3'-アミノアセトアニリド

m-Aminoacetanilide

HCID 7604CAS 102-28-3

基本情報

標準SMILES
CC(=O)Nc1cccc(N)c1
InChIKey
PEMGGJDINLGTON-UHFFFAOYSA-N
分子式
C8H10N2O
平均分子量
150.18 g/mol
単同位体質量
150.07931294

概要

M-aminoacetanilide is a gray solid. (NTP, 1992)

名称と識別子

優先名称
m-Aminoacetanilide
IUPAC
N-(3-aminophenyl)acetamide
現地名
3'-アミノアセトアニリド
英語名
N1-(3-Aminophenyl)acetamide
分子式
C8H10N2O
分子量
150.18

名称と別名

N-(3-Aminophenyl)acetamide102-28-33'-AminoacetanilideM-AMINOACETANILIDE3-AcetamidoanilineAcetamide, N-(3-aminophenyl)-M-Acetaminoanilinem-(Acetylamino)anilineN-Acetyl-m-phenylenediamine3-Amino-N-acetylaniline3-Aminoacetanilid3-Acetylaminoaniline
名称をさらに表示
3'-アミノアセトアニリドアセチル-m-フェニレンジアミンN-アセチル-1,3-フェニレンジアミンN-(3-アミノフェニル)アセトアミドm-アミノアセトアニリドN-アセチル-m-フェニレンジアミン3-アミノセトアニリド3′-アミノアセトアニリド3-アセトアミドアニリンアミノアセトアニリド3'-アミノアセトアニリド, 97%META AMINO ACETANILIDE3-AMINOACETANILIDEFR-2203AKOS BB-8162WLN: ZR CMV13-AcetamidoaniLASISCHEM B52481
Acetanilide, 3'-amino-1-Amino-3-(acetylamino)benzene3-Aminoacetanilid [Czech]3-(Acetylamino)anilinem-AcetamidoanilineN-Acetyl-m-fenylendiaminCCRIS 4574NSC 165576

データベース識別子

CAS
102-28-3
PubChem CID
7604
DTXSID
DTXSID2024454
ChEMBL
CHEMBL1606123
UNII
Q5K7HYS7JJ
EC Number
203-021-5
Nikkaji
J43.351I

物性

構造計算による物性

XLogP
0.9
極性表面積
55.1 Ų
水素結合供与体数
2
水素結合受容体数
2
回転可能結合数
1
重原子数
11

実験および物理化学的性質

Chemical ClassesNitrogen Compounds -> Other Aromatics (Nitrogen)
SpringerMaterials Properties13C nuclear magnetic resonance spectrum
Solubility10 to 50 mg/mL at 75 °F (NTP, 1992)
Boiling PointDecomposes at 1449 °F (NTP, 1992)
Melting Point187.7 to 189.5 °F (NTP, 1992)
Physical Description · 2 件

M-aminoacetanilide is a gray solid. (NTP, 1992)

Gray solid; [CAMEO] Light brown crystalline powder; [Acros Organics MSDS]

物理化学的性質

融点
86 · 86-88 °C(lit.)
沸点
271.72 °C · 271.72°C (rough estimate)
比重(密度)
1.1392 · 1.1392 (rough estimate)
屈折率
1.618 · 1.6180 (estimate)
貯蔵温度
Keep in dark place,Inert atmosphere,Room temperature
外見
powder to crystal

化学的性質

化学的特性light brown crystalline powder

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H302 (21.1%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 57 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory InformationStatus: Active Update: 30-05-2016 https://echa.europa.eu/registration-dossier/-/registered-dossier/17428
Fire HazardsFlash point data concerning this compound are not available, however, it is probably combustible. (NTP, 1992)
Health HazardsACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits toxic fumes. (NTP, 1992)
Hazards SummaryA mild eye irritant; [RTECS] An irritant; [Acros Organics MSDS] See Acetanilide.
Reactive GroupAmides and Imides
Reactivity Profile · 1 件

Aromatic amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

安全と保護具

Fire FightingFires involving this compound can be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

安全データ

wgk
3
tsca
TSCA listed
rtecs
AD8050000
毒性
mouse,LD50,intravenous,320mg/kg (320mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02899,
hs_code
29214200
risk_code
36/37/38

化学と産業

用途と製造

UsesUsed in organic synthesis; [NTP]
General Manufacturing InformationAcetamide, N-(3-aminophenyl)-: ACTIVE
応用分野 · 3 件

用途有機合成原料。

使用3'-Aminoacetanilide is mainly used as reaction intermediates dyes and disperse dyes.

一般的な説明Gray solid.

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関連反応

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