基本情報
- CAS
100-22-1- 標準SMILES
CN(C)c1ccc(N(C)C)cc1- InChIKey
CJAOGUFAAWZWNI-UHFFFAOYSA-N- 分子式
- C10H16N2
- 平均分子量
- 164.25 g/mol
- 単同位体質量
- 164.13134852
概要
Leaflets or a drab green solid. (NTP, 1992)
名称と識別子
- 優先名称
- N,N,N',N'-tetramethyl-p-phenylenediamine
- IUPAC
- 1-N,1-N,4-N,4-N-tetramethylbenzene-1,4-diamine
- 現地名
- 1,4-ビス(ジメチルアミノ)ベンゼン
- 英語名
- N,N,N',N'-Tetramethyl-1,4-phenylenediamine
- 分子式
- C10H16N2
- 分子量
- 164.25
名称と別名
100-22-1N,N,N',N'-TETRAMETHYL-P-PHENYLENEDIAMINEWurster's reagentTetramethyl-p-phenylenediaminep-Bis(dimethylamino)benzeneTL 85DTXSID5026124p-Phenylenediamine, N,N,N',N'-tetramethyl-P4P3AC32ZBTMPD (amine)Reagents, Wurster'sTMPPD
名称をさらに表示
テトラメチル-p-フェニレンジアミンウルスター試薬N,N,N',N'-テトラメチル-1,4-フェニレンジアミンp-ビス(ジメチルアミノ)ベンゼン1,4-ビス(ジメチルアミノ)ベンゼン1,4-ジ(ジメチルアミノ)ベンゼンN,N,N',N'-テトラメチル-1,4-ベンゼンジアミンN,N,N',N'-テトラメチルベンゼン-1,4-ジアミンN,N,N',N'-テトラメチル-p-フェニレンジアミンWurster試薬N,N,N’,N’-テトラメチル-1,4-フェニレンジアミンN,N,N′,N′-テトラメチル-P-フェニレンジアミンN,N,N′,N′‐テトラメチル‐P‐フェニレンジアミンN,N,N′,N′,-テトラメチル-1,4-フェニレンジアミンN,N,N′,N′-Tetramethyl-p-phenylenediamineN1,N1,N4,N4-Tetramethylbenzene-1,4-diaminetl85WursterBlue]
N,N,N',N'-Tetramethyl-1,4-BenzenediamineDTXCID006124RefChem:926437202-831-6TMPDAn,n,n,n-tetramethyl-1,4-phenylenediamineWurster's BlueN,N,N',N'-Tetramethyl-1,4-phenylenediamine
物性
構造計算による物性
- XLogP
- 2.6
- 極性表面積
- 6.5 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 2
- 回転可能結合数
- 2
- 重原子数
- 12
- 形式電荷
- 0
- 複雑度
- 108
実験および物理化学的性質
Chemical Classes
Nitrogen Compounds -> Amines, Aromatic
Nitrogen Compounds -> Amines, Aromatic
SpringerMaterials Properties15N nuclear magnetic resonance spectrum
Solubilityless than 1 mg/mL at 70 °F (NTP, 1992)
Flash Pointgreater than 235 °F (NTP, 1992)
Boiling Point500 °F at 760 mmHg (NTP, 1992)
Melting Point120 to 124 °F (NTP, 1992)
Vapor Pressure0.07 [mmHg]
Physical Description
Leaflets or a drab green solid. (NTP, 1992)
Solid; [Merck Index] Drab green solid; [NTP] Grey powder; [Sigma-Aldrich MSDS]
物理化学的性質
- 融点
- 49 · 49-51 °C(lit.)
- 沸点
- 260 °C · 260 °C(lit.)
- 比重(密度)
- 0.9743 · 0.9743 (rough estimate)
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Warning
H302: Harmful if swallowed [Warning Acute toxicity, oral]
P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, and P501 (click each P-code to see the statement)
Warning
H302 (98%): Harmful if swallowed [Warning Acute toxicity, oral]
P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, and P501 (click each P-code to see the statement)
危険有害性情報
Regulatory Information
Chemical: 1,4-Benzenediamine, N,N,N',N'-tetramethyl-
Tetramethyl-p-phenylenediamine: Does not have an individual approval but may be used under an appropriate group standard
Fire HazardsThis chemical is probably combustible. (NTP, 1992)
Health HazardsACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits toxic fumes. It is an irritant. (NTP, 1992)
Hazards Summary
Causes irritability and acute pulmonary edema in inhalation lethal-concentration studies of mice; [RTECS] May cause irritation; Toxic by inhalation; Harmful by ingestion and skin absorption; Targets the kidney; [Sigma-Aldrich MSDS] See N,N-Diethyl-p-phenylenediamine.
Reactive GroupAmines, Phosphines, and Pyridines
Reactivity Profile
N,N,N',N'-TETRAMETHYL-P-PHENYLENEDIAMINE can burn in air to give toxic NOx gases (NTP, 1992). Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
化学と産業
用途と製造
Uses
Used as a reagent in analytical chemistry (in the hydrochloride form); [Merck Index]
The hydrochloride form is used as a reagent in analytical chemistry; [ChemIDplus]
General Manufacturing Information1,4-Benzenediamine, N1,N1,N4,N4-tetramethyl-: ACTIVE
応用分野
使用In the form of the hydrochloride as a reagent in analytical chemistry.
一般的な説明Leaflets or a drab green solid.
調製方法
純化方法Crystallise the amine from pet ether or water. It can be sublimed or dried carefully in a vacuum line, and stored in the dark under nitrogen. It has been recrystallised from its melt. [Beilstein 13 H 74, 13 I 22, 13 II 40, 13 III 111, IV 107.]
上流・下流製品情報
上流原料
サプライヤー1 社
苏州市森菲达化工有限公司18796480002 18796480002 · [email protected]
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