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化工社化工社 化学情報印刷レポート · 研究参考用
HCID 7617作成日：2026年10月27日

トリアリルアミン

トリアリルアミン · 1,1',1''-ニトリロトリ(2-プロペン) · トリ-2-プロペニルアミン · 第三級アミン · TAA · Trialkylamine · N,N-Diallyl-2-propen-1-amine · 2-Propen-1-amine, N,N-di-2-propen-1-yl-

https://huagongshe.com/ja/chemical/7617

トリアリルアミン の分子構造式

識別子と物理属性

CAS No.102-70-5
分子式C9H15N
平均分子量137.22 g/mol
単同位体質量137.12044948 g/mol
SMILESC=CCN(CC=C)CC=C
InChIKeyVPYJNCGUESNPMV-UHFFFAOYSA-N
PubChem CID7617
ChEMBLCHEMBL3188834
ChEBICHEBI:192451
EC No.203-048-2
DTXSIDDTXSID5026174
現地名トリアリルアミン

化学・物理的性質

XLogP2.6
極性表面積3.2
水素結合供与体数0
水素結合受容体数1
回転可能結合数6
重原子数10
形式電荷0
複雑度92.1
物質分類Nitrogen Compounds -> Amines, AliphaticFlammable agents - 2nd degree
SpringerMaterials PropertiesOptical coefficient
LogP（分配係数）log Kow= 2.59
臭いAmmonia-like
密度0.809 at 68 °F (NTP, 1992) - Less dense than waterwill float0.809 @ 20 °C0.79 g/mL at 25 °C (lit.)
Viscosity2.7783X10-3 Pa.s @ 200.00 K
Color/FormLiquidDark brown liquid
溶解度2.5 mg/mL (NTP, 1992)Soluble in ethanol, ethyl ether, acetone, and benzeneIn water, 2,500 mg/l @ 25 °C250g/100mL
引火点103 °F (NTP, 1992)103 °F OC.87 °F
沸点311 to 313 °F at 760 mmHg (NTP, 1992)155.5 °C150-151 °C (lit.)
DecompositionWhen heated to decomposition it emits toxic fumes of /nitrogen oxides/.
融点-94 °F (NTP, 1992)less than -70 °C-70°C
蒸気密度4.73 (vs air)
蒸気圧90 mm Hg ( 80 °C)
屈折率n20/D 1.451(lit.)
貯蔵条件2-8°C
pKa（酸解離定数）pK1:8.31(+1) (25°C)
外観・状態clear liquid
色Colorless to Yellow to Orange
ヘンリー定数3.9×10-2 mol/(m3Pa) at 25℃, Brockbank (2013)
安定性安定。可燃性。強力な酸化剤とは相容れない。
InChI1S/C9H15N/c1-4-7-10(8-5-2)9-6-3/h4-6H,1-3,7-9H2
InChIKeyVPYJNCGUESNPMV-UHFFFAOYSA-N
SMILESC=CCN(CC=C)CC=C
CAS データベース102-70-5(CAS DataBase Reference)
NISTの化学物質情報2-Propen-1-amine, N,N-di-2-propenyl-(102-70-5)
EPAの化学物質情報Triallylamine (102-70-5)

化学的特性

Triallylamine is a flammble liquid. Triallylamine can be detected at 0.5 ppm and is severely irritating at 75 ppm.

安全性と法規制

GHS 分類DangerH226 (100%): Flammable liquid and vapor [Warning Flammable liquids]P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P361+P364, P362+P364, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 165 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.H226: Flammable liquid and vapor [Warning Flammable liquids]
規制情報Chemical: 2-Propen-1-amine, N,N-di-2-propenyl-2-Propen-1-amine, N,N-di-2-propen-1-yl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propen-1-amine, N,N-di-2-propen-1-yl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 14-02-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/223092-Propen-1-amine, N,N-di-2-propenyl-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
輸送ラベル（DOT）Flammable Liquid Corrosive
火災危険Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:· Flammable/combustible material.
火災の可能性MODERATE FIRE RISK...DANGEROUS, WHEN EXPOSED TO HEAT OR FLAME.Flammable liquid when exposed to heat, flame, or oxidizers.
健康有害性Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:· May cause toxic effects if inhaled or ingested.
有害性の概要Subjects recognize an offensive odor at about 0.5 ppm and have more severe symptoms of coughing and nausea at 75-100 ppm. In animal studies, it can cause pneumonitis and liver/kidney injury after heavy inhalation exposures. Death occurs after repeated exposures to 100-200 ppm. [HSDB] Corrosive to the skin, respiratory tract, and eyes

用途

解説

アンモニアの水素原子が3個とも炭化水素基(アルキル，フェニルなど)で置換された有機化合物．一般式R3N．この形のN原子が環の中に取り込まれた第三級アミンもある．また，ピリジンのように環内のN原子が，一方はN－C，他方はN＝Cの形で結合した複素環式化合物も一種の第三級アミンとしての性質をもつ．

用途

防錆剤、イオン交換樹脂原料

使用

Triallylamine is used in organic synthesis.Triallylamine has been proposed as a catalyst for the production of polyesters and as an initiator for the polymerization of butadiene.

一般的な説明

A colorless liquid with a fishlike odor. Density 0.800 g / cm3 and insoluble in water. Hence floats on water. Flash point 103°F. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals.

製法・合成法

調製方法

Triallylamine is manufactured using allyl chloride and ammonia under heat and pressure. It is used as a solvent and in organic syntheses.

May cause halo vision at lower concentrations
May induce acute pulmonary edema
Causes dizziness at 100 ppm
[CHEMINFO] Triallylamine is a skin irritant. [Quick CPC]
輸送番号・ガイド（DOT）2610 132
反応性グループAmines, Phosphines, and Pyridines
Reactivity AlertsStrong Reducing Agent
Reactivity ProfileTRIALLYLAMINE is a strong reducing agent that reacts violently with oxidizing agents. Corrosive towards Al and Zn [Handling Chemicals Safely 1980 p. 912]. Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
DOT Emergency Guidelines/GUIDE 132: FLAMMABLE LIQUIDS - CORROSIVE/ Fire or Explosion: Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water./GUIDE 132: FLAMMABLE LIQUIDS - CORROSIVE/ Health: May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution./GUIDE 132: FLAMMABLE LIQUIDS - CORROSIVE/ Public Safety: CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering./GUIDE 132: FLAMMABLE LIQUIDS - CORROSIVE/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLYit is not effective in spill situations where direct contact with the substance is possible.For more DOT Emergency Guidelines (Complete) data for TRIALLYLAMINE (8 total), please visit the HSDB record page.
DOT Hazard ClassificationTriallylamineUN2610Class 3 Flammable and combustible liquid (49 eCFR § 173.120)PG III: the degree of danger presented by the material is minor
消火Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
漏出応急措置· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
応急処置EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.General First Aid:
暴露管理・個人防護· Wear positive pressure self-contained breathing apparatus (SCBA).
消火手順FOAM, ALCOHOL FOAM, FOG.If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped or safely confined. Use water in flooding quantities as fog. Solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide. Keep run-off water out of sewers and water sources.
保管条件IN GENERAL, MATERIALS WHICH ARE TOXIC AS STORED OR WHICH CAN DECOMP INTO TOXIC COMPONENTS ... SHOULD BE STORED IN A COOL, WELL-VENTILATED PLACE, OUT OF DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD, & SHOULD BE PERIODICALLY INSPECTED ... . INCOMPATIBLE MATERIALS SHOULD BE ISOLATED FROM EACH OTHER.
非火災時の漏出対応Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
処分方法SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
Preventive Measures...CHARACTERISTIC AMMONIACAL ODORS & IRRITANT PROPERTIES @ LOW CONCN WOULD AFFORD ADEQUATE WARNING. ...RECOMMENDED GOOD VENTILATION WHERE ALLYLAMINES WERE PRESENT & CARE TO PREVENT SKIN CONTACT. /ALLYLAMINES/If material not on fire and not involved in fire: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to knock-down vapors.Personnel protection: Avoid breathing vapors. Keep upwind. ... Avoid bodily contact with the material. ... Do not handle broken packages unless wearing appropriate personal protective equipment. Wash away any material which may have contacted the body with copious amounts of water or soap and water. ... If contact with the material anticipated, wear appropriate chemical protective clothing.SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
Isolation and EvacuationExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:Immediate precautionary measure
Personal Protective Equipment (PPE)Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:Personnel protection: ... Wear positive pressure self-contained breathing apparatus. ... Wear appropriate chemical protective gloves, boots, and goggles.
Emergency Response Planning Guidelines· Some of these materials may react violently with water.
環境中動態TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 611(SRC), determined from a measured log Kow of 2.59(2) and a regression-derived equation(3), indicates that triallylamine is expected to have low mobility in soil(SRC). According to the Henry's Law constant of 2.63X10-4 atm-cu m/mole, derived from its vapor pressure, 3.64 mm Hg(5), and water solubility, 2500 mg/l, volatilization from moist soil surfaces is expected. However, the pKa of triallylamine is 8.31(6), indicating that this compound will partially exist in the protonated form in the environment and cations generally adsorb to organic carbon and clay more strongly than their neutral counterparts. Thus volatilization from moist soil surfaces is not expected to be an important fate process. Furthermore, the pKa suggests that the mobility of the compound will be further reduced. The potential for volatilization of triallylamine from dry soil surfaces may exist(SRC) based upon a vapor pressure of 3.64 mm Hg(5).AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 611(SRC), determined from a measured log Kow of 2.59(2) and a regression-derived equation(3), indicates that triallylamine is expected to adsorb to suspended solids and sediment(SRC). Adsorption will be enhanced as the pKa of triallylamine is 8.31(8), indicating that this compound will exist in the protonated form in the environment and cations generally adsorb to organic carbon and clay more strongly than their neutral counterparts. Based upon an estimated Henry's Law constant of 2.63X10-4 atm-cu m/mole, derived from its vapor pressure, 3.64 mm Hg(4), and water solubility, 2500 mg/l(7), volatilization may occur(3). Using this Henry's Law constant and an estimation method(3), volatilization half-lives for a model river and model lake are 7 hours and 6 days, respectively(SRC). However the existence of the compound in the protonated form will attenuate volatilization and thus it will not be an important fate process. According to a classification scheme(5), a BCF of 2.0-4.8(9), and a regression-derived equation(6), suggests the potential for bioconcentration in aquatic organisms is low. Biodegradation may not be an important fate process. Triallylamine, present at 100 mg/l, reached 1% of its theoretical BOD in 4 weeks using an activated sludge inoculum at 30 mg/l and the Japanese MITI test(9).ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), triallylamine, which has a vapor pressure of 3.64 mm Hg at 25 °C(2), is expected to exist solely as a vapor in the ambient atmosphere. Vapor-phase triallylamine is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC)the half-life for this reaction in air is estimated to be 2 hrs(SRC), calculated from its rate constant of 1.7X10-10 cu cm/molecule-sec at 25 °C(3), determined using a structure estimation method(3).
有害作用Neurotoxin - Other CNS neurotoxin
Soil Adsorption/MobilityThe Koc of triallylamine is estimated as 611(SRC), using a log Kow of 2.59(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that triallylamine is expected to have low mobility in soil. The pKa of triallylamine is 8.31(4), indicating that this compound will partially exist in the protonated form in the environment and cations generally adsorb to organic carbon and clay more strongly than their neutral counterparts. Thus mobility of triallylamine is further reduced.
Human Toxicity Excerpts... RECOGNIZABLE @ 0.5 PPM, MUCOUS MEMBRANE IRRITATION OR CHEST DISCOMFORT IN SOME @ 12.5 PPM, INCREASINGLY FREQUENT SYMPTOMS TO 50 PPM, IRRITANT SYMPTOMS MORE SEVERE @ 75 TO 100 PPM WITH UNPLEASANT SYSTEMIC SYMPTOMS INCL NAUSEA, VERTIGO, & HEADACHE.Triallyl amine /vapors on human subjects/ @ 0.5 ppm had noticeable but musty rather than offensive odor. At 50 to 100 ppm it caused increasing irritation, coughing ... .In general allyl amines irritated nose & throat @ lower concn than were irritant to eyes. Vapors are so unpleasant that it is unlikely human beings would voluntarily submit to systematically dangerous conc. /Allyl amines/UNLIKE SATURATED LOWER ALKYLAMINES, SECONDARY & TERTIARY ALLYLAMINES ARE LESS TOXIC THAN MONOALLYLAMINE. ...DECR ACUTE ORAL & PERCUTANEOUS TOXICITY FROM MONO-ALLYLAMINE TO TRIALLYLAMINE...TRIALLYLAMINE SHOWED INCR RELATIVE TOXICITY AS COMPARED TO DIALLYLAMINE ON INHALATION.
Artificial Pollution SourcesTriallylamine's use as an intermediate in organic synthesis(1), its use as an unsaturated polyester resin comonomer and in crosslinking comonomers(2), and its use as an initiator for the polymerization of butadiene (3) may result in its release to the environment through various waste streams(SRC).
Environmental BiodegradationAEROBIC: Triallylamine, present at 100 mg/l, reached 1% of its theoretical BOD in 4 weeks using an activated sludge inoculum at 30 mg/l and the Japanese MITI test(1).
Environmental BioconcentrationDuring a 6 week period, BCFs of 2.0-2.8 and 2.3-4.8 were calculated for triallylamine at concentrations of 0.1 and 0.01 mg/l(1). According to a classification scheme(2), this BCF suggests the potential for bioconcentration in aquatic organisms is low.
Volatilization from Water/SoilThe Henry's Law constant for triallylamine is estimated as 2.63X10-4 atm-cu m/mole, derived from its vapor pressure, 3.64 mm Hg(1), and water solubility, 2500 mg/l(2). This Henry's Law constant indicates that triallylamine is expected to volatilize from water surfaces(3). Based on this Henry's Law constant, the volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec)(3) is estimated as 7 hours(SRC). The volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec)(3) is estimated as 6 days(SRC). Triallylamine's estimated Henry's Law constant(1,2) indicates that volatilization from moist soil surfaces may occur(SRC). The pKa of triallylamine is 8.31(4), which indicates this compound will partially exist in the protonated form in water and moist soil adn the protonated form will not volatilize. The potential for volatilization of triallylamine from dry soil surfaces may exist(SRC) based upon a vapor pressure of 3.64 mm Hg(1).
Non-Human Toxicity ExcerptsTESTED BY DROPPING ON RABBIT EYES ... TRIALLYL AMINE WAS MILDLY IRRITATING....TRIALLYLAMINE WAS MILDLY IRRITATING /TO SKIN & EYES/. ACUTE EXPOSURES TO VAPORS PRODUCED...RESP TRACT IRRITATION. PATHOLOGICAL CHANGES...IN RATS FOLLOWING REPEATED INHALATION INCL CHEMICAL PNEUMONIAS & SOME LIVER & KIDNEY DAMAGE. ...MYOCARDITIS, WHICH OCCURRED AFTER REPEATED INHALATION OF ALL 3 ALLYLAMINES.REPEATED INHALATION FOR RATS, 7 HRX50, CHANGE IN LIVER OR KIDNEY WT AT 100 PPMREDUCED GROWTH AT 200 PPMDEATHS AT 200 PPM, 1/15 OCCURRED @ 100 PPM. /FROM TABLE/Triallylamine (TAA) was tested for mutagenicity in the Salmonella/microsome preincubation assay using a protocol approved by the National Toxicology Program. TAA was tested over a wide range of doses (0, 33, 100, 333, 1000, 3333, and 10,000 ug/plate) in four Salmonella typhimurium strains (TA98, TA100, TA1535, and TA1537) in the presence and absence of Aroclor-induced rat or hamster liver S9. TAA was negative in these tests and the highest ineffective dose level tested (not causing a clearing of the background lawn) in any Salmonella tester strain was 3333 ug/plate.
Environmental Abiotic DegradationThe rate constant for the vapor-phase reaction of triallylamine with photochemically-produced hydroxyl radicals has been estimated as 1.7X10-10 cu cm/molecule-sec at 25 °C(SRC) using a structure estimation method(1). This corresponds to an atmospheric half-life of about 2 hours at an atmospheric concentration of 5X10+5 hydroxyl radicals per cu cm(1). The rate constant for the reaction of triallylamine with ozone has been estimated as 3.6X10-17 cu cm/molecule-sec at 25 °C(SRC) using a structure estimation method(2). This corresponds to an atmospheric half-life of about 8 hours at an atmospheric concentration of 7X10+11 mol/cu cm(2).
Probable Routes of Human Exposure...WARNING PROPERTIES ARE SUFFICIENTLY GOOD TO MAKE VOLUNTARY EXPOSURE IN CONCN THAT ARE SIGNIFICANT FOR SHORT-TERM EXPOSURE UNLIKELY. /ALLYLAMINES/
Environmental Fate/Exposure SummaryTriallylamine's use as an intermediate in organic synthesis, its use as an unsaturated polyester resin comonomer and in crosslinking comonomers, and its use as an initiator for the polymerization of butadiene may result in its release to the environment through various waste streams. If released to air, a vapor pressure of 3.64 mm Hg at 25 °C indicates triallylamine will exist solely as a vapor in the ambient atmosphere. Vapor-phase triallylamine will be degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicalsthe half-life for this reaction in air is estimated to be 2.0 hrs. If released to soil, triallylamine is expected to have low mobility based upon an estimated Koc of 611. Volatilization from moist soil surfaces is expected to be an important fate process based upon an estimated Henry's Law constant of 2.63X10-4 atm-cu m/mole. The pKa of triallylamine is 8.31, indicating that this compound will partially exist in the protonated form in the environment and cations generally adsorb to organic carbon and clay more strongly than their neutral counterparts. Volatilization from moist soil surfaces maybe hindered because the cation is not expected to volatilize. Triallylamine may volatilize from dry soil surfaces based upon its vapor pressure. Biodegradation may not be an important fate process as suggested by a standard aqueous biodegradation test. If released into water, triallylamine is expected to adsorb to suspended solids and sediment based upon the estimated Koc. Volatilization from water surfaces is expected to be an important fate process based upon this compound's estimated Henry's Law constant. Estimated volatilization half-lives for a model river and model lake are 7 hrs and 6 days, respectively. However, volatilization from water surfaces is expected to be attenuated by adsorption to suspended solids and sediment in the water column. The pKa of triallylamine is 8.31, indicating that this compound will partially exist in the protonated form in the environment and cations generally adsorb to organic carbon and clay more strongly than their neutral counterparts. Thus volatilization from water and moist soil surfaces as well as mobility in soil will be greatly reduced. A BCF of 2.0-4.8 suggests bioconcentration in aquatic organisms is low. Occupational exposure to triallylamine may occur through inhalation and dermal contact with this compound at workplaces where triallylamine is produced or used. (SRC)
水環境危害等級（WGK）3
TSCA 収載状態TSCA listed
RTECS 番号XX5950000
輸送番号（UN）UN 2610
税関コード29211990
危険文句（R）10-20/21/22-34
化審法(2)-2381
消防法危-4-2-III
危険表示C
安全措置（S）16-26-36/37/39-45
危険等級3Acute Tox. 3 InhalationAcute Tox. 4 DermalAcute Tox. 4 OralFlam. Liq. 3Skin Corr. 1B
包装等級III
貯蔵分類3 - Flammable liquids
有害物質データ102-70-5(Hazardous Substances Data)