ジフェニルホスフィン

Diphenylphosphine

HCID 70017CAS 829-85-6

基本情報

標準SMILES
c1ccc(Pc2ccccc2)cc1
InChIKey
GPAYUJZHTULNBE-UHFFFAOYSA-N
分子式
C12H11P
平均分子量
186.19 g/mol
単同位体質量
186.05983698

名称と識別子

優先名称
Diphenylphosphine
IUPAC
diphenylphosphane
現地名
ジフェニルホスフィン
英語名
Diphenylphosphine
分子式
C12H11P
分子量
186.19

名称と別名

Diphenylphosphine829-85-6Phosphine, diphenyl-F9B5T7O7ZYEINECS 212-591-4NSC-152123DIPHENYLPHOSPHINE [MI]DTXSID50232076NSC 152123RefChem:588939DTXCID50154567212-591-4
名称をさらに表示
ジフェニルホスフィンジフェニルホスフィン, 10%W/Wヘキサン溶液ジフェニルホスファンDiphenylphosphin98% Ph2PHAURORA KA-1107Diphenyl phospinePHOSPHINE, DIPHENYLDPP/DIPHENYLPHOSPHIN
diphenylphosphaneHPPH2PH2PHMFCD00003040C12H11PUNII-F9B5T7O7ZYdiphenylphospinediphenyl-phosphane

データベース識別子

CAS
829-85-6
PubChem CID
70017
DTXSID
DTXSID50232076
UNII
F9B5T7O7ZY
EC Number
212-591-4
Nikkaji
J99.507J

物性

構造計算による物性

XLogP
3
極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
2
重原子数
13

実験および物理化学的性質

Chemical ClassesOther Classes -> Phosphorus Compounds
SpringerMaterials Properties31P nuclear magnetic resonance spectrum
Physical DescriptionClear liquid with strong unpleasant odor; [Merck Index] Clear light yellow liquid; [Sigma-Aldrich MSDS]

物理化学的性質

融点
-14.5 °C · -14.5 °C
沸点
280 °C · 280 °C(lit.)
比重(密度)
1.07 g/mL · 1.07 g/mL at 25 °C(lit.)
蒸気圧
2 mm · 2 mm Hg ( 110 °C)
屈折率
20 · n20/D 1.625(lit.)
闪点
-18 °C · -18°C (Hexane)
化学的性質 · 1 件

化学的特性Diphenylphosphine is an organophosphorus compound commonly used in laboratories. It is a clear colorless to slightly yellow liquid with unpleasant odor, irritating, easily oxidized in air and spontaneously combusts, sensitive to air and light, and needs to be protected by nitrogen. It can be used as a precursor for the synthesis of a variety of organophosphine ligands. These ligands, in turn, are used in homogeneous catalysis for many applications including: asymmetric hydrogenation, coupling chemistry, ethylene oligomerization, hydroformylation, hydration of nitriles, and polymerization of alkenes.

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H250 (100%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]

P210, P222, P231, P233, P261, P264, P264+P265, P271, P280, P302+P335+P334, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 50 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory InformationStatus: Active Update: 15-03-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/28173
Hazards SummaryPyrophoric and irritating; [Merck Index] Pyrophoric; Reacts violently with water; A skin and strong eye irritant; [Sigma-Aldrich MSDS] See Triphenylphosphine and Phenylphosphine.
Hazard Classes and CategoriesPyr. Liq. 1 (100%)

安全データ

F
8-10-13-23
wgk
3
ridadr
UN 2845 4.2/PG 1
hs_code
29319090
risk_code
17-36/37/38
消防法
危-4-3-III

化学と産業

用途と製造

UsesUsed as a reagent in synthetic organic chemistry; [Merck Index]

応用分野

使用Diphenylphosphine is used in the synthesis of aminophosphines for application as catalysts. It is also used in the preparation of chiral palladacycles with N-heterocyclic carbene ligands as catalysts.

サプライヤー50 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
T&W GROUP021-61551611 13296011611 · [email protected]
科瑞迪化学400-821-5857 021-64326257 · [email protected]

関連反応

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