2-Chloroacrylonitrile (HCID 70198)

概要

2-chloroacrylonitrile appears as a liquid. Boiling point 190-192 °F (88-89 °C). Density 1.096 g / cm3. Flash point 44 °F. Highly toxic.

名称と識別子

優先名称: 2-Chloroacrylonitrile
IUPAC: 2-chloroprop-2-enenitrile
現地名: 2-クロロアクリロニトリル
英語名: 2-Chloroacrylonitrile
分子式: C3H2ClN
分子量: 87.51

名称と別名

2-Chloroacrylonitrile920-37-6Chloroacrylonitrile2-Propenenitrile, 2-chloro-2-Chloro-2-propenenitrileAcrylonitrile, 2-chloro-alpha-Chloroacrylonitrile2-chloropropenenitrile1-Chloro-1-cyanoethene1-Cyanovinyl chloride1-Cyano-1-chloroethene1-Chloro-1-cyanoethylene

名称をさらに表示

2-クロロアクリロニトリル2-クロロプロペンニトリル1-クロロ-1-シアノエテンα-クロロアクリロニトリル２クロロアクリロニトリル2-クロロシアノエチレン2-Chloroacrylonitrile ,99%oroacryLNSC 5117142-PROPENONITRLLE2-CHLORACRYLONITRIL2-chloropylenitrile2-chloroacrylnitrile2-CHLOROCYANOETHYLENE

FFJ1QHD154NSC-511714DTXSID6052613RefChem:86441DTXCID0031186213-055-22-chloroprop-2-enenitrile.alpha.-Chloroacrylonitrile

データベース識別子

CAS: 920-37-6
PubChem CID: 70198
DTXSID: DTXSID6052613
UNII: FFJ1QHD154
EC Number: 213-055-2
Nikkaji: J55.139B

物性

構造計算による物性

XLogP: 1.4
極性表面積: 23.8 Å²
水素結合供与体数: 0
水素結合受容体数: 1
回転可能結合数: 0
重原子数: 5
形式電荷: 0
複雑度: 86.3

実験および物理化学的性質

Chemical ClassesNitrogen Compounds -> Nitriles

SpringerMaterials PropertiesSchoenflies notation

Flash Point · 2 件

44 °F (NTP, 1992)

44 °F

Boiling Point190 to 192 °F at 760 mmHg (NTP, 1992)

Melting Point-85 °F (NTP, 1992)

Physical Description · 2 件

2-chloroacrylonitrile appears as a liquid. Boiling point 190-192 °F (88-89 °C). Density 1.096 g / cm3. Flash point 44 °F. Highly toxic.

Highly toxic liquid with boiling point of 88-89 deg C; [CAMEO]

物理化学的性質

融点: 65 °C · −65 °C(lit.)
沸点: 88 · 88-89 °C(lit.)
比重(密度): 1.096 g/mL · 1.096 g/mL at 25 °C(lit.)
屈折率: 20 · n20/D 1.429(lit.)
闪点: 44 °F · 44 °F
貯蔵温度: 2 · Inert atmosphere,2-8°C
溶解性: クロロホルム、酢酸エチル、メタノール（微量）
外見: 液体
色: 無色透明～黄色
BRN: 773744 · 773744
InChI: InChI=1S/C3H2ClN/c1-3(4)2-5/h1H2
InChIKey: OYUNTGBISCIYPW-UHFFFAOYSA-N
SMILES: C(#N)C(Cl)=C
CAS データベース: 920 · 920-37-6(CAS DataBase Reference)
NISTの化学物質情報: 2 · 2-Propenenitrile, 2-chloro-(920-37-6)
EPAの化学物質情報: 2 · 2-Chloroacrylonitrile (920-37-6)

化学的性質

化学的特性colorless to light yellow liqui

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P203, P210, P233, P240, P241, P242, P243, P260, P262, P264, P270, P271, P273, P280, P284, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P318, P320, P321, P330, P342+P316, P361+P364, P363, P370+P378, P391, P403, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory InformationChemical: 2-Propenenitrile, 2-chloro-

DOT LabelFlammable Liquid

Fire HazardsExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:

Health HazardsExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:

Hazards SummaryHighly toxic; [Quick CPC] Polymerizable and highly flammable; [CAMEO] Lachrymator and skin irritant; Possible skin sensitizer; May be metabolized to cyanide; [MSDSonline]

Reactive GroupHalogenated Organic Compounds

安全と保護具

Fire FightingFires involving this compound can be controlled with a dry chemical, carbon dioxide, foam, or Halon extinguisher. (NTP, 1992)

First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill ResponseSTORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)

Isolation and EvacuationExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:

Personal Protective Equipment (PPE)MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.

毒性情報

Adverse EffectsOther Poison - Chemical Asphyxiant

Toxicity DataLC50 (mice) = 105 mg/m3/2h

安全データ

wgk: 3
tsca: TSCA listed
rtecs: AT5525000
ridadr: UN 3383 6.1/PG 1
hs_code: 29269095
risk_code: 45-24-26/28-34-43-50-40-36/37/38-28-23/24-11
化審法: (2)-1518
消防法: 危-4-1-II
hazard_code: F,T+,T,N
hazard_note: Flammable/Very Toxic
safety_code: 53-26-36/37/39-45-61-28A-16-1-28
hazard_class: 3.1
packing_group: II
毒劇物取締法: 劇物

化学と産業

用途と製造

General Manufacturing Information2-Propenenitrile, 2-chloro-: ACTIVE

応用分野

使用2-Chloroacrylonitrile (cas# 920-37-6) is a compound useful in organic synthesis.

一般的な説明A liquid. Boiling point 190-192°F (88-89°C). Density 1.096 g / cm3. Flash point 44°F. Highly toxic.

上流・下流製品情報

上流原料

下流製品

4-ベンジルモルホリン-2-カルボン酸 Thieno[3,2-d]pyrimidin-4(3H)-one 5-Butylpyridine-2-carbonitrile 3-アミノチオフェン-2-カルボン酸エチルフザリン酸 2-Cyanopiperazine 3-クロロチオフェン-2-カルボン酸メチルペンタフルオロベンゼンチオール 4-クロロチエノ[3,2-D]ピリミジン

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2-クロロアクリロニトリル

基本情報

概要