ジフェニルジフルオロシラン

Difluorodiphenylsilane

HCID 67557

基本情報

CAS
312-40-3
標準SMILES
F[Si](F)(c1ccccc1)c1ccccc1
InChIKey
BOMPXIHODLVNMC-UHFFFAOYSA-N
分子式
C12H10F2Si
平均分子量
220.29 g/mol
単同位体質量
220.05198329

名称と識別子

優先名称
Difluorodiphenylsilane
IUPAC
difluoro(diphenyl)silane
現地名
ジフェニルジフルオロシラン
英語名
DIPHENYLDIFLUOROSILANE
分子式
C12H10F2Si
分子量
220.29

名称と別名

DifluorodiphenylsilaneDiphenyldifluorosilane312-40-3Silane, difluorodiphenyl-Benzene, 1,1'-(difluorosilylene)bis-V3Y7X7Y43CEINECS 206-226-8NSC 136542NSC-136542DTXSID20598011,1'-(DIFLUOROSILYLENE)BIS(BENZENE)1,1'-(Difluorosilylene)bis[benzene]
名称をさらに表示
ジフェニルジフルオロシランジフルオロジフェニルシラン4-[ジフルオロ(フェニル)シリル]ベンゼンDK733difluorodiphenyl-silanifluoro(diphenyl)silaneDifluorodiphenylsilane97%Benzene,1,1'-(difluorosilylene)bis-Diphenyl difluorosilanegas cylinder
Silane, difluorodiphenylRefChem:587457DTXCID7038311Benzene, 1,1'(difluorosilylene)bis206-226-8difluoro(diphenyl)silanediphenyl difluorosilaneDiphenylsilane difluoride

データベース識別子

CAS
312-40-3
PubChem CID
67557
DTXSID
DTXSID2059801
UNII
V3Y7X7Y43C
EC Number
206-226-8
Nikkaji
J130.544A

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
2
重原子数
15

実験および物理化学的性質

Chemical ClassesToxic Gases & Vapors -> Fluorosilanes
SpringerMaterials Properties29Si nuclear magnetic resonance spectrum
Physical DescriptionClear to straw-colored liquid with an acrid odor; [Gelest MSDS]

物理化学的性質

沸点
159 °C · 159°C 50mm
比重(密度)
1.145 · 1.145
屈折率
1.522 · 1.522
闪点
87 °C · 87°C
貯蔵温度
2 · under inert gas (nitrogen or Argon) at 2-8°C
溶解性
エーテルに溶ける。

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P354+P338, P317, P319, P321, P332+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 38 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazards SummaryReacts with water forming methanol and hydrogen fluoride; A severe eye irritant; A skin irritant that may cause delayed tissue necrosis; [Gelest MSDS]
Hazard Classes and CategoriesSkin Irrit. 2 (100%)

毒性情報

Adverse EffectsDermatotoxin - Skin burns.

安全データ

tsca
TSCA listed
ridadr
1760
hs_code
2931900090
risk_code
34
hazard_code
C
hazard_note
Corrosive

化学と産業

用途と製造

General Manufacturing InformationBenzene, 1,1'-(difluorosilylene)bis-: ACTIVE
応用分野 · 1 件

使用A moisture insensitive equivalent of diphenyldichlorosilane that is more reactive toward nucleophiles. Source of phenyl group in the Hiyama coupling reaction. More stable to electrophilic aromatic substitution than diphenyldichlorosilane. Eaborn reported that fluorosilanes are more reactive toward organometallic reagents than the corresponding chlorosilanes, and therefore more suited for preparation of sterically hindered organosilanes.

調製方法 · 1 件

製造方法commercially available. Readily prepared by oxidation of diphenylsilane with CuF2, or by treatment of diphenyldichlorosilane with HF, ZnF2, NaBF4, or (NH4)2SiF6. Rate enhancements of the chlorine–fluorine exchange have been achieved with ultrasound and addition of water. Diethoxydiphenylsilane and related structures are converted to diphenyldifluorosilane with 48% HF(aq).

サプライヤー63 社

上海康恩博医药科技有限公司17510465506 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
毕佳索(上海毕得医药科技股份有限公司)400-6005915 · [email protected]
上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]

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