トリフェニルほう素

Triphenylborane

HCID 70400CAS 960-71-4

基本情報

標準SMILES
c1ccc(B(c2ccccc2)c2ccccc2)cc1
InChIKey
MXSVLWZRHLXFKH-UHFFFAOYSA-N
分子式
C18H15B
平均分子量
242.1 g/mol
単同位体質量
242.12668088

名称と識別子

優先名称
Triphenylborane
IUPAC
triphenylborane
現地名
トリフェニルほう素
英語名
Triphenylborane
分子式
C18H15B
分子量
242.12

名称と別名

Triphenylborane960-71-4TriphenylboronBorane, triphenyl-TriphenylborineTriphenyboronDTXSID6027345MFCD00003007boron triphenyl6282553L0GBorine, triphenylEINECS 213-504-2
名称をさらに表示
トリフェニルほう素トリフェニルボラントリフェニルボラン 溶液トリフェニルボラン, 96%トリフェニルボラン, min. 95%Triphenylbortriphenyl-boranborine,triphenylTriphenylboron,min.95%
triphenyl borontriphenyl-boraneAI3-60391C18H15BUNII-6282553L0GBPh3Ph3BBORINE, TRIPHENYL-

データベース識別子

CAS
960-71-4
PubChem CID
70400
DTXSID
DTXSID6027345
ChEMBL
CHEMBL1876579
UNII
6282553L0G
EC Number
213-504-2
Nikkaji
J121.102A

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
3
重原子数
19

実験および物理化学的性質

Chemical ClassesMetals -> Metalloid Compounds (Boron)
Endocrine DisruptorsPotential endocrine disrupting compound
Melting Point142 °C
Vapor Pressure0.0000119 [mmHg]
Physical DescriptionWhite crystalline solid; [EPA ChAMP: Screening Level Hazard Characterization: Triphenylboron Category - 2009] Off-white odorless crystals; [Alfa Aesar MSDS]

物理化学的性質

融点
145 °C · 145 °C (lit.)
沸点
203 °C/15 · 203 °C/15 mmHg (lit.)
比重(密度)
0.898 g/mL · 0.898 g/mL at 25 °C
闪点
1 °F · 1 °F
貯蔵温度
2 · Storage temp. 2-8°C
外見
粉

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H228 (100%): Flammable solid [Danger Flammable solids]

P210, P240, P241, P280, and P370+P378 (click each P-code to see the statement)

Aggregated GHS information provided per 45 reports by companies from 4 notifications to the ECHA C&L Inventory.

危険有害性情報

Regulatory Information · 3 件

Chemical: Borane, triphenyl-

Borane, triphenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Borane, triphenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Borane, triphenyl-: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1 件

Rapidly hydrolyzes; Shipped as the sodium hydroxide adduct in aqueous solution; Corrosive to skin and severely irritating to eyes in rabbits; Not a skin sensitizer in guinea pigs; [EPA ChAMP: Screening Level Hazard Characterization: Triphenylboron Category - 2009] Reproductive toxicity observed in oral study of rats at 10 mg/kg/day; One female failed to conceive, 5 of 9 mated females delivered, and the mean number of pups per litter was significantly reduced; Initial histopathology revealed adverse effects to semen; [EPA - TSCATS] Decomposed by water; A severe eye irritant that may cause eye injury; [Alfa Aesar MSDS] See Tri-n-butylborane.

Hazard Classes and CategoriesFlam. Sol. 1 (100%)

安全と保護具

Protective Action Criteria (PAC) · 3 件

0.59 [mg/m3]

6.5 [mg/m3]

39 [mg/m3]

毒性情報

Adverse Effects · 1 件

Reproductive Toxin - A chemical that is toxic to the reproductive system, including defects in the progeny and injury to male or female reproductive function. Reproductive toxicity includes developmental effects. See Guidelines for Reproductive Toxicity Risk Assessment.

Toxicity DataLC50 (rat) = 73 mg/m3/4hr

安全データ

F
10-23
wgk
3
tsca
TSCA listed
rtecs
ED2367500
ridadr
UN 1993 3/PG 2
risk_code
11-36/37/38-22-19-40-36/37

化学と産業

用途と製造

Uses · 1 件

A monofunctional Lewis acid; Not currently commercially marketed; Possible applications include olefin polymerization, agrochemicals, metal scavenging, and consumer products (i.e. fuel additives and flame retardants); [EPA ChAMP: Screening Level Hazard Characterization: Triphenylboron Category - 2009]

U.S. Production2023: <50,000 lb
General Manufacturing InformationBorane, triphenyl-: ACTIVE

応用分野

使用TRIPHENYLBORANE is a type of Lewis acid used as catalyst and intermediate.

調製方法 · 1 件

純化方法Recrystallise the borane three times from Et2O or *C6H6 under N2 and dry it at 130o. It can be distilled in a high vacuum at 300-350o and has been distilled (b 195-215o/~15mm) in vacuum using a bath temperature of 240-330o. N2 is introduced into the apparatus before dismantling. It forms complexes with amines. [Nielsen et al. Chem Ind (London) 1069 1957, Wittig et al. Justus Liebigs Ann Chem 563 110 1949, Bent & Dorfman J Am Chem Soc 57 1259 1935, Beilstein 16 IV 1623.]

サプライヤー50 社

湖北万得化工有限公司15377098680 15377098680 · [email protected]
武汉英诺医药科技有限公司+86-027-59232304 15387063101 · [email protected]
咸宁深蓝生物医药研发有限公司18171815831 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
上海药诚医药科技合伙企业(有限合伙)400-6181121 18616381138 · [email protected]

関連反応

11 件

関連ノート

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