基本情報
- 標準SMILES
CCCC(C)Br- InChIKey
LGAJYTCRJPCZRJ-UHFFFAOYSA-N- 分子式
- C5H11Br
- 平均分子量
- 151.04 g/mol
- 単同位体質量
- 150.00441245
概要
2-bromopentane appears as a colorless to yellow-colored liquid with a strong odor. Flash point 90 °F. Slightly denser than water and insoluble in water. Vapors heavier than air. May irritate skin and eyes. In high concentrations the vapors may be narcotic.
名称と識別子
- 優先名称
- 2-Bromopentane
- IUPAC
- 2-bromopentane
- 現地名
- 2-ブロモペンタン (約12%3-ブロモペンタン含む)
- 英語名
- 2-Bromopentane
- 分子式
- C5H11Br
- 分子量
- 151.04
名称と別名
2-BROMOPENTANE107-81-3Pentane, 2-bromo-2-Pentyl bromideDTXSID908704562-amyl bromideRefChem:85891DTXCID10818178203-521-3(+/-)-2-BromopentaneNSC 78961-methylbutyl bromide
名称をさらに表示
2-ブロモペンタン (約12%3-ブロモペンタン含む)2-ブロモペンタン1-メチルブチルブロミドsec-アミルブロミド2ブロモペンタン2-ペンチルブロミド (約12%3-ブロモペンタン含む)2‐ブロモペンタンブロモ-sec-ペンタン2-bromo-pentan2-Pentylbromidpentane,2-bromo-sec-Pentylbromide2-Bromopentaneid2-BROMPENTAN 5 ML
130321-66-3sec-amyl bromideMFCD00000160NSC-7896BR1101EINECS 203-521-3UN2343BRN 1718829
データベース識別子
- CAS
107-81-3- PubChem CID
- 7890
- DTXSID
DTXSID90870456- UNII
- E7B8GV5AA4
- EC Number
- 203-521-3
- Nikkaji
- J53.726H
物性
構造計算による物性
- XLogP
- 2.7
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 0
- 回転可能結合数
- 2
- 重原子数
- 6
- 形式電荷
- 0
- 複雑度
- 27.1
実験および物理化学的性質
Chemical ClassesFlammable agents - 3rd degree
SolventsSolvents -> Brominated Solvents
Density1.208 at 68 °F (USCG, 1999) - Denser than water; will sink
Flash Point69 °F (USCG, 1999)
Boiling Point243 °F at 760 mmHg (USCG, 1999)
Melting Point-140 °F (USCG, 1999)
Vapor Pressure21.3 [mmHg]
Physical Description
2-bromopentane appears as a colorless to yellow-colored liquid with a strong odor. Flash point 90 °F. Slightly denser than water and insoluble in water. Vapors heavier than air. May irritate skin and eyes. In high concentrations the vapors may be narcotic.
Colorless to yellow liquid; [CAMEO] Colorless liquid; [MSDSonline]
物理化学的性質
- 融点
- -95.5 °C · -95.5 °C
- 沸点
- 116 · 116-117 °C(lit.)
- 比重(密度)
- 1.223 g/mL · 1.223 g/mL at 25 °C(lit.)
- 屈折率
- 20 · n20/D 1.441(lit.)
- 闪点
- 69 °F · 69 °F
- 貯蔵温度
- Flammables area
- 溶解性
- Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
- 外見
- 液体
- 色
- クリア
- 水溶解度
- 実質的に不溶
- BRN
- 1718829 · 1718829
- 安定性
- 安定。とても燃えやすい。強塩基、強酸化剤とは相容れない。
- InChI
- 1S/C5H11Br/c1-3-4-5(2)6/h5H,3-4H2,1-2H3
- InChIKey
- LGAJYTCRJPCZRJ-UHFFFAOYSA-N
- SMILES
- CCCC(C)Br
- CAS データベース
- 107 · 107-81-3(CAS DataBase Reference)
- NISTの化学物質情報
- 2 · Pentane, 2-bromo-(107-81-3)
- EPAの化学物質情報
- 2 · Pentane, 2-bromo- (107-81-3)
化学的性質
化学的特性2-bromopentane is a colorless to yellow-colored liquid with a strong odor. It is an optically active compound because it contains an asymmetric carbon (chiral carbon). An asymmetric carbon is carbon atom that is attached to four different types of atoms or groups of atoms. In 2-Bromopentance, the central carbon atom is attached to four different types of atoms (CH2, CH3, Br, H), hence it is an optically active compound.
安全と法規制
GHS分類
GHS Classification
Danger
H225 (70.6%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 68 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
危険有害性情報
Regulatory Information
Chemical: Pentane, 2-bromo-
Status: Active Update: 13-04-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/23970
The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelFlammable Liquid
Fire Hazards
Special Hazards of Combustion Products: Toxic fumes of Br
· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Health Hazards
Irritating to eyes, nose, throat, and upper respiratory tract. Causes skin irritation. (USCG, 1999)
· May cause toxic effects if inhaled or absorbed through skin.
Hazards SummaryHighly flammable; A skin, eye, nose, throat, and upper respiratory tract irritant; Inhalation of high concentrations may cause CNS depression; [CAMEO] Highly flammable; An irritant; [MSDSonline]
DOT ID and Guide2343 130
Reactive GroupHalogenated Organic Compounds
Reactivity AlertsHighly Flammable
Reactivity Profile2-BROMOPENTANE is incompatible with strong oxidizing and reducing agents. Also incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
DOT Hazard Classification
2-Bromopentane
UN2343
Class 3 Flammable and combustible liquid (49 eCFR § 173.120)
PG II: the degree of danger presented by the material is medium
Air and Water ReactionsHighly flammable. Insoluble in water.
Hazard Classes and Categories
Flam. Liq. 2 (70.6%)
Flammable agents - 3rd degree
安全と保護具
Fire FightingExcerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
Call a physician.
General First Aid:
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:
Isolation and Evacuation
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:
Immediate precautionary measure
Personal Protective Equipment (PPE)Approved respirator, safety goggles, chemical-resistant gloves, other protective clothing. (USCG, 1999)
Emergency Response Planning GuidelinesCAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient.
毒性情報
Adverse EffectsNeurotoxin - Acute solvent syndrome
Toxicity DataLC50 (mice) = 33,000 mg/m3
安全データ
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- RZ9800000
- ridadr
- UN 2343
- hs_code
- 29033990
- risk_code
- 11-36/37/38
- 化審法
- (2)-67
- 消防法
- 危-4-2-III
- hazard_code
- F,Xi
- safety_code
- 16-26-36/37/39
- hazard_class
- 3
- packing_group
- II
- Hazard Classifications
- Aquatic Chronic 2Flam. Liq. 2Skin Irrit. 2
- ストレージクラス
- 3 - Flammable liquids
化学と産業
用途と製造
General Manufacturing InformationPentane, 2-bromo-: ACTIVE
応用分野
使用Used as a chemical intermediate.
一般的な説明A colorless to yellow-colored liquid with a strong odor. Flash point 90°F. Slightly denser than water and insoluble in water. Vapors heavier than air. May irritate skin and eyes. In high concentrations the vapors may be narcotic.
調製方法
純化方法Dry it over K2CO3 and distil it through a short Vigreux column (p 11). [IR: Pines et al. J Am Chem Soc 74 4063 1952, Brown & Wheeler J Am Chem Soc 78 2199 1956, Beilstein 1 IV 312.]
上流・下流製品情報
上流原料
下流製品
サプライヤー50 社
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北鑫杰成化工科技有限公司13554075426 · [email protected]
合肥翰刚医药科技有限公司+8618062405514 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]
杭州品高化工有限公司0571-87658025 · [email protected]
山东德信精细化工有限公司18553366272
VladaChem GmbH+49-7246-3082843 +86-18411632868 · [email protected]
宁波季诺化学品有限公司0574-87314919 057487319282 · [email protected]
爱斯特（成都）生物制药股份有限公司+86-28-85122536 85324413 · [email protected]
衢州明锋化工有限公司0570-3062502 13819002126;13819008176 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
阿法埃莎（中国）化学有限公司400-6106006 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
江苏艾康生物医药研发有限公司025-5885952 15955137747 · [email protected]
郑州凡尔赛特化工有限公司0371-67991738 13783628208
武汉市皇臻生物化工有限公司13795480948 · [email protected]
上海毕楷科技有限公司18516304666
山东西亚化学有限公司13355009207 13355009207 · [email protected]
ChemeGen 中国18818260767 · [email protected]
玛雅试剂+86 (573) 82222445 (0)18006601000 452520369 · [email protected]
四川库利南科技有限公司400-1166-196 18981987031 · [email protected]
天津希恩思生化科技有限公司400 638 7771 · [email protected]
南京维奥化工有限公司Please Send Email 18652950785 · [email protected]
Wuhan Demeikai Biotechnology Co., Ltd+8618942921723 · [email protected]
艾科试剂4008-755-333 18080918076 · [email protected]
赛默飞世尔科技（中国）有限公司800-810-5118 · [email protected]
北京伊诺凯科技有限公司400-810-7969 010-59572699 · [email protected]
TCI AMERICA800-4238616 · [email protected]
TCI Europe320-37350700 · [email protected]
成都麦卡希化工有限公司028-85632863 18108198598 · [email protected]
上海贤鼎生物科技有限公司4009209199 · [email protected]
武汉卡诺斯科技有限公司153-37111468 15337111468 · [email protected]
上海倍卓生物科技有限公司021-61119791,13386096464 · [email protected]
北京环宇世纪化学科技有限公司hysj_bj.com
上海湄水化工科技有限公司021-60549325 18616193163
HBCChem, Inc.+1-510-219-6317 · [email protected]
日照力德士化工有限公司010-51268198 · [email protected]
江苏汇鸿国际集团鸿金贸易有限公司+86-025-84522992 84524602 13805186390 · [email protected]
美岚实业（上海）有限公司021-58958189 · [email protected]
上海爱蝶实业有限公司021-58957966 18930537195 · [email protected]
广拓化学（上海）有限公司021-60899189-8001 18918189673 · [email protected]
上海御略医药科技有限公司021-60345187 13671753212 · [email protected]
上海鑫圭生物科技有限公司15121041756 · [email protected]
杭州杰恒化工有限公司0571-87396432 · [email protected]
康迪斯化工（湖北）有限公司13125172151 · [email protected]
上海嵩爰化工科技有限公司010-1234567 18521000990 · [email protected]
陕西缔都医药化工有限公司+86-29-87569262 +86-15003564040 · [email protected]
陕西缔都医药化工有限公司029-81024372 17792795018 · [email protected]
凯试（上海）科技有限公司021-50135380 · [email protected]
関連反応
52 件
関連ノート
読み込み中…