excreted in the urine and faeces. (T11)

用途と製造

Uses · 6 件

Used in antiseptics and antifouling paints; [Hawley]

Painting (Pigments, Binders, and Biocides) [Category: Paint]

For Mercuric Oleate (USEPA/OPP PC Code: 052105) there are 0 labels match. /SRP: Not registered for current use in the U.S./

In antiseptics; antifouling paints

THERAP CAT: Has been used as ectoparacitide.

MEDICATION

Methods of ManufacturingCommercial product prepd by dissolving yellow mercuric oxide in oleic acid.
Formulations/Preparations · 2 件

Grades: technical; pharmaceutical.

Contains 24-26% mercuric oxide and about 10% excess oleic acid.

General Manufacturing Information9-Octadecenoic acid (9Z)-, mercury(2+) salt (2:1): ACTIVE

応用分野

使用Antiseptic, antifouling paints.

一般的な説明A yellowish to red liquid/semi-solid or solid mass. Prepared by dissolving yellow mercuric oxide in oleic acid. Contains 24-26% HgO by mass. Insoluble in water. Toxic by ingestion. Used in medicine, antiseptic and antifouling paint.

サプライヤー

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関連反応

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化合物ノート

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このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
PubChem CID
6433251
DTXSID
DTXSID4061591
UNII
00HPQ7674K
EC Number
214-741-4
Nikkaji
J4.495D

Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Mercuric oleate is included on this list.

DOT Emergency Guidelines · 5 件

/GUIDE 151: SUBSTANCES - TOXIC (Non-combustible)/ Fire or Explosion: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.

/GUIDE 151: SUBSTANCES - TOXIC (Non-combustible)/ Health: Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

/GUIDE 151: SUBSTANCES - TOXIC (Non-combustible)/ Public Safety: CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Keep unauthorized personnel away. Stay upwind. Keep out of low areas.

/GUIDE 151: SUBSTANCES - TOXIC (Non-combustible)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible.

For more DOT Emergency Guidelines (Complete) data for MERCURIC OLEATE (8 total), please visit the HSDB record page.

DOT Hazard Classification · 6 件

Mercuric oleate

Severe marine pollutant

Mercury oleate

Severe marine pollutant

Mercury oleate

UN1640

安全と保護具

Fire FightingExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

First Aid · 2 件

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

General First Aid:

Exposure Control and Personal Protection · 2 件

· Wear positive pressure self-contained breathing apparatus (SCBA).

0.02 [mg/m3], as Hg, inhalable fraction[German Research Foundation (DFG)]

Fire Fighting Procedures · 1 件

If material involved in fire: Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as in fog. Use foam, dry chemical, or carbon dioxide.

Storage ConditionsPROTECT FROM LIGHT.
Nonfire Spill ResponseExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Disposal Methods · 1 件

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Preventive Measures · 2 件

If material not involved in fire: Keep material out of water sources and sewers.

Personnel protection: Avoid breathing dusts, and fumes from burning material. Keep upwind. Avoid bodily contact with the material. ... Wash away any material which may have contacted the body with copious amounts of water or soap and water. ... If contact with the material anticipated, wear appropriate chemical protective clothing.

Isolation and Evacuation · 2 件

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

Immediate precautionary measure

Minimum Risk LevelChronic Inhalation: 0.0002 mg/m3 (L134)
Threshold Limit Values (TLV) · 2 件

0.02 [mg/m3], as Hg

8 hr Time Weighted Avg (TWA): 0.01 mg/cu m; 15 min Short Term Exposure Limit (STEL): 0.03 mg/cu m, skin /Mercury, alkyl cmpds, as Hg/

毒性情報

TreatmentMercury poisoning is treated by immediate decontamination and chelation therapy using DMSA, DMPS, DPCN, or dimercaprol. (A7)
Health Effects · 1 件

Mercury mainly affects the nervous system. Exposure to high levels of metallic, inorganic, or organic mercury can permanently damage the brain, kidneys, and developing fetus. Effects on brain functioning may result in irritability, shyness, tremors, changes in vision or hearing, and memory problems. Acrodynia, a type of mercury poisoning in children, is characterized by pain and pink discoloration of the hands and feet. Mercury poisoning can also cause Hunter-Russell syndrome and Minamata disease. (L7)

Adverse EffectsNeurotoxin - Sensorimotor
Exposure RoutesOral (L7) ; inhalation (L7) ; dermal (L7)
Toxicity Summary · 1 件

High-affinity binding of the divalent mercuric ion to thiol or sulfhydryl groups of proteins is believed to be the major mechanism for the activity of mercury. Through alterations in intracellular thiol status, mercury can promote oxidative stress, lipid peroxidation, mitochondrial dysfunction, and changes in heme metabolism. Mercury is known to bind to microsomal and mitochondrial enzymes, resulting in cell injury and death. For example, mercury is known to inhibit aquaporins, halting water flow across the cell membrane. It also inhibits the protein LCK, which causes decreased T-cell signalling and immune system depression. Mercury is also believed to inhibit neuronal excitability by acting on the postsynaptic neuronal membrane. It also affects the nervous system by inhibiting protein kinase C and alkaline phosphatase, which impairs brain microvascular formation and function, as well as alters the blood-brain barrier. Organic mercury exerts developmental effects by binding to tubulin, preventing microtubule assembly and causing mitotic inhibition. Mercury also produces an autoimmune response, likely by modification of major histocompatibility complex (MHC) class II molecules, self peptides, T-cell receptors, or cell-surface adhesion molecules. (L7, A8, A25, A26)

Signs and SymptomsCommon symptoms include peripheral neuropathy (presenting as paresthesia or itching, burning or pain), skin discoloration (pink cheeks, fingertips and toes), edema (swelling), and desquamation (dead skin peels off in layers). (A5)
Carcinogen ClassificationNo indication of carcinogenicity (not listed by IARC). (L135)

法規制情報

RCRA Requirements · 1 件

D009; A solid waste containing mercury may or may not become characterized as a hazardous waste when subjected to the Toxicity Characteristic Leaching Procedure listed in 40 CFR 261.24, and if so characterized, must be managed as a hazardous waste. /Mercury/

Atmospheric Standards · 1 件

Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Mercuric oleate is included on this list.

Clean Water Act RequirementsToxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Mercury and cmpd/
State Drinking Water Guidelines(AZ) ARIZONA 3 ug/l /Mercury/
Federal Drinking Water StandardsEPA 2 ug/l /Mercury/
Federal Drinking Water GuidelinesEPA 2 ug/l /Mercury/

安全データ

tsca
TSCA listed
ridadr
UN 1640
hazard_class
6.1
packing_group
II
有毒物質データの
1191-80-6(Hazardous Substances Data)