テトラエチルアンモニウムヒドロキシド (10%水溶液)
テトラエチルアンモニウムヒドロキシド (10%水溶液) · テトラエチルアンモニウムヒドロキシド (10%水溶液) [IPC試薬] · テトラエチルアンモニウムヒドロキシド · N,N,N-トリエチルエタンアミニウム·ヒドロキシド · テトラエチルアミニウム·ヒドロキシド · テトラエチルアンモニウム·ヒドロキシド · テトラエチルアンモニウム ヒドロキシド · 水酸化テトラエチルアンモニウム
識別子と物理属性
| CAS No. | 77-98-5 |
|---|---|
| 分子式 | C8H20N.HO |
| 平均分子量 | 147.26 g/mol |
| 単同位体質量 | 147.16231429 g/mol |
| SMILES | CC[N+](CC)(CC)CC.[OH-] |
| InChIKey | LRGJRHZIDJQFCL-UHFFFAOYSA-M |
| PubChem CID | 6509 |
| EC No. | 201-073-3 |
| DTXSID | DTXSID30883222 |
| 現地名 | テトラエチルアンモニウムヒドロキシド (10%水溶液) |
化学・物理的性質
| 極性表面積 | 1 |
|---|---|
| 水素結合供与体数 | 1 |
| 水素結合受容体数 | 1 |
| 回転可能結合数 | 4 |
| 重原子数 | 10 |
| 形式電荷 | 0 |
| 複雑度 | 47.5 |
| 物質分類 | Nitrogen Compounds -> Quaternary Amines |
| Physical Description | LiquidAqueous solution: Colorless odorless liquid[Merck Index] 35% Aqueous solution: Colorless to pale yellow liquid[Alfa Aesar MSDS] |
| 融点 | -98C |
| 沸点 | 110 °C |
| 密度 | 1.023 g/mL at 25 °C |
| 屈折率 | n20/D 1.422 |
| 引火点 | 11 °C |
| 貯蔵条件 | 2-8°C |
| 外観・状態 | 解決 |
| 色 | 無色～黄色 |
| pH | >13 (H2O, 20°C) |
| 溶解度 | 溶ける |
| Merck | 14,9201 |
| BRN | 3912961 |
| 安定性 | 安定していますが、空気中の二酸化炭素を吸収します |
| InChI | 1S/C8H20N.H2O/c1-5-9(6-2,7-3)8-4/h5-8H2,1-4H31H2/q+1/p-1 |
| InChIKey | LRGJRHZIDJQFCL-UHFFFAOYSA-M |
| SMILES | [OH-].CC[N+](CC)(CC)CC |
| CAS データベース | 77-98-5(CAS DataBase Reference) |
| EPAの化学物質情報 | Tetraethyl ammonium hydroxide (77-98-5) |
化学的特性
colourless liquid
安全性と法規制
| GHS 分類 | DangerH290 (15.3%): May be corrosive to metals [Warning Corrosive to Metals]P234, P260, P262, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P308+P316, P316, P317, P319, P321, P330, P361+P364, P363, P390, P391, P405, P406, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 301 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.H302: Harmful if swallowed [Warning Acute toxicity, oral] |
|---|---|
| 規制情報 | Chemical: Ethanaminium, N,N,N-triethyl-, hydroxideEthanaminium, N,N,N-triethyl-, hydroxide (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Ethanaminium, N,N,N-triethyl-, hydroxide (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 09-10-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/10763Ethanaminium, N,N,N-triethyl-, hydroxide: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
| その他の安全情報 | IMAP assessments - Ethanaminium, N,N,N-triethyl-, hydroxide: Human health tier II assessment |
| 有害性の概要 | Subcutaneous LDLo (mouse) = 107 mg/kg[RTECS] The free base exists only in solution or as hydratesA strong base that absorbs carbon dioxide from the air[Merck Index] 35% Aqueous solution: Causes burns[Alfa Aesar MSDS] See Tetraethylammonium bromide. |
| Hazard Classes and Categories | Met. Corr. 1 (15.3%)Acute toxicity (ingestion) - category 4 |
| Protective Action Criteria (PAC) | 0.90 [mg/m3]9.9 [mg/m3]59 [mg/m3] |
| 有害作用 | Dermatotoxin - Skin burns. |
| F | 9-34 |
| 水環境危害等級（WGK） | 3 |
| TSCA 収載状態 | TSCA listed |
| RTECS 番号 | KH3150000 |
| 輸送番号（UN） | UN 3286 3/PG 2 |
| 税関コード | 29239000 |
| 危険文句（R） | 34-51-39/23/24/25-23/24/25-11-35 |
| 化審法 | (2)-186 |
| 安衛法 | 有機溶剤中毒予防規則:第2種有機溶剤,57,57-2 |
| 消防法 | 危-4-1-S-II |
| 危険表示 | C,N,T,F |
| 安全措置（S） | 7-16-26-36/37/39-45-61-36/37 |
| 危険等級 | 8Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 3 OralEye Dam. 1Flam. Liq. 2Skin Corr. 1BSTOT SE 1 |
| 包装等級 | II |
| 貯蔵分類 | 3 - Flammable liquids |
用途
使用
Tetraethylammonium hydroxide is a strong organic base and finds applications in photovoltaic chemicals, advanced ceramics, flat panel display chemicals, selective etching and transesterification catalysts. Its solution (35 wt. % in H2O) may be used as an organic structure-directing agent (SDA)/template in the synthesis of mesoporous molecular sieves and zeolite samples.
一般的な説明
The product is 20wt.% solution of tetraethylammonium hydroxide (TEA hydroxide, TENOH) in H2O. TEA hydroxide is a quaternary ammonium hydroxide (QAH). It participates in the synthesis of zeolite beta. TENOH peptized titania aqueous sols have been employed in the preparation of nanocrystalline anatase films.