基本情報
- CAS
26571-79-9- 標準SMILES
Clc1ccc([Si](Cl)(Cl)Cl)cc1- InChIKey
ABADVTXFGWCNBV-UHFFFAOYSA-N- 分子式
- C6H4Cl4Si
- 平均分子量
- 246 g/mol
- 単同位体質量
- 243.88363738
概要
Chlorophenyltrichlorosilane is a colorless to pale yellow liquid with a pungent odor. The material will burn though it may take some effort to ignite. It is decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue.
名称と識別子
- 優先名称
- 4-Chlorophenyltrichlorosilane
- IUPAC
- trichloro-(4-chlorophenyl)silane
- 現地名
- トリクロロ(4-クロロフェニル)シラン
- 英語名
- Chlorophenyltrichlorosilane
- 分子式
- C6H4Cl4Si
- 分子量
- 245.99
名称と別名
825-94-5Silane, trichloro(4-chlorophenyl)-p-ChlorophenyltrichlorosilaneChlorophenyltrichlorosilaneTrichloro(4-chlorophenyl)silane4-ChlorophenyltrichlorosilaneTrichloro(p-chlorophenyl)silane2Q5LG5ZGM4Benzene, 1-chloro-4-(trichlorosilyl)-EINECS 212-551-6DTXSID80611831-CHLORO-4-(TRICHLOROSILYL)BENZENE
名称をさらに表示
トリクロロ(4-クロロフェニル)シラン(4-クロロフェニル)トリクロロシランtrichloro(chlorophenyl)silaneTRICHLORO(4-CHLOROPHENHYL)SILANE, 97%ChlorophenyltrichlorosilanemixedisomersCHLOROPHENYLTRICHLOROSILANE, MIXED M,P-ISOMERS
RefChem:522054DTXCID4048301212-551-6trichloro-(4-chlorophenyl)silaneBenzene,1-chloro-4-(trichlorosilyl)-C6H4Cl4SiUNII-2Q5LG5ZGM44-Chlorophenyl Trichlorosilane
データベース識別子
- CAS
26571-79-9、825-94-5- PubChem CID
- 70002
- DTXSID
DTXSID8061183- UNII
- 2Q5LG5ZGM4
- EC Number
- 212-551-6
- Nikkaji
- J195.082G
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 0
- 回転可能結合数
- 0
- 重原子数
- 11
- 形式電荷
- 0
- 複雑度
- 125
実験および物理化学的性質
Chemical ClassesCorrosives
SpringerMaterials Properties13C nuclear magnetic resonance spectrum
Physical Description
Chlorophenyltrichlorosilane is a colorless to pale yellow liquid with a pungent odor. The material will burn though it may take some effort to ignite. It is decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue.
物理化学的性質
- 融点
- 0 °C · <0°C
- 沸点
- 105 °C15 · 105 °C15 mm Hg(lit.)
- 比重(密度)
- 1.424 g/mL · 1.424 g/mL at 25 °C(lit.)
- 屈折率
- 20 · n20/D 1.544(lit.)
- 闪点
- 230 °F · >230 °F
- 比重
- 1.432 · 1.432
- EPAの化学物質情報
- Silane, trichloro(4-chlorophenyl)- (825-94-5)
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Danger
H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory.
危険有害性情報
Hazards IdentificationWater-reactive material (WR)
Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelCorrosive
Fire Hazards
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
· Combustible material: may burn but does not ignite readily.
Health Hazards
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.
DOT ID and Guide1753 156
Reactive GroupChlorosilanes
Reactivity AlertsWater-Reactive
Reactivity Profile
Chlorosilanes, such as CHLOROPHENYLTRICHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.
DOT Hazard Classification
Chlorophenyltrichlorosilane
Marine pollutant
Chlorophenyltrichlorosilane
UN1753
Class 8 Corrosive material (49 eCFR § 173.136)
PG II: the degree of danger presented by the material is medium
Air and Water Reactions
Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Hydrogen Chloride gas will be created in 1.9 minutes. Experimental details are in the following: "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook", ANL/DIS-09-2, D.F. Brown, H.M. Hartmann, W.A. Freeman, and W.D. Haney, Argonne National Laboratory, Argonne, Illinois, June 2009.
Hazard Classes and Categories
Skin Corr. 1B (100%)
Corrosives, Reactive agents - 1st degree
安全と保護具
Fire FightingExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
General First Aid:
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Isolation and Evacuation
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Immediate precautionary measure
When spilled in water
When spilled in water
Toxic-by-Inhalation (TIH) GasHCl - when spill Chlorophenyltrichlorosilane into water.
Personal Protective Equipment (PPE)Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Emergency Response Planning Guidelines· Note: Most foams will react with the material and release corrosive/toxic gases.
安全データ
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- UN 1753
- risk_code
- 34
- hazard_code
- C
- safety_code
- 26-36/37/39-45
- hazard_class
- 8
- packing_group
- II
化学と産業
用途と製造
General Manufacturing InformationBenzene, 1-chloro-4-(trichlorosilyl)-: ACTIVE
上流・下流製品情報
下流製品
サプライヤー26 社
湖北成丰化工有限公司13125175253 · [email protected]
温州共赢化学有限公司+86-0086-577-64498589 +86-15355981851 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
北京华威锐科化工有限公司0757-86329057 18934348241 · [email protected]
上海祈铭新材料有限公司021-36010885 13661599081;13701898138 · [email protected]
上海探圭新材料科技有限公司18516111942 · [email protected]
Shanghai Enchem Industry Co., Ltd.15021317485
壮铭新材料科技江苏有限公司17312398916 051386936896 15216715905 · [email protected]
Alfa Chemistry1-516-6625404 · [email protected]
HANGZHOU LEAP CHEM CO., LTD.+86-571-87711850 +86-15355479329 · [email protected]
深圳市创鑫生物科技有限公司13417589054 · [email protected]
徐州卓运新材料科技有限公司0516-0516 13776763863 · [email protected]
Shanghai Daken Advanced Materials Co.,Ltd+86-2158073036 · [email protected]
苏州矽索新材料有限公司（生产型企业）0512-65402974 18550909935 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
career henan chemical co+86-0371-86658258 · [email protected]
ATK CHEMICAL COMPANY LIMITED+undefined-21-51877795 · [email protected]
武汉赢元贝商贸有限公司86-13349903920 13349903920 · [email protected]
郑州艾克姆化工有限公司0371-63315541 13323832564 · [email protected]
深圳聚合生化科技有限公司+86-400-002-6226 13028896684 · [email protected]
湖南秉航新材料有限公司85521272 18932438858 · [email protected]
深圳市创鑫生物科技有限公司13417589054 · [email protected]
陕西缔都医药化工有限公司029-029-029-81148696 18161915376 · [email protected]
沈阳莫德医药科技有限公司024-23982345 · [email protected]
北京百灵威科技有限公司18210857532 18210857532 · [email protected]
湖北成丰化工有限公司15827338311 · [email protected]
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