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1,2,3-トリクロロプロペン (cis-, trans-混合物)
1,2,3-トリクロロプロペン (cis-, trans-混合物) · 1,2,3-トリクロロ-1-プロペン · 1,2,3-トリクロロプロペン · Nsc164001 · Wln: G1ygu1g · 1,2,3-trichloro-propen · 1,2,3-Trichloropropene · Propene,1,2,3-trichloro-
識別子と物理属性
| CAS No. | 96-19-5 |
|---|---|
| 分子式 | C3H3Cl3 |
| 平均分子量 | 145.41 g/mol |
| 単同位体質量 | 143.93003314 g/mol |
| SMILES | ClC=C(Cl)CCl |
| InChIKey | HIILBTHBHCLUER-UHFFFAOYSA-N |
| PubChem CID | 7286 |
| EC No. | 202-487-7 |
| DTXSID | DTXSID3047766 |
| 現地名 | 1,2,3-トリクロロプロペン (cis-, trans-混合物) |
化学・物理的性質
| XLogP | 2.2 |
|---|---|
| 極性表面積 | 0 |
| 水素結合供与体数 | 0 |
| 水素結合受容体数 | 0 |
| 回転可能結合数 | 1 |
| 重原子数 | 6 |
| 形式電荷 | 0 |
| 複雑度 | 57.1 |
| 物質分類 | Other Classes -> Halogenated Aliphatics, Unsaturated |
| SpringerMaterials Properties | Density |
| 密度 | 1.412 @ 20 °C/20 °C1,43 g/cm3 |
| 溶解度 | VERY SOL IN CHLOROFORMVERY SOL IN ALCOHOL, ETHERSOL IN BENZENEINSOL IN WATERAcetonitrile (Slightly), Chloroform (Sparingly), DMSO (Sparingly), Methanol (Slightly) |
| 引火点 | 85 °C185 °F (Open cup)82°C |
| 沸点 | 142 °C145°C |
| Decomposition | WHEN HEATED TO DECOMP, IT PRODUCES TOXIC FUMES. |
| 蒸気圧 | 4.4 [mmHg]vapor pressure = 4.4 mm Hg @ 25 °C |
| 屈折率 | INDEX OF REFRACTION: 1.5030 @ 20 °C/D1.5000-1.5020 |
| Physical Description | 1,2,3-trichloropropene appears as an amber liquid. May be absorbed through the skin. Vapors are heavier than air. Contact with vapors or liquid may cause burns or irritation.[CAMEO] |
| Other Experimental Properties | Freezing point= -78 °CPounds per gallon= 11.65 at 20 °C.vapor pressure = 4-7 torr, at 20 °C. |
| 融点 | -30°C (estimate) |
| 外観・状態 | clear liquid |
| 色 | Colorless to Almost colorless |
| ヘンリー定数 | 5.5×10-4 mol/(m3Pa) at 25℃, HSDB (2015) |
| CAS データベース | 96-19-5(CAS DataBase Reference) |
| EPAの化学物質情報 | 1-Propene, 1,2,3-trichloro- (96-19-5) |
安全性と法規制
| GHS 分類 | DangerH227 (50%): Combustible liquid [Warning Flammable liquids]P210, P260, P261, P262, P264, P264+P265, P270, P271, P280, P284, P301+P316, P301+P317, P302+P352, P304+P340, P305+P351+P338, P316, P319, P320, P321, P330, P332+P317, P337+P317, P361+P364, P362+P364, P370+P378, P403, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 2 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 輸送ラベル（DOT） | Poison |
| 火災危険 | Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: |
| 火災の可能性 | MODERATE WHEN EXPOSED TO HEAT, FLAMES (SPARKS) OR POWERFUL OXIDIZERS |
| 健康有害性 | Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: |
| 有害性の概要 | Caused somnolence in rats at 36 ppm for 6 hours[RTECS] External application to rabbit eyes scored 5 on a scale of 1-10 after 24 hours (moderate irritation)Observations in three month rodent inhalation study include eye and upper respiratory tract irritation and increased liver enzymesNo significant gross or histopathological effects observed in 13 week inhalation study with ratsA ten week inhalation study with rats produced no evidence of reproductive or developmental toxicity[HSDB] May cause irritation or burns[CAMEO] An irritant that may cause burns[MSDSonline] |
| 反応性グループ | Halogenated Organic Compounds |
| Reactivity Profile | 1,2,3-TRICHLOROPROPENE incompatible with strong oxidizing and reducing agents. Incompatible with many amines, nitrides, azo/diazo compounds, with alkali metals, and with epoxides. Reacts with bases. Produces toxic fumes when heated to decomposition. Avoid contact with iron, plastics, and aluminum. |
| Air and Water Reactions | Flammable. |
| Hazard Classes and Categories | Flam. Liq. 4 (50%) |
| 消火 | Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: |
用途
一般的な説明
An amber liquid. Flash point 185°F. Boiling range 280-304°F (depending on purity). Density 12 lb / gal. May be absorbed through the skin. Vapors are heavier than air. Contact with vapors or liquid may cause burns or irritation.