基本情報
- CAS
3536-96-7- 標準SMILES
[CH-]=C.[Cl-].[Mg+2]- InChIKey
NAFZXKWEUWVSAW-UHFFFAOYSA-M- 分子式
- C2H3ClMg
- 平均分子量
- 86.8 g/mol
- 単同位体質量
- 85.9773695
概要
See also: Magnesium, chloroethenyl (annotation moved to).
名称と識別子
- 優先名称
- Magnesium, chloroethenyl-
- IUPAC
- magnesium;ethene;chloride
- 現地名
- クロロビニルマグネシウム
- 英語名
- Vinylmagnesium chloride
- 分子式
- C2H3ClMg
- 分子量
- 86.8
名称と別名
Vinylmagnesium chlorideChlorovinylmagnesiumMagnesium, chloroethenyl-EINECS 222-575-9DTXSID80883919EC 222-575-9RefChem:800679DTXCID601023401Vinylmagnesium chloride, 15 wt% solution in tetrahydrofuran222-575-93536-96-7magnesium;ethene;chloride
名称をさらに表示
ビニルマグネシウムクロリドクロロビニルマグネシウムビニルクロロマグネシウムビニルマグネシウム＝クロリド塩化ビニルマグネシウム,テトラヒドロフラン溶液塩化ビニルマグネシウム・テトラヒドロフラン溶液ビニルマグネシウムクロリド 溶液クロロ(エテニル)マグネシウムVinylmagnesiumChlorvinylmagnesiumVinylchloromagnesiumMagnesium,chloroethenyl-Magnesium vinyl chlorideAlkenylmagnesiumchloride
chloro(ethenyl)magnesiumVinyl magnesium chloridemagnesium,ethene,chloridevinyl magnesium-chloridevinyl-magnesium chlorideSCHEMBL356372AR-1K5632MFCD00013594
データベース識別子
- CAS
3536-96-7
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 2
- 回転可能結合数
- 0
- 重原子数
- 4
- 形式電荷
- 0
- 複雑度
- 6
実験および物理化学的性質
Chemical ClassesMetals -> Metals, Organic Compounds
Physical Description
Liquid
15% solution in tetrahydrofuran: Brown liquid; [Acros Organics MSDS]
物理化学的性質
- 沸点
- 66 °C · 66 °C
- 比重(密度)
- 0.98 g/mL · 0.980 g/mL at 20 °C
- 闪点
- 1 °F · −1 °F
- 貯蔵温度
- 0 · 0-6°C
- 外見
- 結晶性粉末
- 色
- 白からベージュ
- 水溶解度
- 激しい反応
- BRN
- 3535268 · 3535268
- InChI
- InChI=1S/C2H3.ClH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1
- InChIKey
- NAFZXKWEUWVSAW-UHFFFAOYSA-M
- SMILES
- C(=C)[Mg]Cl
- CAS データベース
- 3536 · 3536-96-7(CAS DataBase Reference)
- EPAの化学物質情報
- Magnesium, chloroethenyl- (3536-96-7)
化学的性質
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
This chemical does not meet GHS hazard criteria for 3.3% (11 of 333) of reports.
Danger
H225 (50.2%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P223, P231+P232, P233, P240, P241, P242, P243, P260, P264, P264+P265, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P402+P404, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 333 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
危険有害性情報
Regulatory Information
Magnesium, chloroethenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Magnesium, chloroethenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.
REACH registered substance: Chlorovinylmagnesium (EC: 222-575-9)
Hazards Summary
Corrosive to skin; [Quick CPC] 15% solution in tetrahydrofuran: Reacts violently and/or explosively with water and moisture in the air; May ignite or explode on contact with moisture; Causes burns; Inhalation may cause chemical burns to respiratory tract and CNS depression; May cause liver and kidney injury; [Acros Organics MSDS]
Hazard Classes and CategoriesFlam. Liq. 2 (50.2%)
毒性情報
Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
化学と産業
用途と製造
UsesUsed as an intermediate; [ExPub: ECHA REACH Registrations]
U.S. Production2023: 69,446 lb
Industry UsesIntermediate
General Manufacturing Information
All Other Basic Organic Chemical Manufacturing
Magnesium, chloroethenyl-: ACTIVE
応用分野
用途有機合成用試薬。
使用Vinylmagnesium chloride (Grignard reagent) can be prepared from vinyl chloride and then used to make a variety of useful end products or intermediates by adding a vinyl anion to organic functional groups. For instance, the vinylmagnesium compounds can be coupled with cuprous chloride, CuCl, at 60 °C (76 °F) to give 1,3-butadiene, while vinyl ketones and alcohols can be prepared by the addition of vinylmagnesium chloride to organic acids.
上流・下流製品情報
下流製品
関連反応
0 件
現在のフィルター条件では反応記録がありません。
化合物ノート
読み込み中…