N-Methylcyclohexylamine (HCID 7514)

概要

Methyl cyclohexylamine appears as a water-white liquid. Slightly soluble in water and floats on water. A strong irritant to skin and eyes. Corrosive. Used as a solvent.

名称と識別子

優先名称: N-Methylcyclohexylamine
IUPAC: N-methylcyclohexanamine
現地名: N-メチルシクロヘキシルアミン
英語名: N-Methylcyclohexylamine
分子式: C7H15N
分子量: 113.2

名称と別名

N-METHYLCYCLOHEXYLAMINEN-Methylcyclohexanamine100-60-7MethylcyclohexylamineCyclohexanamine, N-methyl-CyclohexylmethylamineCyclohexyl(methyl)amineNSC 434UNII-YH8PF4C1OWYH8PF4C1OWEINECS 202-869-3BRN 1523664

名称をさらに表示

N-メチルシクロヘキシルアミンN-メチルシクロヘキサンアミンメチルシクロヘキシルアミンメチルアミノシクロヘキサンN-メチルシクロヘキサン-1-アミンNシクロヘキシルメチルアミンN‐メチルシクロヘキシルアミンN-メチルシクロヘキシルアミン, 98%1-MethylcyclohexylamineAKOS BBS-00004304TIMTEC-BB SBB004314N-METHYCYCLOHEXYLAMINEMETHYLAMINOCYCLOHEXANEBromhexine Impurity 35N-CYCLOHEXYLMETHYLAMINE

N-MetyhcyclohexylamineAI3-16733NSC-434DTXSID3059216CHEBI:590184-12-00-00017 (Beilstein Handbook Reference)methyl cyclohexylamineRefChem:163815

データベース識別子

CAS: 100-60-7
PubChem CID: 7514
DTXSID: DTXSID3059216
ChEBI: CHEBI:59018
UNII: YH8PF4C1OW
EC Number: 202-869-3
Nikkaji: J23.469I

物性

構造計算による物性

XLogP: 1.6
極性表面積: 12 Å²
水素結合供与体数: 1
水素結合受容体数: 1
回転可能結合数: 1
重原子数: 8
形式電荷: 0
複雑度: 55.4

実験および物理化学的性質

SpringerMaterials PropertiesOptical coefficient

Physical DescriptionMethyl cyclohexylamine appears as a water-white liquid. Slightly soluble in water and floats on water. A strong irritant to skin and eyes. Corrosive. Used as a solvent.

物理化学的性質

融点: -9 · -9--7 °C (lit.)
沸点: 149 °C · 149 °C (lit.)
比重(密度): 0.868 g/mL · 0.868 g/mL at 25 °C (lit.)
蒸気密度: 4 · 4 (vs air)
蒸気圧: 11 mm · 11 mm Hg ( 40 °C)
屈折率: 20 · n20/D 1.456(lit.)
闪点: 85 °F · 85 °F
貯蔵温度: Keep in dark place,Inert atmosphere,Room temperature
溶解性: 54 g/リットル · 54g/リットル
外見: 液体
酸解離定数(Pka): 11.03 · 11.03±0.20(Predicted)
比重: 0.855 · 0.855 (20/4℃)
色: 無色透明～黄色
PH: 12 · 12 (10g/l, H2O, 20℃)
爆発限界(explosive limit): 2.2 · 2.2-10.5%(V)
水溶解度: 5.4 g/100mL · 5.4g/100mL(20℃)
BRN: 1523664 · 1523664
Dielectric constant: 3.64 · 3.6400000000000001
InChI: 1S/C7H15N/c1-8-7-5-3-2-4-6-7/h7-8H,2-6H2,1H3
InChIKey: XTUVJUMINZSXGF-UHFFFAOYSA-N
SMILES: CNC1CCCCC1
CAS データベース: 100 · 100-60-7(CAS DataBase Reference)
NISTの化学物質情報: Cyclohexanamine, N-methyl-(100-60-7)
EPAの化学物質情報: Cyclohexanamine, N-methyl- (100-60-7)

化学的性質

化学的特性clear colourless to yellow liquid

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H226 (99.5%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P234, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P362+P364, P363, P370+P378, P390, P403+P233, P403+P235, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 218 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 3 件

Chemical: Cyclohexanamine, N-methyl-

Status: Active Update: 13-01-2016 https://echa.europa.eu/registration-dossier/-/registered-dossier/17035

Cyclohexyl(methyl)amine: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelFlammable Liquid Corrosive

Fire HazardsExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Health HazardsExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Reactive GroupAmines, Phosphines, and Pyridines

Reactivity AlertsHighly Flammable

安全と保護具

Fire FightingExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

First AidExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Nonfire Spill ResponseExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Isolation and EvacuationExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Personal Protective Equipment (PPE)Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

毒性情報

EPA Provisional Peer-Reviewed Toxicity Values · 3 件

n-Methylcyclohexylamine

PDF Document

2011

安全データ

wgk: 1
tsca: TSCA listed
rtecs: GX1529000
ridadr: UN 2734 8/PG 2
hs_code: 29213099
risk_code: 10-21/22-35-20/21/22
化審法: (3)-4003
消防法: 危-4-2-III
hazard_code: C
hazard_note: Corrosive
safety_code: 16-26-36/37/39-45
hazard_class: 8
packing_group: II
Hazard Classifications: Acute Tox. 3 DermalAcute Tox. 4 OralAquatic Chronic 3Eye Dam. 1Flam. Liq. 3Met. Corr. 1Skin Corr. 1A
ストレージクラス: 3 - Flammable liquids

化学と産業

用途と製造

General Manufacturing InformationCyclohexanamine, N-methyl-: ACTIVE

応用分野 · 3 件

使用Intermediate, solvent, acid acceptor.

使用N-Methylcyclohexylamine is used as a component of vulcanization accelerators, but the market size is relatively small.

一般的な説明A water-white liquid. Slightly soluble in water and floats on water. A strong irritant to skin and eyes. Corrosive. Used as a solvent.

調製方法 · 1 件

製造方法N-Methylcyclohexylamine can be prepared by a procedure similar to that used for cyclohexylamine, i.e., by hydrogenation of methylaniline over a supported nickel catalyst or from cyclohexanone and methylamine under hydrogenation conditions. Cyclohexylamine reacts with methanol over copper, zinc, or copper – calcium catalysts.

上流・下流製品情報

上流原料

ジクロロ水銀(II)アルミニウムシクロヘキシルアミンシクロヘキサノン N,N′-ジシクロヘキシルホルムアミジン N,N-ジメチルシクロヘキシルアミン 1,2,3-トリシクロヘキシルグアニジン tert-Butyl N-cyclohexylcarbaMate シクロヘキシルイソシアニド (クロロメチル)トリエトキシシランメチルアミン塩酸塩ジメチルアミン

下流製品

ブロムヘキシン·塩酸塩 2-アミノ-N-シクロヘキシル-N-メチルベンゼンメタンアミン 4-Chloro-N-cyclohexyl-N-MethylbutyraMide, 97%

サプライヤー50 社

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

郑州阿尔法化工有限公司+86-18530059196 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

南京迪恩赛尔生物科技有限公司19951952469 · [email protected]

補足説明

定義ChEBI: A secondary aliphatic amine having methyl and cyclohexyl as the two alkyl groups.

N-メチルシクロヘキシルアミン

基本情報

概要