Phenyltrimethylsilane (HCID 69849)

名称と識別子

優先名称: Phenyltrimethylsilane
IUPAC: trimethyl(phenyl)silane
現地名: トリメチルフェニルシラン
英語名: PHENYLTRIMETHYLSILANE
分子式: C9H14Si
分子量: 150.29

名称と別名

Phenyltrimethylsilane768-32-1TrimethylphenylsilaneSilane, trimethylphenyl-(Trimethylsilyl)benzeneBenzene, (trimethylsilyl)-PX1SG1Q5YPEINECS 212-192-5NSC 96828NSC-96828DTXSID6061109RefChem:861845

名称をさらに表示

トリメチルフェニルシラントリメチルシリルベンゼントリメチル(フェニル)シラン(トリメチルシリル)ベンゼンフェニルトリメチルシラン(フェニル)トリメチルシランフェニルトリメチルシラン, 99%DK899DK393DKSI048DKFELEX0238Co-Formula CFS-321TriMethyl(phenyl)silatrimethylphenyl-silanphenyltrimethylsiloxane

DTXCID9047916212-192-5trimethyl(phenyl)silanes1377576188-55-1NSC96828MFCD00008271MFCD01324274

データベース識別子

CAS: 768-32-1
PubChem CID: 69849
DTXSID: DTXSID6061109
UNII: PX1SG1Q5YP
EC Number: 212-192-5
Nikkaji: J109.305C

物性

構造計算による物性

極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 1
重原子数: 10
形式電荷: 0
複雑度: 95

物理化学的性質

融点: 166 · 166-169 °C
沸点: 168 · 168-170 °C(lit.)
比重(密度): 0.873 g/mL · 0.873 g/mL at 25 °C(lit.)
屈折率: 20 · n20/D 1.491(lit.)
闪点: 112 °F · 112 °F
貯蔵温度: Inert atmosphere,Room Temperature
外見: clear liquid
色: Colorless to Almost colorless
比重: 0.873 · 0.873
水溶解度: 水と混和しないか、または混合しにくい。
BRN: 1855012 · 1855012
InChI: 1S/C9H14Si/c1-10(2,3)9-7-5-4-6-8-9/h4-8H,1-3H3
InChIKey: KXFSUVJPEQYUGN-UHFFFAOYSA-N
SMILES: C[Si](C)(C)c1ccccc1
CAS データベース: 768 · 768-32-1(CAS DataBase Reference)
NISTの化学物質情報: Silane, trimethylphenyl-(768-32-1)
EPAの化学物質情報: Silane, trimethylphenyl- (768-32-1)

化学的性質

化学的特性CLEAR COLOURLESS TO GREEN LIQUID

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H226 (97.8%): Flammable liquid and vapor [Warning Flammable liquids]；H315 (13%): Causes skin irritation [Warning Skin corrosion/irritation]；H318 (84.8%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H319 (13%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H413 (84.8%): May cause long lasting harmful effects to aquatic life [Hazardous to the aquatic environment, long-term hazard]

P210, P233, P240, P241, P242, P243, P264, P264+P265, P273, P280, P302+P352, P303+P361+P353, P305+P351+P338, P305+P354+P338, P317, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P235, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Hazard Classes and CategoriesFlam. Liq. 3 (97.8%)；Skin Irrit. 2 (13%)；Eye Dam. 1 (84.8%)；Eye Irrit. 2 (13%)；Aquatic Chronic 4 (84.8%)

安全データ

wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 3
hs_code: 29319090
risk_code: 10-41-36/37/38
消防法: 危-4-2-III
hazard_code: Xi
safety_code: 16-26-36/39-37/39
hazard_class: 3
packing_group: III
Hazard Classifications: Aquatic Chronic 4Eye Dam. 1Flam. Liq. 3
ストレージクラス: 3 - Flammable liquids

化学と産業

用途と製造

General Manufacturing InformationBenzene, (trimethylsilyl)-: ACTIVE

応用分野

使用It is employed as intermediate for pharmaceutical and organic synthesis.

調製方法 · 1 件

純化方法Fractionally distil the silane at atmospheric or reduced pressure (Podbielniak column p 11) and estimate it by GC with a column packed with Silicone Fluid No 710 on Chromosorb P support. [Gilman et al. J Org Chem 18 1743 1953, Maienthal et al. J Am Chem Soc 76 6392 1954, House & Respess J Organomet Chem 4 95 1965, Roberts et al. J Am Chem Soc 71 2923 1949, Freiser et al. J Am Chem Soc 75 2821 1953, Beilstein 16 I 525, 16 II 605, 16 III 1198, 16 IV 1361.]