Diethylene glycol dibutyl ether

HCID 8210CAS 112-73-2

基本情報

標準SMILES
CCCCOCCOCCOCCCC
InChIKey
KZVBBTZJMSWGTK-UHFFFAOYSA-N
分子式
C12H26O3
平均分子量
218.33 g/mol
単同位体質量
218.18819469

名称と識別子

優先名称
Diethylene glycol dibutyl ether
IUPAC
1-[2-(2-butoxyethoxy)ethoxy]butane
現地名
ジエチレングリコールジブチルエーテル
英語名
Diethylene Glycol Dibutyl Ether
分子式
C12H26O3
分子量
218.33

名称と別名

112-73-2DIETHYLENE GLYCOL DIBUTYL ETHERBis(2-butoxyethyl) etherDibutyl carbitolButyl diglyme5,8,11-TrioxapentadecaneEther, bis(butoxyethyl)2-Butoxyethyl etherDiethylene glycol di-n-butyl ether2,2'-Dibutoxyethyl etherButexEther, bis(2-butoxyethyl)
名称をさらに表示
ジエチレングリコールジブチルエーテルビス(2-ブトキシエチル)エーテル1-[2-(2-ブトキシエトキシ)エトキシ]ブタン5,8,11-トリオキサペンタデカン1,1'-オキシビス(2-ブトキシエタン)2,2'-ジブトキシエチルエーテルジブチルカルビトールジエチレングリコールブチルエーテルジエチレングリコルジブチルエテルジエチレングリコ-ルジブチルエ-テルジエチレングリコールジ-N-ブチルエーテルビス(2-N-ブトキシエチル)エーテルジエチレングリコールジ‐N‐ブチルエーテルジブチルジグリコール1,1′-オキシビス(2-ブトキシエタン)2,2′-ジブトキシエチルエーテルDiethylene Glycol Di-n-butylDiethylene glycol diBIS(BUTOXYETHYL)ETHER
Dibutylether diethylenglykoluButane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-Diethyleneglycoldibutyl etherDTXSID8025046EINECS 204-001-9Dibutylether diethylenglykolu [Czech]F8P3DHG73ZBRN 1750713

データベース識別子

CAS
112-73-2
PubChem CID
8210
DTXSID
DTXSID8025046
ChEMBL
CHEMBL1485392
UNII
F8P3DHG73Z
EC Number
204-001-9
Nikkaji
J36.822I

物性

構造計算による物性

XLogP
1.9
極性表面積
27.7 Ų
水素結合供与体数
0
水素結合受容体数
3
回転可能結合数
12
重原子数
15

実験および物理化学的性質

Density · 2 件

0.885 (USCG, 1999) - Less dense than water; will float

0.8853 @ 20°C

Solubilityless than 1 mg/mL at 72 °F (NTP, 1992)
Flash Point · 2 件

245 °F (NTP, 1992)

245.0 °F [CAMEO] VP from ChemIDplus

Boiling Point · 2 件

493 °F at 760 mmHg (NTP, 1992)

256 °C @760 [mm Hg]

Melting Point-76 °F (NTP, 1992)
Vapor Densitygreater than 1 (NTP, 1992) (Relative to Air)

物理化学的性質

融点
-60 °C · -60 °C (lit.)
沸点
256 °C · 256 °C (lit.)
比重(密度)
0.885 g/mL · 0.885 g/mL at 25 °C (lit.)
蒸気密度
1 · >1 (vs air)
蒸気圧
0.01 mm · <0.01 mm Hg ( 20 °C)
屈折率
20 · n20/D 1.423(lit.)

化学的性質

化学的特性clear colorless to yellowish liquid

安全と法規制

GHS分類

GHS Classification · 3 件

This chemical does not meet GHS hazard criteria for 94.6% (192 of 203) of all reports.

Not Classified;Reported as not meeting GHS hazard criteria by 192 of 203 companies (only 5.4% companies provided GHS information). For more detailed information, please visit ECHA C&L website.

Aggregated GHS information provided per 203 reports by companies from 7 notifications to the ECHA C&L Inventory.;Reported as not meeting GHS hazard criteria per 192 of 203 reports by companies.;There are 5 notifications provided by 11 of 203 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 5 件

Chemical: Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-

Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

S - indicates a substance that is identified in a final Significant New Use Rule.

Status: Active Update: 10-07-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/5839

Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-: Does not have an individual approval but may be used under an appropriate group standard

Fire HazardsSpecial Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flash back. (USCG, 1999)
Health HazardsMay be harmful by inhalation, ingestion and skin absorption. Causes eye and skin irritation. Material is irritating to mucous membrane and upper respiratory tract. (USCG, 1999)
Hazards SummaryOxidizes in air and may cause explosive peroxides; A skin and eye irritant; [CAMEO] See Monoglyme.
Reactive GroupEthers
Reactivity AlertsPeroxidizable Compound

安全と保護具

Fire FightingFire Extinguishing Agents: Water spray, dry chemical, alcohol foam. (USCG, 1999)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.;SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.;INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.;INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.;STORAGE PRECAUTIONS: You should keep this material in a tightly closed container under an inert atmosphere, and store it at refrigerated temperatures. (NTP, 1992)

Protective Action Criteria (PAC) · 3 件

12 [ppm]

130 [ppm]

770 [ppm]

Personal Protective Equipment (PPE)Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. (USCG, 1999)

毒性情報

Adverse EffectsNeurotoxin - Acute solvent syndrome

法規制情報

Regulatory Information · 5 件

Chemical: Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-

Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

S - indicates a substance that is identified in a final Significant New Use Rule.

Status: Active Update: 10-07-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/5839

Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-: Does not have an individual approval but may be used under an appropriate group standard

安全データ

wgk
1
tsca
TSCA listed
rtecs
KN0350000
毒性
LD50 orally in Rabbit: 3900 mg/kg LD50 dermal Rabbit 3555 mg/kg
hs_code
29091900
化審法
(2)-3870, (7)-1321

化学と産業

用途と製造

Uses · 2 件

Used as a solvent with applications in coatings and inks, vinyl chloride dispersion, and uranium extraction; [Hawley]

Painting (Solvents) [Category: Paint]

U.S. Production2023: 131,154 lb;2022: 141,941 lb;2021: 66,002 lb;2020: 609,534 lb
Industry UsesAlloys;Solvent;Not Known or Reasonably Ascertainable;Corrosion inhibitor;Flux agent
General Manufacturing Information · 2 件

Not Known or Reasonably Ascertainable;All Other Chemical Product and Preparation Manufacturing;Primary Metal Manufacturing

Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-: ACTIVE

応用分野

使用Butyl diglyme is used to extract gold from hydrochloric acid solutions containing other metals. Treatment of the diglyme extract with hydrogen or oxalic acid precipitates the ionic gold as gold powder.

一般的な説明Colorless liquid. Floats on water.

調製方法 · 1 件

純化方法Dibutylcarbitol is freed from peroxides by slow passage through a column of activated alumina. The eluate is then shaken with Na2CO3 (to remove any remaining acidic impurities), washed with water, and stored with CaCl2 in a dark bottle [Tuck J Chem Soc 3202 1957]. [Beilstein 1 IV 2395.]

上流・下流製品情報

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関連反応

5 件

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