食用 赤色 104号

Acid Red 92

HCID 6433718CAS 18472-87-2

基本情報

標準SMILES
O=C1OC2(c3cc(Br)c([O-])c(Br)c3Oc3c2cc(Br)c([O-])c3Br)c2c(Cl)c(Cl)c(Cl)c(Cl)c21.[Na+].[Na+]
InChIKey
OOYIOIOOWUGAHD-UHFFFAOYSA-L
分子式
C20H2Br4Cl4Na2O5
平均分子量
829.6 g/mol
単同位体質量
823.51852

名称と識別子

優先名称
Acid Red 92
IUPAC
disodium;2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate
現地名
食用 赤色 104号
英語名
Acid Red 92
分子式
C20H5Br4Cl4NaO5
分子量
809.66

名称と別名

Acid red 92RefChem:552645ACID RED 92 [INCI]18472-87-2Phloxin BEosine BlueCyanosin BMFCD00070627Phloxine PWater Pink 2sodium 2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3-oxo-3H-spiro[isobenzofuran-1,9'-xanthene]-3',6'-bis(olate)Daiwa Red 45
名称をさらに表示
アシッド レッド 92食用 赤色 104号エオシンIブルーイッシュフロキシンBインペリアルレッドC.I.アシッドレッド91エオシンブルイシュ食用赤色104号テトラクロロテトラブロモフルオレセインビス[2-(2,4,5,7-テトラブロモ-3-オキソ-6-ヒドロキシ-3H-キサンテン-9-イル)-3,4,5,6-テトラクロロ安息香酸]鉛(II)シアノシンエオシンスカーレット2',4',5',7'-テトラブロモ-4,5,6,7-テトラクロロ-3',6'-ビス(ソジオオキシ)スピロ[イソベンゾフラン-1(3H),9'-[9H]キサンテン]-3-オンエオシンBビス[2-(2,4,5,7-テトラブロモ-6-ヒドロキシ-3-オキソ-3H-キサンテン-9-イル)-3,4,5,6-テトラクロロ安息香酸]鉛(II)C.I.アシッドレッド922-(4,5-ジブロモ-3-オキソ-6-ソジオオキシ-3H-キサンテン-9-イル)-3,6-ジクロロ安息香酸ナトリウムホロキシンPbフードレッドNo.104ノパリンGCI 45410PHLOXINE BPHLOXINERED 28CI 45405AKA231d&credred104SUREDYE
Cyanosin (acid dye)Orient Water Pink 2Food Red 104Aizen Acid Phloxine PB3427 Veri Pur PinkD and C Red No. 28Food Dye Red No. 104Red 104

データベース識別子

CAS
18472-87-2
PubChem CID
6433718
DTXSID
DTXSID1031090
Nikkaji
J4.465B

物性

構造計算による物性

極性表面積
81.7 Ų
水素結合供与体数
0
水素結合受容体数
5
回転可能結合数
0
重原子数
35

実験および物理化学的性質

Physical Description · 2 件

Liquid; Wet Solid; Other Solid

Brick red to brown solid; [Merck Index] Dark red powder; [Sigma-Aldrich MSDS]

物理化学的性質

融点
250 °C · >250°C
比重(密度)
0.871 · 0.871[at 20℃]
蒸気圧
0 Pa · 0Pa at 25℃
貯蔵温度
Store at RT.
溶解性
100 g/リットル · 100g/リットル
外見
粉体・固形

化学的性質

化学的特性red-brown powder

安全と法規制

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 7.3% (17 of 234) of reports.

Warning

H319 (56.4%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H373 (31.6%): May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure];H412 (38%): Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P260, P264+P265, P273, P280, P305+P351+P338, P319, P337+P317, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 234 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 17 of 234 reports by companies.;There are 8 notifications provided by 217 of 234 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 4 件

Chemical: Spiro[isobenzofuran-1(3H),9'-[9H]xanthen]-3-one, 2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3',6'-dihydroxy-, disodium salt

Spiro[isobenzofuran-1(3H),9'-[9H]xanthen]-3-one, 2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3',6'-dihydroxy-, sodium salt (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Spiro[isobenzofuran-1(3H),9'-[9H]xanthen]-3-one, 2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3',6'-dihydroxy-, sodium salt (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 15-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/17402

Acid Red 92: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1 件

Causes no skin and mild to moderate eye irritation in rabbits; Not a skin sensitizer in a local lymph node assay (LLNA) of mice; Mild maternal toxicity but no embryotoxicity or teratogenicity observed in rats at 250 mg/kg/day; [SCCS (Scientific Committee on Consumer Safety), Opinion on Acid Red 92, 27 March 2012] May cause irritation; [Sigma-Aldrich MSDS] See Rose Bengal.

Hazard Classes and CategoriesEye Irrit. 2 (56.4%);STOT RE 2 (31.6%);Aquatic Chronic 3 (38%)

法規制情報

Regulatory Information · 4 件

Chemical: Spiro[isobenzofuran-1(3H),9'-[9H]xanthen]-3-one, 2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3',6'-dihydroxy-, disodium salt

Spiro[isobenzofuran-1(3H),9'-[9H]xanthen]-3-one, 2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3',6'-dihydroxy-, sodium salt (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Spiro[isobenzofuran-1(3H),9'-[9H]xanthen]-3-one, 2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3',6'-dihydroxy-, sodium salt (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 15-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/17402

Acid Red 92: Does not have an individual approval but may be used under an appropriate group standard

安全データ

wgk
2
tsca
TSCA listed
rtecs
LM5900000
毒性
LD50 orally in Rabbit: 2870 mg/kg
hs_code
32041200
risk_code
36

化学と産業

用途と製造

Uses · 2 件

Used as a histological and bacterial stain, and colorant for cosmetics, drugs, inks, lacquers, wool, nylon, jute, leather, silk, and acid dyeable acrylics; [Merck Index] Used in hair dye formulations; [SCCS (Scientific Committee on Consumer Safety), Opinion on Acid Red 92, 27 March 2012] Permitted for use as an inert ingredient in non-food pesticide products; [EPA]

Painting (Pigments, Binders, and Biocides) [Category: Paint];Leather Tanning and Processing [Category: Industry];Textiles (Printing, Dyeing, or Finishing) [Category: Industry];Dressing Hair [Category: Other]

U.S. Production2022: 1,200 lb;2021: 8 lb;2020: 49,700 lb
Consumer UsesPigment;Not Known or Reasonably Ascertainable
Household ProductsInformation on 6 consumer products that contain D&C Red #28 in the following categories is provided:;• Personal Care
Use ClassificationCosmetics -> Cosmetic colorant; Hair dyeing
General Manufacturing InformationSpiro[isobenzofuran-1(3H),9'-[9H]xanthen]-3-one, 2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3',6'-dihydroxy-, sodium salt (1:2): ACTIVE

応用分野

用途印刷インキ、化粧品原料。

使用Phloxine B acts as the sensitizers of dye-sensitized solar cells. Also, it is a fluorescein photoactive dye. Dyes and metabolites, Environmental Testing.

調製方法

製造方法the Resorcinol and 4,5,6,7-Tetrachloroisobenzofuran-1,3-dione condensation, get 3,4,5,6-Tetrachlorophthalic acid four bromination, and translated into sodium salt.

サプライヤー50 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
上海康朗生物科技有限公司021-61998208 18217752821 · [email protected]
武汉欣扬瑞和化学科技有限公司13720274133 · [email protected]
Baoji Guokang Healthchem co.,ltd+8615604608665 15604608665 · [email protected]

補足説明

定義本品は、平成15年厚労省令第126号に示される赤色104号の(1)又はそのアルミニウムレーキ又はそのバリウムレーキである。

関連反応

1 件

関連ノート

読み込み中…