2,3-ジアミノナフタレン

2,3-Diaminonaphthalene

HCID 69872CAS 771-97-1

基本情報

標準SMILES
Nc1cc2ccccc2cc1N
InChIKey
XTBLDMQMUSHDEN-UHFFFAOYSA-N
分子式
C10H10N2
平均分子量
158.2 g/mol
単同位体質量
158.08439832

名称と識別子

優先名称
2,3-Diaminonaphthalene
IUPAC
naphthalene-2,3-diamine
現地名
2,3-ジアミノナフタレン
英語名
2,3-diaminonaphthalene
分子式
C10H10N2
分子量
158.2

名称と別名

2,3-Diaminonaphthalene771-97-12,3-Naphthalenediamine2BNZ6BRS87DTXSID4061121NSC-62692RefChem:441954DTXCID6047947212-241-0naphthalene-2,3-diamine2,3-NaphthylenediamineMFCD00004116
名称をさらに表示
2,3-ジアミノナフタレン2,3-ナフタレンジアミンナフチレンジアミン-(2,3)2,3-ナフチレンジアミンナフタレン-2,3-ジアミン2,3-ジアミノナフタレン [生化学用]2,3‐ジアミノナフタレン2,3-ジアミノナフタレン, NO測定用2,3-ジアミノナフタレン, 97%DAND1JACS-771-97-1NAPHTHALENEDIAMINETIMTEC-BB SBB0001272,3-DiaminonaphthaL
UNII-2BNZ6BRS87EINECS 212-241-0NSC 62692CCRIS 83992,3-diaminonapthaleneDANSCHEMBL139321STK396657

データベース識別子

CAS
771-97-1
PubChem CID
69872
DTXSID
DTXSID4061121
UNII
2BNZ6BRS87
EC Number
212-241-0
Nikkaji
J79.947E

物性

構造計算による物性

XLogP
1.9
極性表面積
52 Ų
水素結合供与体数
2
水素結合受容体数
2
回転可能結合数
0
重原子数
12

実験および物理化学的性質

Chemical ClassesOther Classes -> Naphthalenes
LogP1.54
Vapor Pressure0.0000293 [mmHg]
Physical DescriptionPowder; [Aldrich MSDS]

物理化学的性質

融点
197 · 197-203 °C
沸点
273.29 °C · 273.29°C (rough estimate)
比重(密度)
1.0968 · 1.0968
屈折率
1.6392 · 1.6392 (estimate)
貯蔵温度
2 · Keep in dark place,Inert atmosphere,2-8°C
溶解性
50 mg/mL · ピリジン:可溶50mg/mL

化学的性質

化学的特性colourless to white crystalline powder

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H302 (97.9%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory InformationChemical: 2,3-Naphthalenediamine
Hazards SummaryAn irritant; Harmful by ingestion; Targets the bladder; [Aldrich MSDS] See 1,5-Naphthalenediamine. See beta-Naphthylamine and alpha-Naphthylamine.
Hazard Classes and CategoriesAcute Tox. 4 (97.9%)

安全データ

F
8-10-23
wgk
3
tsca
TSCA listed
ridadr
2811
hs_code
29215900
risk_code
22-36/37/38-45

化学と産業

用途と製造

General Manufacturing Information2,3-Naphthalenediamine: ACTIVE
応用分野 · 2 件

説明2,3-Diaminonaphthalene is a highly selective colorimetric and fluorometric reagent for selenium detection and also used for the fluorometric determination of nitrite. It is also useful for detection of ketones and alpha-keto acids.2,3-Diaminonaphthalene reacts with nitrosonium, which is formed from nitrite at low pH, to form the fluorescent dye 1 H-naphthotriazole. This method can be used to detect 10 nM to 10 uM of nitrite (NO2-) and is compatible with 96-well format.Fluorometric probe for nitriteQuantify 10 nM to 10 uM of nitriteYellow orange solid soluble in DMSO

使用In a reaction similar to that of DAF-FM , 2,3- diaminonaphthalene (D-7918) reacts with the nitrosonium cation that forms spontaneously from NO to form the fluorescent product 1H-naphthotriazole.Using 2,3-diaminonaphthalene, researchers have developed a rapid, quantitative fluorometric assay that can detect from 10 nM to 10 μM nitrite and is compatible with a 96-well microplate format.

調製方法

純化方法Crystallise the diamine from water, or dissolve it in 0.1M HCl, by heating to 50o. After cooling, the solution is extracted with decalin to remove fluorescent impurities and centrifuged. [Beilstein 13 IV 346.]

サプライヤー50 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
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Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]
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Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]

関連反応

24 件

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