Tetramethylhexamethylenediamine (HCID 8097)

概要

See also: Hexadimethrine Bromide (monomer of); Hexadimethrine chloride (monomer of); Hexadimethrine (monomer of).

名称と識別子

優先名称: Tetramethylhexamethylenediamine
IUPAC: N,N,N',N'-tetramethylhexane-1,6-diamine
現地名: N,N,N',N'-テトラメチル-1,6-ジアミノヘキサン
英語名: N,N,N',N'-Tetramethyl-1,6-hexanediamine
分子式: C10H24N2
分子量: 172.31

名称と別名

1,6-Bis(dimethylamino)hexaneHexamethylenebis(dimethylamine)tetramethylhexamethylenediamine1,6-HEXANEDIAMINE, N,N,N',N'-TETRAMETHYL-Toyocat MRKoolizer 1Minico TMHDNIAX catalyst C-210U 1000 (amine)N,N,N',N'-TetramethylhexamethylenediamineEINECS 203-842-9U 1000

名称をさらに表示

N,N,N',N'-テトラメチル-1,6-ジアミノヘキサンN,N,N',N'-テトラメチル-1,6-ヘキサンジアミンヘキサメチレンビス(ジメチルアミン)N,N,N',N'-テトラメチルヘキサメチレンジアミンN,N'-(ヘキサメチレン)ビス(ジメチルアミン)1,6-ビス(ジメチルアミノ)ヘキサンN,N,N',N'-テトラメチルヘキサン-1,6-ジアミンN，N，N’，N’テトラメチル1，6ヘキサメチレンジアミンN,N,N',N'-テトラメチルー1,6-ヘキサメチレンジアミンＮ，Ｎ，Ｎ’，Ｎ’テトラメチルヘキサメチレンジアミンN，N，N’，N’-テトラメチルヘキサメチレンジアミンN,N,N',N'-テトラメチル-1,6-ヘキサメチレンジアミンN,N,N′,N′-テトラメチル-1,6-ヘキサンジアミンTMHDTMHDAN1,N1,N6,N6-TetraMethylhexane-1,6-diaMineN,N,N,N-Tetramethyl-1,6-hexanediamine6-hexanediamineu1000TMHMDAkoolizer1Ambap3162toyocatmr

UNII-7D0T53S99VBRN 1738567AI3-26634N,N,N',N'-Tetramethylhexamethylene diamine7D0T53S99VU-CAT 1000EC 203-842-94-04-00-01322 (Beilstein Handbook Reference)

データベース識別子

CAS: 111-18-2
PubChem CID: 8097
DTXSID: DTXSID5033701
ChEMBL: CHEMBL118765
UNII: 7D0T53S99V
EC Number: 203-842-9
Nikkaji: J26.197A

物性

構造計算による物性

XLogP: 1.7
極性表面積: 6.5 Å²
水素結合供与体数: 0
水素結合受容体数: 2
回転可能結合数: 7
重原子数: 12
形式電荷: 0
複雑度: 77.8

実験および物理化学的性質

Physical DescriptionLiquid

物理化学的性質

融点: -46 °C · -46 °C
沸点: 209 · 209-210 °C(lit.)
比重(密度): 0.806 g/mL · 0.806 g/mL at 25 °C(lit.)
蒸気圧: 12.4 Pa · 12.4Pa at 20℃
屈折率: 20 · n20/D 1.4359(lit.)
闪点: 165 °F · 165 °F
貯蔵温度: Sealed in dry,Room Temperature
溶解性: 混和性
外見: 液体
酸解離定数(Pka): 10.07 · 10.07±0.28(Predicted)
色: 無色透明～黄色
水溶解度: 混和性
LogP: 1.99 at · 1.99 at 23℃
CAS データベース: 111 · 111-18-2(CAS DataBase Reference)
NISTの化学物質情報: (CH3)2N(CH2)6N(CH3)2(111-18-2)
EPAの化学物質情報: -1 · N,N,N',N'-Tetramethyl-1,6-hexanediamine (111-18-2)

化学的性質

化学的特性clear colorless to yellow liquid

安全と法規制

GHS分類

GHS Classification · 6 件

Danger

H301+H311+H331 (23.9%): Toxic if swallowed, in contact with skin or if inhaled [Danger Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation]

P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P316, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P330, P361+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 264 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H227: Combustible liquid [Warning Flammable liquids]

危険有害性情報

Regulatory Information · 4 件

Chemical: 1,6-Hexanediamine, N,N,N',N'-tetramethyl-

1,6-Hexanediamine, N1,N1,N6,N6-tetramethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1,6-Hexanediamine, N1,N1,N6,N6-tetramethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 13-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/11920

1,6-Hexanediamine, N,N,N',N'-tetramethyl-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazard Classes and Categories · 2 件

Acute Tox. 3 (88.3%)

Flammable liquids - Category 4

安全データ

wgk: 1
tsca: TSCA listed
rtecs: MO1370000
ridadr: UN 3390 6.1/PG 1
hs_code: 29212900
risk_code: 22-24-34-23/24
化審法: (2)-156
消防法: 危-4-3-III
hazard_code: T
safety_code: 26-36/37/39-45
hazard_class: 8
packing_group: III

化学と産業

用途と製造

U.S. Production2023: 29,063 lb

Industry UsesCatalyst

General Manufacturing Information · 2 件

All Other Basic Organic Chemical Manufacturing

1,6-Hexanediamine, N1,N1,N6,N6-tetramethyl-: ACTIVE

応用分野

用途医薬?農薬中間体,ポリウレタン重合用触媒

使用N,N,N'',N''-Tetramethyl-1,6-hexanediamine is used in the synthesis of fluorene containing poly(arylene ether sulfone) as anion exchange membranes for alkaline fuel cells.