Hexaethylphosphorous triamide (HCID 75292)

概要

structure given in first source

名称と識別子

優先名称: Hexaethylphosphorous triamide
IUPAC: N-[bis(diethylamino)phosphanyl]-N-ethylethanamine
現地名: トリス(ジエチルアミノ)ホスフィン
英語名: Tris(diethylamino)phosphine
分子式: C12H30N3P
分子量: 247.36

名称と別名

Tris(diethylamino)phosphine2283-11-6Hexaethylphosphorous triamidePhosphorous triamide, hexaethyl-WPC83R9HNCDTXSID4062305Phosphorous triamide, N,N,N',N',N'',N''-hexaethyl-RefChem:900283DTXCID0036760218-920-8Hexaethyl phosphorous triamideN,N,N',N',N'',N''-Hexaethylphosphinetriamine

名称をさらに表示

トリス(ジエチルアミノ)ホスフィントリス(N,N-ジエチルアミノ)ホスフィントリ(ジエチルアミノ)ホスフィンヘキサエチルホスホラストリアミドP(N(C2H5)2)3HexaethyLphosphorous triamideHexaethylphosphinetriamineHEXAETHYLPHOSPHORUS TRIAMIDEAURORA KA-1249

N-[bis(diethylamino)phosphanyl]-N-ethylethanamineMFCD00009041Tris(N,N-diethylamino)phosphineN,N,N',N',N'',N''-hexaethylphosphorous triamideHexaethyltriamidophosphiteHexaethyltriaminophosphineTris(diethylamido)phosphinePhosphorous acid tris(diethylamide)

データベース識別子

CAS: 2283-11-6
PubChem CID: 75292
DTXSID: DTXSID4062305
UNII: WPC83R9HNC
EC Number: 218-920-8
Nikkaji: J21.143E

物性

構造計算による物性

XLogP: 2.8
極性表面積: 9.7 Å²
水素結合供与体数: 0
水素結合受容体数: 3
回転可能結合数: 9
重原子数: 16
形式電荷: 0
複雑度: 126

実験および物理化学的性質

SpringerMaterials Properties15N nuclear magnetic resonance spectrum

物理化学的性質

融点: 230 · 230-232 °C
沸点: 80 · 80-90 °C10 mm Hg(lit.)
比重(密度): 0.903 g/mL · 0.903 g/mL at 25 °C(lit.)
屈折率: 20 · n20/D 1.475(lit.)
闪点: 58 °C · 58 °C
貯蔵温度: 30 °C · Store below +30°C.
酸解離定数(Pka): 9.74 · 9.74±0.70(Predicted)
外見: 液体
比重: 0.903 · 0.903
色: 無色透明～黄橙色
水溶解度: 水に不溶。
BRN: 636187 · 636187
InChI: 1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3
InChIKey: FDIOSTIIZGWENY-UHFFFAOYSA-N
SMILES: CCN(CC)P(N(CC)CC)N(CC)CC
CAS データベース: 2283 · 2283-11-6(CAS DataBase Reference)
EPAの化学物質情報: Phosphorous triamide, hexaethyl- (2283-11-6)

化学的性質

化学的特性clear colorless to yellow-orange liquid

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory InformationHexaethyltriaminophosphine: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 3 (100%)

安全データ

F: 10-23
wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 3
hs_code: 29319090
risk_code: 36/37/38
消防法: 危-4-2-III
hazard_code: Xi
safety_code: 26-36
hazard_class: 3
packing_group: III
Hazard Classifications: Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3
ストレージクラス: 3 - Flammable liquids

化学と産業

用途と製造

General Manufacturing InformationPhosphorous triamide, N,N,N',N',N'',N''-hexaethyl-: ACTIVE

応用分野 · 1 件

使用Tris(diethylamino)phosphine [(Et2N)3P] can be used as a reagent to synthesize: 1,1′-Dialkylisoindigo derivatives by reacting with various 1-alkylisatins via deoxygenation reaction.1-Aminomethylisatins by treating with isatin and primary and secondary amines.It can also be used in the deoxygenation of some cyclic α-diketones using fullerene C60.