Bromomethylcyclopropane (HCID 81503)

名称と識別子

優先名称: Bromomethylcyclopropane
IUPAC: bromomethylcyclopropane
現地名: 1-(ブロモメチル)シクロプロパン
英語名: (Bromomethyl)cyclopropane
分子式: C4H7Br
分子量: 135

名称と別名

(Bromomethyl)cyclopropane7051-34-5BromomethylcyclopropaneCyclopropane, (bromomethyl)-1-(bromomethyl)cyclopropaneCyclopropanemethyl bromideD8ZPP7X54BEINECS 230-331-8DTXSID40220785(BROMO)(CYCLOPROPYL)METHANERefChem:121604DTXCID70143276

名称をさらに表示

1-(ブロモメチル)シクロプロパンブロモ(シクロプロピル)メタンブロモメチルシクロプロパンシクロプロピルメチルブロミド(ブロモメチル)シクロプロパンシクロプロピルメチルブロマイド(ブロモメチル)シクロプロパン臭化物臭化シクロプロピルメチル(ブロモメチル)シクロプロパン, 97%Cyclopropylcarbinyl bromideCPMBr(Bromomethyl)cyclopr(Xiu Jiaji)cyclopropaneBroMoMethyl)cyclopropanCyclopropylmethylbromidRoflumilast impurity 18CYCLOPROPYLMETYL BROMIDE

230-331-8AEILLAXRDHDKDY-UHFFFAOYSA-NCyclopropylmethyl bromideMFCD00001306bromocyclopropylmethaneCyclopropyl bromo methanebromomethyl cyclopropanecyclopropylmethylbromide

データベース識別子

CAS: 7051-34-5
PubChem CID: 81503
DTXSID: DTXSID40220785
UNII: D8ZPP7X54B
EC Number: 230-331-8
Nikkaji: J23.250E

物性

構造計算による物性

XLogP: 1.7
極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 1
重原子数: 5
形式電荷: 0
複雑度: 30

物理化学的性質

融点: 87 · 87-90 °C
沸点: 105 · 105-107 °C(lit.)
比重(密度): 1.392 g/mL · 1.392 g/mL at 25 °C(lit.)
屈折率: 20 · n20/D 1.457(lit.)
闪点: 107 °F · 107 °F
貯蔵温度: 2 · Inert atmosphere,2-8°C
溶解性: Chloroform (Slightly), Methanol (Slightly)
外見: 液体
比重: 1.392 · 1.392
色: 無色透明～微有色透明
水溶解度: 水には混和しません。
BRN: 605296 · 605296
安定性: 安定。可燃性。強塩基、強酸化剤とは相容れない。
InChI: 1S/C4H7Br/c5-3-4-1-2-4/h4H,1-3H2
InChIKey: AEILLAXRDHDKDY-UHFFFAOYSA-N
SMILES: BrCC1CC1
CAS データベース: 7051 · 7051-34-5(CAS DataBase Reference)
NISTの化学物質情報: Cyclopropane, (bromomethyl)-(7051-34-5)

化学的性質

化学的特性Colorless to yellow liquid

安全と法規制

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 0.5% (1 of 182) of reports.

Danger

H225 (57.1%): Highly Flammable liquid and vapor [Danger Flammable liquids]；H226 (42.3%): Flammable liquid and vapor [Warning Flammable liquids]；H302 (70.9%): Harmful if swallowed [Warning Acute toxicity, oral]；H315 (69.8%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (69.2%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (68.7%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 182 reports by companies from 16 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Reported as not meeting GHS hazard criteria per 1 of 182 reports by companies.；There are 15 notifications provided by 181 of 182 reports by companies with hazard statement code(s).；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 3 件

Chemical: Cyclopropane, (bromomethyl)-

Status: Active Update: 06-03-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/21443

Bromomethyl-cyclopropane: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 2 (57.1%)；Flam. Liq. 3 (42.3%)；Acute Tox. 4 (70.9%)；Skin Irrit. 2 (69.8%)；Eye Irrit. 2A (69.2%)；STOT SE 3 (68.7%)

法規制情報

Regulatory Information · 3 件

Chemical: Cyclopropane, (bromomethyl)-

Status: Active Update: 06-03-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/21443

Bromomethyl-cyclopropane: Does not have an individual approval but may be used under an appropriate group standard

安全データ

wgk: 3
ridadr: UN 1993 3/PG 3
hs_code: 29035990
risk_code: 10-36/37/38-22
化審法: 新規公示化学物質（2011年3月31日以前届出）
消防法: 危-4-2-III
hazard_code: Xi,F,Xn
hazard_note: Irritant
safety_code: 23-24/25-37/39-26-16-36/37/39
hazard_class: 3
packing_group: III
Hazard Classifications: Acute Tox. 4 OralFlam. Liq. 3
ストレージクラス: 3 - Flammable liquids

化学と産業

応用分野 · 3 件

用途有機合成用試薬。

使用(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

一般的な説明The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.

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1-(ブロモメチル)シクロプロパン

基本情報