ホームMCPワークベンチSkills
ホームワークベンチ通知マイページ
化工社オープンプロジェクト:[email protected]AIアクセス:llms.txt · MCPガイドプライバシーポリシー · 利用規約 · サポートv1.7.8
戻る
化工社化工社 化学情報印刷レポート · 研究参考用
HCID 7966作成日:2026年10月27日

シクロヘキサノール

ヘキサヒドロフェノール · シクロヘキサン-1-オール · 1-シクロヘキサノール · アドロナル · ヘキサリン · ヒドラリン · シクロヘキサノール · ヒドロキシシクロヘキサン

https://huagongshe.com/ja/chemical/7966

シクロヘキサノール の分子構造式

識別子と物理属性

CAS No.108-93-0
分子式C6H12O
平均分子量100.16 g/mol
単同位体質量100.088815 g/mol
SMILESOC1CCCCC1
InChIKeyHPXRVTGHNJAIIH-UHFFFAOYSA-N
PubChem CID7966
ChEMBLCHEMBL32010
ChEBICHEBI:18099
EC No.203-630-6
DTXSIDDTXSID4021894
現地名シクロヘキサノール

化学・物理的性質

XLogP1.2
極性表面積20.2
水素結合供与体数1
水素結合受容体数1
回転可能結合数0
重原子数7
形式電荷0
複雑度46.1
物質分類Flammable agents - 2nd degree
医薬品Pharmaceuticals -> Listed in ZINC15
PolymersOther Classes -> Alcohols and Polyols, Other
SpringerMaterials PropertiesActivity
香料Fragrance Ingredient (Cyclohexanol) -> IFRA transparency List
農薬Insecticides
LogP(分配係数)log Kow = 1.231.36
臭いCamphor-like odor樟脳のように。
密度0.947 at 68 °F (USCG, 1999) - Less dense than waterwill float0.9624 at 20 °C/4 °CPercent in "saturated" air: 0.33 (30 °C)density of "saturated" air: 1.01 (air = 1)Relative density (water = 1): 0.960.962 @ 20°C0.948 g/mL at 25 °C (lit.)
香味料EU Flavoring substances
Viscosity4.6 mPa.s (= cP) at 25 °C
Color/FormColorless needles or viscous liquidHygroscopic crystalsSticky solid or colorless to light-yellow liquid (above 77 degrees F)
融点20-22 °C (lit.)
沸点160-161 °C (lit.)
蒸気密度3.5 (vs air)
蒸気圧0.98 mm Hg ( 25 °C)
屈折率n20/D 1.465(lit.)
引火点67 °C
貯蔵条件Store below +30°C.
溶解度40g/リットル3.6g/100mL(20℃)
外観・状態融解後の液体
pKa(酸解離定数)16
色無色透明
pH6.5 (40g/l, H2O, 20℃)
においのタイプ樟脳のような
爆発限界2-11.2%(V)
比熱容量Cp(liquid): 2.08 J/(g·K), at 25℃
Merck14,2725
BRN906744
ヘンリー定数16.9 at 50.00 °C, 34.4 at 60.00 °C (headspace-GC, Hovorka et al., 2002)
誘電率15.0(25℃)
安定性安定。酸化剤と相容れない。過酸化水素、硝酸などの酸化剤と激しく反応し、室温では爆発性物質を生成する。吸湿性。可燃性。
化粧品成分の機能香料
InChI1S/C6H12O/c7-6-4-2-1-3-5-6/h6-7H,1-5H2
InChIKeyHPXRVTGHNJAIIH-UHFFFAOYSA-N
SMILESOC1CCCCC1
LogP(分配係数)1.25 at 25℃
表面張力33.15mN/m at 293.15K
CAS データベース108-93-0(CAS DataBase Reference)
NISTの化学物質情報Cyclohexanol(108-93-0)
EPAの化学物質情報Cyclohexanol (108-93-0)

化学的特性

Cyclohexanol is a clear, colorless to pale yellow, viscous, hygroscopic liquid with a camphor-like odor. A detection odor threshold concentration of 64 μg/m3 (155 ppbv) was reported by Punter (1983). It has a fairly high flash point and boiling range. A solvent for cellulose ethers, ester gum,shellac, low viscosity silicones and polyvinyl chloride. lt has a fairly limited use in screen inks. lt is miscible with oils and hydrocarbon solvents.

化学性质

色の液体、カプロラクタムおよびアジピン酸の原料

安全性と法規制

GHS 分類WarningH302: Harmful if swallowed [Warning Acute toxicity, oral]P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P319, P321, P330, P332+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)This chemical does not meet GHS hazard criteria for 0.2% (2 of 1012) of reports.H302 (99.8%): Harmful if swallowed [Warning Acute toxicity, oral]
規制情報Chemical: CyclohexanolCommission Regulation (EC) No 1565/2000 (Repealed by Com. Implementing Reg. (EU) No 872/2012)Cyclohexanol is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cyclohexanol are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 23-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/15181Cyclohexanol: HSNO Approval: HSR001397 Approved with controlsThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
その他の安全情報Evaluation - Chemicals that are unlikely to require further regulation to manage risks to human health
輸送ラベル(DOT)Flammable Liquid Poison
火災危険Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:Combustible. Above 68 °C explosive vapour/air mixtures may be formed.
火災の可能性Flammable when exposed to heat or flame.
健康有害性Narcosis-depression of the central nervous system tending to produce sleep or unconsciousness. (USCG, 1999)
有害性の概要Liquid or solid form causes first degree burns on short exposure[CHRIS] Skin absorption and narcosis seen in acute animal studies[ACGIH] A skin, eye, and respiratory tract irritantInhalation of high concentrations may cause CNS effects[ICSC] Causes liver and kidney injury in high-dose animal studies[HSDB]

用途

解説

シクロヘキサノール,C6H12O(100.16).アノールともいう.環状脂肪族飽和アルコール類の一つ.工業的製法には,シクロヘキサンの液相空気酸化法,およびフェノールの水素化法がある.最近,旭化成において,ゼオライト触媒を用いるシクロヘキセンの水和法が工業化された.ショウノウに似た臭いをもつ無色の液体.融点25.15 ℃,沸点161.10 ℃.d4250.9416.nD251.4648.各種有機溶剤に可溶,水に微溶.二級アルコールであるが,直鎖状二級アルコールと違って酸化によって環が開裂してアジピン酸を生じる。また酸化によってシクロヘキサノンを生じるので合成原料として重要。有機溶媒として合成樹脂工業で用いられる。立体構造はイス形が安定。ナイロン原料であるアジピン酸およびカプロラクタムの製造中間体.乳化剤,溶剤として用いられる.

用途

有機合成原料、溶剤。

用途

溶剤( ゴム、塗料等) 、乳化安定剤、可塑剤

用途

シクロヘキサノン(カプロラクタム原料)原料、アジピン酸原料、医薬品抽出溶剤

使用

Cyclohexanol is used for the productionof adipic acid and caprolactam for makingnylon. Its phthalate derivatives are used forplasticizers. It is used as a stabilizer for soapsand detergents; as a solvent for lacquers,varnishes, and shellacs; and as a dye solventfor textiles.

一般的な説明

Cyclohexanol appears as a colorless liquid with a camphor-like odor. Soluble in most organic liquids. Flash point 154 °F. May be toxic by inhalation or skin exposure. Vapors are narcotic in high concentrations. Irritates skin, eyes and mucus membranes. Used in making soap, lacquers, and plastics.

製法・合成法

調製方法

Cyclohexanol is prepared by the catalytic air oxidation of cyclohexane or by the catalytic hydrogenation of phenol. The most important use of cyclohexanol is in producing adipic acid used in the manufacture of caprolactam. Cyclohexanol is used in the manufacture of esters for use as plasticizers; it is also used as a chemical intermediate, a stabilizer, a homogenizer for various soap and detergent emulsions, and as a solvent for lacquers and varnishes . The primary routes of occupational exposure are dermal and inhalation.

合成方法

ベンゼンを出発原料として製造される。シクロヘキサンの空気酸化,シクロヘキサノールの脱水素,フェノールの水素化による方法がある。

純化方法

Reflux it with freshly ignited CaO, or dry it with Na2CO3, then fractionally distil it. Redistil it from Na. It is further purified by fractional crystallisation from the melt in dry air. Peroxides and aldehydes can be removed by prior washing with ferrous sulfate and water, followed by distillation under nitrogen from 2,4-dinitrophenylhydrazine, using a short fractionating column: water distils as the azeotrope. Dry cyclohexanol is very hygroscopic. The 3,4-dinitrobenzoate has m 111-112o (EtOH or aqueous EtOH) It has TOXIC vapours. [Beilstein 6 III 10, 6 IV 20.]

輸送番号・ガイド(DOT)
1993 128(combustible liquid, n.o.s.)
FDA 要件Cyclohexanol is an indirect food additive for use only as a component of adhesives.
反応性グループAlcohols and Polyols
EC 分類Symbol: XnR: 20/22-37/38S: (2)-24/25
Special ReportsEuropean Commission, ESISIUCLID Dataset, Cyclohexanol (108-93-0) (2000 CD-ROM edition) contains information on use, toxicology, and environmental effects of this chemical as supplied to the European Union by industry.[Available from, as of May 5, 2010: http://esis.jrc.ec.europa.eu/]
消火Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:Use powder, carbon dioxide, foam.
応急処置措置Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .
応急処置EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.(General first aid procedures)
安全保管Separated from strong oxidants. Dry.
暴露管理・個人防護Biological Exposure Indices (BEI) [ACGIH] - Screen for 1,2-Cyclohexandiol (with hydrolysis) in urine at end of shift at end of workweekScreen for Cyclohexanol (with hydrolysis) in urine at end of shift
消火手順Use dry chemical, carbon dioxide, or alcohol foam extinguishers. Vapors are heavier than air and will collect in low areas. Vapors may travel long distances to ignition sources and flashback. Vapors in confined areas may explode when exposed to fire. Containers may explode in fire. Storage containers and parts of containers may rocket great distances, in many directions. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters. Notify local health and fire officials and pollution control agencies. From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure position ... The only respirators recommended for fire fighting are self-contained breathing apparatuses that have full facepieces and are operated in a pressure-demand or other positive-pressure mode.If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use "alcohol" foam, carbon dioxide or dry chemical.
保管条件Cyclohexanol must be stored to avoid contact with strong oxidizers (such as chlorine, bromine, and fluorine), since violent reactions occur. Metal containers involving the transfer of this chemical should be grounded and bonded. Where possible, automatically pump liquid from drums or other storage containers to process containers. Drums must be equipped with self-closing valves, pressure vacuum bungs, and flame arresters. Use only non-sparking tools and equipment, especially when opening and closing containers of this chemical. Sources of ignition, such as smoking and open flames, are prohibited where this chemical is used, handled, or stored in a manner that could created a potential fire or explosion hazard. Wherever this chemical is used, handled, manufactured, or stored, use explosion-proof electrical equipment and fittings.
清掃方法SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must be evaluated in accordance with EPA 40 CFR Part 261, specifically Subpart B, in order to determine the appropriate local, state and federal requirements for disposal.Spill handling: evacuate and restrict persons not wearing protective equipment from area of spill or leak until cleanup is complete. Remove all ignition sources. Ventilate area of spill or leak. Absorb liquids in vermiculite, dry sand, earth, or a similar material and deposit in sealed containers. Collect powdered material in the most convenient and safe manner and deposit in sealed containers. It may be necessary to contain and dispose of this chemical as a hazardous waste. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters. Contact your Department of Environmental Protection or your regional office of the federal EPA for specific recommendations.Collect leaking and spilled liquid in sealable containers as far as possible. Sweep spilled substance into sealable containersif appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water.Environmental considerations - land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. /SRP: If time permits, pits, ponds, lagoons, soak holes, or holding areas should be sealed with an impermeable flexible membrane liner./ Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial sorbents.For more Cleanup Methods (Complete) data for Cyclohexanol (6 total), please visit the HSDB record page.
非火災時の漏出対応Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:
処分方法SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air qualitypotential migration in soil or watereffects on animal and plant lifeand conformance with environmental and public health regulations.
漏出処分Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in sealable containers as far as possible. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water.
Preventive MeasuresSRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protectionequipment should be worn even when contact lenses are in place.SRP: Contaminated protective clothing should be segregated in a manner that results in no direct personal contact by personnel who handle, dispose of, or clean the clothing. Quality assurance procedures to confirm the efficacy of the cleaning procedures should be implemented prior to the decontaminated protective clothing being returned for reuse by the workers. Contaminated clothing (including shoes/socks) should not be taken home at end of shift, but should remain at employee's place of work for cleaning.SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must be evaluated in accordance with EPA 40 CFR Part 261, specifically Subpart B, in order to determine the appropriate local, state and federal requirements for disposal.If material not on fire and not involved in fire: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary.For more Preventive Measures (Complete) data for Cyclohexanol (9 total), please visit the HSDB record page.
体内負荷Cyclohexanol was detected in the expired air of 5 of 8 volunteer employees from the U.S. Air Force School of Aerospace Medicine, Brooks Air Force Base, Texasthe concentration averaged 0.78 ug/hr (for positive samples) and ranged between 0.28 and 1.6 ug/hr(1). It was detected in 65.6% of 387 samples of expired air taken from 54 study subjects who were carefully selected from urban areas and were normal, healthy, and non-smoking individualsthe geometric mean was 2.6 ng/L of expired air(2). In a study of 59 workers with occupational exposure to cyclohexanone, it was found that urinary cyclohexanol correlated with the time-weighted-average cyclohexanone exposure(3). When the time-weighted exposure was 25 ppm, the corresponding calculated cyclohexanol level was 54.5 mg/L.
相互作用... This study explored the acute effect of ethanol (EtOH) on the urinary excretion of cyclohexanol (CH-ol), 1,2- and 1,4-cyclohexanediol (CH-diol), biomarkers of exposure to important solvents, and chemical intermediates cyclohexanone (CH-one), cyclohexane (CH) and cyclohexanol. ... Volunteers (5-8 in each group) were exposed for 8 hours either to CH-one, CH or CH-ol vapor at concentrations of about 200, 1000, and (SRP: 2000) mg/cu m, respectively, with concomitant ingestion of EtOH (4 14-g doses taken during the exposure). Urine was collected for 72 hours and analyzed for CH-ol and CH-diols ... . RESULTS: The metabolic yields of CH-ol, 1,2-, and 1,4-CH-diol, respectively, in the exposures with EtOH were as follows: 11.3%, 36%, 23% after the exposure to CH-one, 3.1%, 15%, 8% after the exposure to CH, and 6.6%, 24%, 18% after the exposure to CH-ol. [The corresponding values obtained previously in matching experiments without EtOH were as follows: 1.0%, 39%, 18% (CH-one)0.5%, 23%, 11% (CH)and 1.1%, 19%, 8% (CH-ol).] The excretion curves of the metabolites in the exposures with EtOH were not delayed when compared with the corresponding curves of a comparison group. CONCLUSIONS: The urinary excretion of CH-diols is much less sensitive to EtOH than that of CH-ol. It is recommended to employ CH-diols as useful and more reliable biomarkers of exposure to CH-one, CH and CH-ol in field examinations.
標的器官Eyes, skin, respiratory system
生態毒性値LC50Species: Lepomis macrochirusConditions: freshwater, static, 23 °C, mild aeration applied after 24 hrConcentration: 1100 ppm for 96 hrSpecies: Menidia beryllinaConditions: synthetic seawater, static, 23 °C, mild aeration applied after 24 hrConcentration: 720 ppm for 96 hrSpecies: Pimephales promelas (fathead minnow)Conditions: Lake Superior water, static, 18-22 °CConcentration: 1033 mg/L for 96 hrConditions: flow through, 25.4 °C, pH 7.75, dissolved oxygen 6.3 mg/L, hardness 46.0 mg/L CaCO3, alkalinity 41.0 mg/L CaCO3Concentration: 732 mg/L for 96 hr (confidence limit: 696-770 mg/L)For more Ecotoxicity Values (Complete) data for Cyclohexanol (24 total), please visit the HSDB record page.
環境中動態TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 11(SRC), determined from a log Kow of 1.23(2) and a regression-derived equation(3), indicates that cyclohexanol is expected to have very high mobility in soil(SRC). Volatilization of cyclohexanol from moist soil surfaces is expected to be an important fate process(SRC) given a Henry's Law constant of 4.40X10-6 atm-cu m/mole(4). Cyclohexanol is not expected to volatilize from dry soil surfaces(SRC) based upon a vapor pressure of 0.657 mm Hg at 25 °C(5). In the Japanese MITI test, a 96% of theoretical BOD using activated sludge was reached in 4 weeks(6). Various other aerobic screening studies reported 5-day degradations ranging from 57% to 96% based on theoretical BOD in acclimated sewage inoculums or mixed microbial cultures(7-9). These data suggest that biodegradation is an important environmental fate process in soil(SRC).AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 11(SRC), determined from a log Kow of 1.23(2) and a regression-derived equation(3), indicates that cyclohexanol is not expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is expected(4) based upon a Henry's Law constant of 4.40X10-6 atm-cu m/mole(5). Using this Henry's Law constant and an estimation method(4), volatilization half-lives for a model river and model lake are 8.4 days and 64 days, respectively(SRC). According to a classification scheme(6), an estimated BCF of 3.0(SRC), from its log Kow(2) and a regression-derived equation(3), suggests the potential for bioconcentration in aquatic organisms is low(SRC). In the Japanese MITI test, a 96% of theoretical BOD using activated sludge was reached in 4 weeks(7). Various other aerobic screening studies reported 5-day degradations ranging from 57% to 96% based on theoretical BOD in acclimated sewage inoculums or mixed microbial cultures(8-10). These data suggest that biodegradation is an important environmental fate process in water(SRC).ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), cyclohexanol, which has a vapor pressure of 0.657 mm Hg at 25 °C(2), will exist solely in the vapor phase in the ambient atmosphere. Vapor-phase cyclohexanol is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC)the half-life for this reaction in air is estimated to be 22 hrs(SRC), calculated from its rate constant of 1.7X10-11 cu cm/molecule-sec at 25 °C(3). Cyclohexanol does not contain chromophores that absorb at wavelengths >290 nm(4) and therefore is not expected to be susceptible to direct photolysis by sunlight(SRC).
食品調査値Cyclohexanol was detected in boiled and roasted Chinese chestnuts commercially grown in western Pennsylvania in 1994(1). Cyclohexanol was detected in raw earth almond from Valencia, Spain, but was not detected after subsequent roasting(2). Cyclohexanol was qualitatively detected in mixtures of volatile flavor components from fried chicken(3) and baked potatoes (Idaho Russet Burbank potatoes)(4).
有害作用Neurotoxin - Acute solvent syndrome
暴露経路The substance can be absorbed into the body by inhalation and by ingestion.inhalation, skin absorption, ingestion, skin and/or eye contact
Plant ConcentrationsPlants containing cyclohexanol(1). [Table#173]
Signs and SymptomsCough. Dizziness. Drowsiness. Headache. Nausea. Sore throat.Dry skin. Redness.Redness. Pain.Abdominal pain. Diarrhoea. Further see Inhalation.irritation eyes, skin, nose, throatnarcosis
Effluent ConcentrationsCyclohexanol was qualitatively detected in 5 of 16 samples derived from large volume (>400 gallons) samples of advanced treatment concentrate from 4 of 6 cities (Lake Tahoe, CA, Oct 1974Orange County, CA, Feb 1976Dallas, TX, Nov 1974Blue Plains, Washington, DC, May 1975)(1). Cyclohexanol was found at concentrations ranging from 0.24 to 1.2 mg/L in trench leachate from low level radioactive waste sites at Maxey Flats, KY and West Valley, NY(2,3). It has been found at concentrations >0.5 ppm in wastewaters from unspecified industries in the organic chemicals and plastics/synthetic fibers industrial categories(4). A concentration of 1 ppb was found in samples of leachate or samples of groundwater plume taken at an unspecified municipal landfill at an unspecified time(5). The cyclohexanol concentration found in wastewater from a Russian caprolactam manufacturing facility was reported to be 3.5 mg/L(6). Cyclohexanol was detected in the distillate of landfill leachate of Japanese municipal waste at a concentration of 112 ug/L(7).
Medical SurveillancePhysical examinations of exposed personnel annually, including studies of liver and kidney function.
TSCA 要件Section 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, exposure, and use to EPA as cited in the preamble in 51 FR 41329. Effective date 8/4/95Reporting date: 10/3/95.Pursuant to section 8(d) of TSCA, EPA promulgated a model Health and Safety Data Reporting Rule. The section 8(d) model rule requires manufacturers, importers, and processors of listed chemical substances and mixtures to submit to EPA copies and lists of unpublished health and safety studies. Cyclohexanol is included on this list. Effective date 8/4/95Sunset date: 6/30/98.
大気基準This action promulgates standards of performance for equipment leaks of Volatile Organic Compounds (VOC) in the Synthetic Organic Chemical Manufacturing Industry (SOCMI). The intended effect of these standards is to require all newly constructed, modified, and reconstructed SOCMI process units to use the best demonstrated system of continuous emission reduction for equipment leaks of VOC, considering costs, non air quality health and environmental impact and energy requirements. Cyclohexanol is produced, as an intermediate or final product, by process units covered under this subpart.
F21
職業暴露区分(OEB)A
職業暴露限界(OEL)TWA: 50 ppm (200 mg/m3) [skin]
水環境危害等級(WGK)1
生命健康即時危険濃度400 ppm
TSCA 収載状態TSCA listed
RTECS 番号GV7875000
輸送番号(UN)NA1993
毒性LD50 orally in rats: 2.06 g/kg (Smyth)
税関コード2906 12 00
危険文句(R)20/22-37/38
化審法一般化学物質
安衛法有機溶剤中毒予防規則:第2種有機溶剤,57,57-2
消防法危-4-2-III
危険表示Xn
安全措置(S)24/25
危険等級CBLAcute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralAquatic Chronic 3Eye Irrit. 2Skin Irrit. 2STOT SE 3
自然発火温度572 °F
貯蔵分類10 - Combustible liquids
有害物質データ108-93-0(Hazardous Substances Data)